Abstract: The submicrometric ZnO hollow spheres with low density, large specific surface area, well-defined structure, controllable size, and many other special physical and chemical properties, have attracted a great deal of attentions. Consequently, seeking simple, highly efficient and economical synthesis technique for submicrometric ZnO hollow spheres has been a focus of attention. Based on our previous study in the field of hollow ZnO and the predecessors work, a comprehensive overview of some novel preparation technologies of submicrometric ZnO hollow spheres, including hydrothermal method, sonochemical method, ultrasonic assisted hydrothermal method, electrostatic spinning and microwave irradiation are introduced in this paper. The mechanism, characteristics and applications of these techniques are also summarized. In addition, the photocatalytic performance of submicrometric ZnO hollow spheres is introduced. Besides, the research foreground of submicrometric ZnO hollow spheres is proposed briefly.
1 She X, Chen L, Velleman L, et al. Fabrication of high specificity hollow mesoporous silica nanoparticles assisted by eudragit for targeted drug delivery[J]. J Colloid Interface Sci,2015,445:151. 2 Mohamed R M, McKinney D, Kadi M W, et al. Cobalt/zinc oxide hollow spheres: Visible light nanophotocatalysts[J]. Ceram Int,2016,42(2):2299. 3 Wang Y, Zhu S, Chen X, et al. One-step template-free fabrication of mesoporous ZnO/TiO2 hollow microspheres with enhanced photocatalytic activity[J]. Appl Surf Sci,2014,307:263. 4 Bera S, Pal M, Naskar A, et al. Hierarchically structured ZnO-graphene hollow microspheres towards effective reusable adsorbent for organic pollutant via photodegradation process[J]. J Alloys Compd,2016,669:177. 5 Wang L, Lou Z, Fei T, et al. Templating synthesis of ZnO hollow nanospheres loaded with Au nanoparticles and their enhanced gas sensing properties[J]. J Mater Chem,2012,22(11):4767. 6 Lai X, Halpert J E, Wang D. Recent advances in micro-/nano-structured hollow spheres for energy applications: From simple to complex systems[J]. Energy Environ Sci,2012,5(2):5604. 7 Gao L, He J. Surface hydrophobic co-modification of hollow silica nanoparticles toward large-area transparent superhydrophobic coa-tings[J]. J Colloid Interface Sci,2013,396:152. 8 Xu S, Hessel C M, Ren H, et al. α-Fe2O3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention[J]. Energy Environ Sci,2014,7(2):632. 9 Zhang F, Li X, et al. Fabrication of α-Fe2O3/In2O3 composite hollow microspheres: A novel hybrid photocatalyst for toluene degradation under visible light[J]. J Colloid Interface Sci,2015,457:18. 10 Sun C, Rajasekhara S, Chen Y, et al. Facile synthesis of monodisperse porous Co3O4 microspheres with superior ethanol sensing pro-perties[J]. Chem Commun,2011,47(48):12852. 11 Hao S, Zhang B, Ball S, et al. Porous and hollow NiO microspheres for high capacity and long-life anode materials of Li-ion batteries[J]. Mater Des,2016,92:160. 12 Liu S, Yu B, Zhang T. A novel non-enzymatic glucose sensor based on NiO hollow spheres[J]. Electrochim Acta,2013,102:104. 13 Zhang P, Ma X, Guo Y, et al. Size-controlled synthesis of hierarchical NiO hollow microspheres and the adsorption for Congo red in water[J]. Chem Eng J,2012,189:188. 14 He S, Li J, Wang J, et al. Facile synthesis and lithium storage performance of hollow CuO microspheres[J]. Mater Lett,2014,129:5. 15 Lo S S, Huang D. Morphological variation and Raman spectroscopy of ZnO hollow microspheres prepared by a chemical colloidal process[J]. Langmuir,2010,26(9):6762. 16 Bao Y, Wang C, Ma J. Morphology control of ZnO microstructures by varying hexamethylenetetramine and trisodium citrate concentration and their photocatalytic activity[J]. Mater Des,2016,101:7. 17 Chen Z, Wang F, Zhang H, et al. Synthesis of uniform hollow TiO2 and SiO2 microspheres via a freezing assisted reverse microemulsion-templated sol-gel method[J]. Mater Lett,2015,151:16. 