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《材料导报》期刊社  2017, Vol. 31 Issue (6): 125-129    https://doi.org/10.11896/j.issn.1005-023X.2017.06.025
  材料研究 |
PCs/GO复合物对水泥基材料微观结构和力学性能的影响
吕生华1, 朱琳琳1, 贾春茂2, 李莹1, 贺亚亚1, 赵浩然1, 邓丽娟1
1 陕西科技大学轻工科学与工程学院, 西安 710021;

2 陕西科技大学化学与化工学院, 西安 710021
Influence of PCs/GO Composites on Microstructure and Mechanical
Properties of Cement Based Materials
LU Shenghua1, ZHU Linlin1, JIA Chunmao2, LI Ying1, HE Yaya1,
ZHAO Haoran1, DENG Lijuan1
1 College of Resources and Environment, Shaanxi University of Science and Technology, Xi’an 710021;
2 College of
Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021
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摘要 用氧化石墨烯(GO)纳米片层分散液与甲基丙烯酸聚氧乙烯单甲醚(MPE)、甲基丙烯酸(MAA)和丙烯磺酸盐(AA)进行插层聚合反应制备了聚羧酸减水剂(PCs)与GO的插层复合物(PCs/GO),将其应用于水泥基复合材料。结果表明,PCs/GO能够调控水泥基体成为由多面体状产物构成的规整的微观结构,具有显著的增强增韧效果,同时也发现PCs/GO能够在水泥基体的裂缝和孔洞处产生花状和多面体状晶体,具有修复裂缝、孔洞的功效。研究结果对于制备无裂缝及高强度、高韧性和高耐久性水泥基复合材料具有积极的意义。
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吕生华
朱琳琳
贾春茂
李莹
贺亚亚
赵浩然
邓丽娟
关键词:  氧化石墨烯  水泥微观结构  自修复作用  增强作用    
Abstract: The composites of polycarboxylate superplasticizer (PCs) and raphene oxide (GO) (PCs/GO) was prepared by intercalation of GO and methacrylic acid (MAA), sodium allyl sulfonate (SAS) and methacrylate polyoxyethylene ether (MPE). The application results indicated that PCs/GO could regulate to form ordered micromorphology consisted by polyhedron products, which exhibited obvious reinforcing and toughening effect. Meanwhile, it was found that GO could generate flower-like and polyhedron products in the holes and cracks to repair the holes and cracks. The research result has positive significance to preparation of the cement composites with defect-free structure, high strength, high toughness as well as long service life.
Key words:  graphene oxide    cement microstructure    self-repairing effects    reinforcement
出版日期:  2017-03-25      发布日期:  2018-05-02
ZTFLH:  TU528.572  
基金资助: 国家自然科学基金面上项目(21276152)
作者简介:  吕生华:1963年生,博士,教授,博士研究生导师,主要研究方向为水泥基材料的结构与性能,E-mail:lvsh@sust.edu.cn
引用本文:    
吕生华, 朱琳琳, 贾春茂, 李莹, 贺亚亚, 赵浩然, 邓丽娟. PCs/GO复合物对水泥基材料微观结构和力学性能的影响[J]. 《材料导报》期刊社, 2017, 31(6): 125-129.
LU Shenghua, ZHU Linlin, JIA Chunmao, LI Ying, HE Yaya,
ZHAO Haoran, DENG Lijuan. Influence of PCs/GO Composites on Microstructure and Mechanical
Properties of Cement Based Materials. Materials Reports, 2017, 31(6): 125-129.
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https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.06.025  或          https://www.mater-rep.com/CN/Y2017/V31/I6/125
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