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材料导报  2025, Vol. 39 Issue (16): 24060038-9    https://doi.org/10.11896/cldb.24060038
  高分子与聚合物基复合材料 |
Janus膜改性强化蒸馏膜抗污染和抗润湿性能的研究进展
刘乾亮1, 王泳淞1, 艾恒雨1,*, 梁洪博1, 郭鑫1, 刘彩虹2
1 哈尔滨理工大学材料科学与化学工程学院,黑龙江省绿色化工技术重点实验室,哈尔滨 150080
2 重庆大学环境与生态学院,三峡库区生态环境教育部重点实验室,重庆 400044
Research Progress on Janus Membrane Modification to Enhance the Anti-fouling and Anti-wetting Properties of Distillation Membranes
LIU Qianliang1, WANG Yongsong1, AI Hengyu1,*, LIANG Hongbo1, GUO Xin1, LIU Caihong2
1 Key Laboratory of Green Chemical Engineering and Technology of Heilongjiang Province, School of Material Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, China
2 Key Laboratory of Eco-environments in Three Gorges Reservoir Region, Ministry of Education, College of Environment and Ecology, Chongqing University, Chongqing 400044, China
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摘要 膜蒸馏(MD)是一种以温度梯度为驱动力,可从含盐、含油废水中提取淡水的膜分离技术,因具有分离效率高、操作压力低、热源品位要求低等优点而备受关注。但膜蒸馏普遍存在通量低、膜易污染和易润湿等问题,直接影响膜蒸馏的长期稳定运行。众多研究发现,在膜蒸馏所用的疏水基膜上增加亲水层制成亲水/疏水复合膜(又称Janus膜),可有效避免或延缓膜润湿与膜污染现象,但实施方法与使用效果有较大差异。为开发更耐用的Janus膜,本文从Janus膜的亲疏水特征与评价入手,系统归纳了制备Janus膜的不同改性方法,并对比了其膜接触角、通量、抗污染和抗润湿性能等指标,同时总结分析了改性前后的膜蒸馏效果,在此基础上,探讨了Janus膜在膜蒸馏过程中的抗污染和抗润湿机制及面临的问题,展望了Janus膜在膜蒸馏领域的应用潜力和发展前景。
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刘乾亮
王泳淞
艾恒雨
梁洪博
郭鑫
刘彩虹
关键词:  膜蒸馏  Janus膜  膜改性  膜污染  膜润湿    
Abstract: Membrane distillation (MD) is a separation technology driven by temperature gradient, which could extract freshwater from waste water containing salt and oil. It has advantages such as high separation efficiency, low operating pressure, and low-grade thermal energy utilization, making it receive wide attention in recent years. However, MD commonly faces issues such as low flux, membrane wetting, and membrane fou-ling, which directly affect its long-term stable operation. In recent years, numerous studies have found that adding hydrophilic layers to the hydrophobic base membrane used in membrane distillation, which is called Janus membrane, can effectively avoid or delay membrane wetting and fouling. However, there are significant differences in implementation methods and performances. In order to develop more durable Janus composite membranes, based on hydrophilic-hydrophobic property and evaluation indexes of Janus membrane, their different preparation methods are systematically summarized, and the contact angle, flux, anti-fouling and anti-wetting properties of Janus membranes are compared. Meanwhile, the distillation effects of the membranes before and after modification are compared and comparatively analyzed. On this basis, the mechanism and challenges of Janus membrane in anti-fouling and anti-wetting are discussed. Finally, the application potential and prospects of commercializing Janus distillation membranes in the field of membrane distillation are proposed.
Key words:  membrane distillation    Janus membrane    membrane modification    membrane wetting    membrane fouling
出版日期:  2025-08-15      发布日期:  2025-08-15
ZTFLH:  TB34  
基金资助: 国家自然科学基金青年基金(52100024)
通讯作者:  艾恒雨,哈尔滨理工大学材料科学与化学工程学院教师。目前主要从事环境功能材料、水污染防治技术等方面的研究工作。aihengyu@126.com   
作者简介:  刘乾亮,哈尔滨理工大学材料科学与化学工程学院教师、硕士研究生导师。目前主要从事膜材料开发与应用等方面的研究工作。
引用本文:    
刘乾亮, 王泳淞, 艾恒雨, 梁洪博, 郭鑫, 刘彩虹. Janus膜改性强化蒸馏膜抗污染和抗润湿性能的研究进展[J]. 材料导报, 2025, 39(16): 24060038-9.
LIU Qianliang, WANG Yongsong, AI Hengyu, LIANG Hongbo, GUO Xin, LIU Caihong. Research Progress on Janus Membrane Modification to Enhance the Anti-fouling and Anti-wetting Properties of Distillation Membranes. Materials Reports, 2025, 39(16): 24060038-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24060038  或          https://www.mater-rep.com/CN/Y2025/V39/I16/24060038
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