18 Bao Y, Shi C, Wang T, et al. Recent progress in hollow silica: Template synthesis, morphologies and applications[J]. Microp Mesop Mater,2016,227:121. 19 Wang D, Du S, Zhou X, et al. Template-free synthesis and gas sensing properties of hierarchical submicrometer ZnO hollow spheres[J]. Cryst Eng Comm,2013,5(37):7438. 20 Patrinoiu G, Tudose M, Calderón-Moreno J M, et al. A green chemical approach to the synthesis of photoluminescent ZnO hollow spheres with enhanced photocatalytic properties[J]. J Solid State Chem,2012,186:17. 21 Wang L, Ma C, Ru X, et al. Facile synthesis of ZnO hollow microspheres and their high performance in photocatalytic degradation and dye sensitized solar cells[J]. J Alloys Compd,2015,647:57. 22 Chen M, Ye C, Zhou S, et al. Recent advances in applications and performance of inorganic hollow spheres in devices[J]. Adv Mater,2013,25(37):5343. 23 Li H, Cui Y, Hong W, et al. Photocatalytic performance of Pr/In/Nd composite oxides synthesized by solid state reaction[J]. Ceram Int,2013,39(6):6583. 24 Serio S, Torge M E M, Coutinho M L, et al. Spectroscopic studies of anatase TiO2 thin films prepared by DC reactive magnetron sputtering[J]. Chem Phys Lett,2011,508(8):71. 25 Zhu S, Tian X, Chen J, et al. A facile approach to construct multiple structured ZnO crystals by trisodium citrate-assisted hydrothermal growth toward performance enhancement of dye-sensitized solar cells[J]. J Phys Chem C,2013,118(30):16401. 26 Bao Y, Wang C, Ma J. A two-step hydrothermal route for synthesis hollow urchin-like ZnO microspheres[J]. Ceram Int,2016,42(8):10289. 27 Zang Z, Wen M, Chen W, et al. Strong yellow emission of ZnO hollow nanospheres fabricated using polystyrene spheres as templates[J]. Mater Des,2015,84:418. 28 Lan S, Liu L, Li R, et al. Hierarchical hollow structure ZnO: Synthesis, characterization, and highly efficient adsorption/photocatalysis toward Congo red[J]. Ind Eng Chem Res,2014,53(8):3131. 29 Zhang H, Xu C, Sheng P, et al. Synthesis of ZnO hollow spheres through a bacterial template method and their gas sensing properties[J]. Sens Actuators B: Chem,2013,181:99. 30 Zhao B, Shao G, Fan B, et al. Preparation and microwave absorption of porous hollow ZnO by CO2 soft-template[J]. Adv Powder Technol,2014,25(6):1761. 31 Kim S H, Olson T Y, Satcher J H, et al. Hierarchical ZnO structures templated with amino acid based surfactants[J]. Microp Mesop Mater,2012,151:64. 32 Patrinoiu G, Calderón-Moreno J M, Chifiriuc C M, et al. Tunable ZnO spheres with high anti-biofilm and antibacterial activity via a simple green hydrothermal route[J]. J Colloid Interface Sci,2016,462:64. 33 Zhang Y, Shi E W, Chen Z Z, et al. Fabrication of ZnO hollow nanospheres and “jingle bell” shaped nanospheres[J]. Mater Lett,2008,62(8):1435. 34 Matsuyama K, Mishima K, Kato T, et al. Preparation of submicrometer ZnO hollow spheres using poly(methyl methacrylate) as a template with supercritical CO2-ethanol solution[J].J Am Chem Soc,2010,49:8510. 35 Zhou Y, Li M, Wang Y, et al. Synthesis of sea urchin-like ZnO by a simple soft template method and its photoelectric properties[J]. Mater Sci Semicond Processing,2014,27:1050. 36 Zhou H, Fan T, Zhang D. Hydrothermal synthesis of ZnO hollow spheres using spherobacterium as biotemplates[J]. Microp Mesop Mater,2007,100(1):322. 37 Bao Y, Wang C, Ma J. Trisodium citrate as bridging and suppres-sing agent to control synthesis of ZnO hollow hierarchical microspheres and their photocatalytic properties[J]. Ceram Int,2016,42(1):1746. 38 Siddaramanna A, Thipperudraiah K V, Chandrappa G T. Simple non-basic solution route for the preparation of zinc oxide hollow spheres[J]. Physica E: Low-dimens Syst Nanostruct,2012,44(7):1346. 39 Guo W, Liu T, Sun R, et al. Hollow, porous, and yttrium functionalized ZnO nanospheres with enhanced gas-sensing performances[J]. Sens Actuators B: Chem,2013,178:53. 