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材料导报  2024, Vol. 38 Issue (6): 22080204-7    https://doi.org/10.11896/cldb.22080204
  高分子与聚合物基复合材料 |
含过氧键化合物在土壤及地下水PAHs污染修复中的应用进展
韩跃鸣1, 代朝猛1,*, 段艳平2, 刘曙光1, 张亚雷3
1 同济大学土木工程学院,上海 200092
2 上海师范大学环境与地理科学学院,上海 200233
3 同济大学环境科学与工程学院,上海 200092
Application Progress of Peroxybond Compounds in Remediation of PAHs Pollution in Soil and Groundwater
HAN Yueming1, DAI Chaomeng1,*, DUAN Yanping2, LIU Shuguang1, ZHANG Yalei3
1 College of Civil Engineering, Tongji University, Shanghai 200092, China
2 School of Environmental and Geographical Sciences, Shanghai Normal University, Shanghai 200233, China
3 School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
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摘要 土壤及地下水中多环芳烃(PAHs)污染的修复治理是当前亟需解决的问题,其中基于含过氧键化合物的高级氧化技术由于对土壤及地下水中PAHs具有高效的降解能力,在近年来受到越来越多的关注。本文重点总结了过氧化氢、过硫酸盐以及过氧乙酸在土壤及地下水中PAHs污染修复方面的研究,从过氧键断裂产生自由基的角度讨论了其活化机制与降解机理,探究了过氧乙酸在土壤及地下水中PAHs污染修复中的应用前景,分析了影响修复效率的主要外部因素。总体来看,不同活化方式所产生的自由基种类有所不同,对PAHs污染的修复效果也有所差异,与此同时,土壤及地下水复杂环境因素对修复效果有着重要的影响。因此在未来的研究中应开发新型活化材料,提高修复效果并降低二次污染,同时需针对不同的土壤及地下水环境选择合适的活化方式,采用表面活性剂增强氧化剂的修复范围,在过氧乙酸修复PAHs污染方面开展更深入的研究。含过氧键化合物修复PAHs污染土壤及地下水是一个值得深入研究的领域,未来具有广阔的应用前景,本综述为此提供了理论基础。
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韩跃鸣
代朝猛
段艳平
刘曙光
张亚雷
关键词:  高级氧化技术(AOPs)  过氧键  多环芳烃(PAHs)  土壤及地下水    
Abstract: The remediation and treatment of soil and groundwater contaminated by polycyclic aromatic hydrocarbons (PAHs) is an urgent task that remains to be accomplished. The advanced oxidation technology based on peroxobond compounds has attracted constant attention because of its high efficiency in degrading PAHs in soil and groundwater. This study reviews the research on the application of hydrogen peroxide, persulfate and peracetic acid in remediating PAHs-contaminated soil and groundwater. We discuss the activation and degradation mechanisms from the perspective of free radicals generated by peroxybond breakage, explore the application prospect of peracetic acid in remediating PAHs-polluted soil and groundwater, and analyze the main external factors affecting the remediation efficiency. It is found that the types of free radicals produced vary based on different activation methods, so does their effect on PAHs pollution remediation. Moreover, the remediation effect is affected greatly by the complex environments of soil and groundwater. Therefore, in future research, new activation materials should be developed to improve the remediation effect and reduce secondary pollution. In addition, appropriate activation methods should be chosen based on the specific soil and groundwater environments, and surfactants should be used to expand the remediation range of oxidants. For that, more in-depth studies should be carried out on the remediation of PAHs pollution by peracetic acid. The remediation of PAHs-contaminated soil and groundwater by peroxybond compounds is a fruitful ground for continuing studies and a technology with broad and bright application prospect. This review provides a theoretical basis for such studies.
Key words:  advanced oxidation technologies (AOPs)    peroxy bond    polycyclic aromatic hydrocarbons (PAHs)    soil and groundwater
出版日期:  2024-03-25      发布日期:  2024-04-07
ZTFLH:  X53  
基金资助: 国家重点研发计划 (2019YFE0114900);国家自然科学基金(42077175);上海市“科技创新行动计划”(19230742400;19ZR1459300)
通讯作者:  *代朝猛,同济大学土木工程学院研究员、博士研究生导师。2011年同济大学环境工程专业博士毕业。主要研究方向为地下水安全保障理论与技术、地下水中污染物迁移转化规律及模拟、新型环境功能材料在地下水安全修复中的应用。在国内外核心期刊上发表论文90余篇,其中SCI收录60余篇(第一作者/通信作者39篇),ESI高被引3篇,总引次2 000余次,H指数26,单篇最高他引190余次。   
作者简介:  韩跃鸣,2017年6月、2020年6月分别于三峡大学和郑州大学获得工学学士学位和硕士学位。现为同济大学土木工程学院博士研究生,在代朝猛研究员的指导下进行研究。目前主要研究领域为土壤及地下水中PAHs污染修复。
引用本文:    
韩跃鸣, 代朝猛, 段艳平, 刘曙光, 张亚雷. 含过氧键化合物在土壤及地下水PAHs污染修复中的应用进展[J]. 材料导报, 2024, 38(6): 22080204-7.
HAN Yueming, DAI Chaomeng, DUAN Yanping, LIU Shuguang, ZHANG Yalei. Application Progress of Peroxybond Compounds in Remediation of PAHs Pollution in Soil and Groundwater. Materials Reports, 2024, 38(6): 22080204-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.22080204  或          https://www.mater-rep.com/CN/Y2024/V38/I6/22080204
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