POLYMERS AND POLYMER MATRIX COMPOSITES |
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Sulfate Attack Resistance of Graphene Oxide Reinforced Geopolymer |
FAN Jinyuan1, LI Maosen1, DUAN Ping1,*, CHEN Wei2, ZHANG Zuhua3
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1 Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China 2 State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China 3 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China |
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Abstract This work aims to investigate the effect of graphene oxide (GO) on the sulfate attack of geopolymers. Geopolymers were prepared from metakaolin (MK) and graphene oxide (GO) by alkali activation. Mechanical property and microstructure of the GO-reinforced geopolymers after sulfate attack were analyzed by using compressive strength test, scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and infrared spectroscopy analysis (FTIR) to evaluate its durability. The results show that GO improves compressive strength. The sample with 0.1wt% of GO exhibits the highest compressive strength, which reaches 73.07 MPa at 7 d of sulfate exposure. GO increases the compactness of geopolymers, effectively reduces the ingress of harmful substances, and improves early-age sulfate attack resistance. The compressive strength of the sample with 7—14 d of sulfate exposure decreases by only 5.5%. GO accelerates geopolymerization process and hydration rate, and promotes nucleation crystallization of albite and flusston in geopolymer gel.
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Published:
Online: 2023-07-10
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Fund:Key Research and Development Program of Hubei Province (2020BAB065), and Key Research and Development Program of Jiangxi Province (20201BBG71011). |
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