40 Sun H, Wang L, Chu D, et al. Facile template-free hydrothermal fabrication of ZnO hollow microspheres for gas sensing applications[J]. Ceram Int,2014,40(10):16465. 41 Yin M, Liu S. Preparation of ZnO hollow spheres with different surface roughness and their enhanced gas sensing property[J]. Sens Actuators B: Chem,2014,197:58. 42 Zhang X, Zhao H, Tao X, et al. Sonochemical method for the pre-paration of ZnO nanorods and trigonal-shaped ultrafine particles[J]. Mater Lett,2005,59(14):1745. 43 Hu X L, Zhu Y J, Wang S W. Sonochemical and microwave-assisted synthesis of linked single-crystalline ZnO rods[J]. Mater Chem Phys,2004,88(2):421. 44 Bang J H, Suslick K S. Applications of ultrasound to the synthesis of nanostructured materials[J]. Adv Mater,2010,22(10):1039. 45 Pokhrel N, Vabbina P K, Pala N. Sonochemistry: Science and engineering[J]. Ultrason Sonochem,2016,29:104. 46 Suslick K S, Hammerton D A, Cline R E. Sonochemical hot spot[J]. J Am Chem Soc,1986,108(18):5641. 47 Suslick K S. Sonochemistry[J]. Science,1990,247(4949):1439. 48 Jia X, Fan H, Zhang F, et al. Using sonochemistry for the fabrication of submicrometer ZnO hollow spheres[J]. Ultrason Sonochem,2010,17(2):284. 49 He C X, Lei B X, Wang Y F, et al. Sonochemical preparation of hierarchical ZnO hollow spheres for efficient dye-sensitized solar cells[J]. Chemistry—A Eur J,2010,16(29):8757. 50 Nguyen D T, Kim K S. Structural evolution of highly porous/hollow ZnO nanoparticles in sonochemical process[J]. Chem Eng J,2015,276:11. 51 Ameta G, Pathak A K, Ameta C, et al. Sonochemical synthesis and characterization of imidazolium based ionic liquids: A green pathway[J]. J Mol Liquids,2015,211:934. 52 Abdelhamid H N. Ionic liquids for mass spectrometry: Matrices, separation and microextraction[J]. TrAC Trends Anal Chem,2015,77:122. 53 Kowsari E. Sonochemically assisted synthesis and application of hollow spheres, hollow prism, and coralline-like ZnO nanophotocatalyst[J]. J Nanoparticle Res,2011,13(8):3363. 54 Ameen S, Akhtar M S, Seo H K, et al. An electrochemical sensing platform based on hollow mesoporous ZnO nanoglobules modified glassy carbon electrode: Selective detection of piperidine chemical[J]. Chem Eng J,2015,270:564. 55 Xie Q, Ma Y, Wang X, et al. Electrostatic assembly of sandwich-like Ag-C@ ZnO-C@ Ag-C hybrid hollow microspheres with excellent high-rate lithium storage properties[J]. ACS Nano,2016,10(1):1283. 56 Xie Q, Li J, Tian Q, et al. Template-free synthesis of zinc citrate yolk-shell microspheres and their transformation to ZnO yolk-shell nanospheres[J]. J Mater Chem,2012,22(27):13541. 57 Zhu C, Lu B, Su Q, et al. A simple method for the preparation of hollow ZnO nanospheres for use as a high performance photocatalyst[J]. Nanoscale,2012,4(10):3060. 58 Zhao X, Qi L. Rapid microwave-assisted synthesis of hierarchical ZnO hollow spheres and their application in Cr (Ⅵ) removal[J]. Nanotechnology,2012,23(23):235604. 59 Li X, Wang C, Guo H, et al. Double-shell architectures of ZnFe2O4 nanosheets on ZnO hollow spheres for high-performance gas sensors[J]. ACS Appl Mater Interfaces,2015,7(32):17811. 60 Zhang C, Yin L W, Zhang L Y, et al. Preparation and photocataly-tic activity of hollow ZnO and ZnO-CuO composite spheres[J]. Mater Lett,2012,67:303. 61 Lee W W, Chung W H, Lu C S, et al. A study on the degradation efficiency and mechanisms of ethyl violet by HPLC-PDA-ESI-MS and GC-MS[J]. Sep Purif Technol,2012,98:488. 62 Patrinoiu G, Tudose M, Calderón-Moreno J M, et al. A green chemical approach to the synthesis of photoluminescent ZnO hollow spheres with enhanced photocatalytic properties[J]. J Solid State Chem,2012,186:17. 63 Yu J, Yu X. Hydrothermal synthesis and photocatalytic activity of zinc oxide hollow spheres[J]. Environ Sci Technol,2008,42(13):4902.
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2017, Vol. 31 
