掺氢/纯氢环境下燃气轮机的氢致损伤研究进展

doi:10.11896/cldb.24040126

材料导报

2025, Vol. 39

Issue (9): 24040126-10 https://doi.org/10.11896/cldb.24040126

金属与金属基复合材料

掺氢/纯氢环境下燃气轮机的氢致损伤研究进展

李丛^1,2, 赵雷^1,2,*, 徐连勇^1,2, 韩永典^1,2, 郝康达^1,2

1 天津大学材料科学与工程学院,天津 300350
2 天津市现代连接技术重点实验室,天津 300350

Research Advances in Hydrogen Induced Damage of Gas Turbines in Hydrogen-containing/Pure-hydrogen Circumstances

LI Cong^1,2, ZHAO Lei^1,2,*, XU Lianyong^1,2, HAN Yongdian^1,2, HAO Kangda^1,2

1 School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China
2 Tianjin Key Laboratory of Modern Connection Technology, Tianjin 300350, China

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摘要随着全球能源结构向低碳化转变,氢能作为一种清洁、可再生的能源,正受到越来越多的关注。掺氢/纯氢燃气轮机作为一种高效能源转换技术,为氢能的大规模应用提供了重要支撑。然而,氢气环境下的燃气轮机热端部件面临着氢致损伤的挑战,限制了其长期稳定运行。本文在国内外大量研究成果的基础上,阐述了目前主要的氢损伤机制以及相关影响因素,归纳了氢与镍基高温合金材料微观缺陷(空位、位错、晶界等)相互作用的机理以及临氢环境下氢气对镍基高温合金力学性能的影响。研究表明,氢会导致镍基高温合金的延性下降,但对屈服强度和抗拉强度的影响相对较小。同时,氢对裂纹扩展行为也具有重要的影响,尤其在动态循环加载的条件下,氢加速了疲劳裂纹的扩展。然而,在高温高压条件下,氢致损伤机理的研究以及材料性能的测试仍存在诸多挑战,亟待进一步深入研究和开发专用设备。因此,未来的工作应致力于探索多种机制的协同作用,建立适应高温高压环境下材料性能测试的新标准,以更准确地评估镍基高温合金在掺氢/纯氢燃气轮机等实际工程中的应用前景和安全性能。

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	李丛
	赵雷
	徐连勇
	韩永典
	郝康达

关键词: 燃气轮机氢能镍基高温合金氢致损伤

Abstract: Amidst the global shift towards low-carbon energy structures, hydrogen energy has emerged as a prominent clean and renewable energy source, garnering increased attention. The utilization of hydrogen-doped or pure hydrogen gas turbines represents a crucial advancement in energy conversion technology, facilitating the widespread adoption of hydrogen energy on a large scale. However, the utilization of gas turbines in hydrogen-rich environments presents significant challenges due to the potential for hydrogen-induced damage, thereby constraining their long-term operational stability. Drawing upon extensive research findings from both domestic and international sources, this paper delineates the principal mechanisms underlying hydrogen-induced damage and elucidates the pertinent influencing factors. Furthermore, it synthesizes the intricate interactions occurring at the microscopic level between hydrogen and nickel-based superalloys, encompassing phenomena such as vacancies, dislocations, and grain boundaries. Research has evidenced that the presence of hydrogen canreduce in the ductility of nickel-based superalloys, although its impact on yield strength and tensile strength appears relatively marginal. Concurrently, hydrogen exerts a notable influence on crack propagation behavior, particularly under conditions of dynamic cyclic loading, whereby it expedites fatigue crack growth rates. Nevertheless, investigating the mechanisms of hydrogen-induced damage and material properties under elevated temperature and pressure poses significant challenges, necessitating further research and advancements in experimental apparatus. Hence, future endeavors should prioritize elucidating the synergistic interplay of multiple mechanisms to establish a novel standard for assessing material performance in high-temperature, high-pressure environments. Such efforts aim to more precisely evaluate the potential applications and safety characteristics of nickel-based superalloys in practical endeavors, such as hydrogen-doped/pure hydrogen gas turbine systems.

Key words: gas turbine hydrogen energy nickel-base superalloy hydrogen damage

出版日期: 2025-05-10 发布日期: 2025-04-28

ZTFLH:

TG174

基金资助: 国家自然科学基金(52375371)

通讯作者: ^*赵雷,天津大学材料科学与工程学院教授、博士研究生导师。目前主要从事先进材料的高性能焊接;面向火电、核电、航空、航天、深海等领域重大装备,解决蠕变、疲劳、腐蚀、氧化、临氢等环境下焊接结构的性能评价、损伤评估与寿命预测;以及先进材料的增材制造以及使役性能评价。zhaolei85@tju.edu.cn

作者简介: 李丛,2020年6月、2023年6月分别于南昌大学和天津大学获得工学学士学位和工学硕士学位。目前主要研究领域为高温以及临氢环境下材料的损伤行为及相关部件的安全完整性评估。

引用本文:

李丛, 赵雷, 徐连勇, 韩永典, 郝康达. 掺氢/纯氢环境下燃气轮机的氢致损伤研究进展[J]. 材料导报, 2025, 39(9): 24040126-10.
LI Cong, ZHAO Lei, XU Lianyong, HAN Yongdian, HAO Kangda. Research Advances in Hydrogen Induced Damage of Gas Turbines in Hydrogen-containing/Pure-hydrogen Circumstances. Materials Reports, 2025, 39(9): 24040126-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24040126 或 https://www.mater-rep.com/CN/Y2025/V39/I9/24040126

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