等离子体技术应用于碳载体改性及铂基催化剂制备的研究进展

doi:10.11896/cldb.21030319

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Abstract Platinum (Pt) is still an irreplaceable main catalyst for fuel cells due to its high catalytic activity. However, platinum's high cost and low reserves hinder the commercialization of fuel cells. In order to reduce the amount of Pt metal and increase its catalytic activity, it is often loaded with carbon carriers to enhance Pt dispersion and reduce Pt particle size. Lots of studies have confirmed that the modification of carbon carriers can enhance the activity of catalysts. Plasma has been widely used in the modification of carbon carriers and preparation of catalysts due to its green and fast advantages, and has currently become a research hot spot.
In the process of modifying carbon carriers and preparing platinum-based catalysts by plasma, the plasma treatment conditions affect surface modification structure, Pt particle size distribution, morphology and performance of materials. Therefore, it is necessary to find out the optimum synthesis conditions of different carbon carriers according to the action mechanism of plasma, to achieve precise control of modified structure, finally to provide effective anchor points for the loading of Pt nanoparticles and improve Pt catalytic activity. Preparation of platinum-based catalysts by plasma also requires in-depth analysis of the nucleation and growth mechanism of Pt nanoparticles, and exploration of controllable synthesis process conditions to achieve large-scale and controllable preparation of platinum-based catalysts. At the same time, the modification of carbon carriers and the preparation of platinum-based catalysts by plasma are often two separate processes, which limits the development scale and industrialization of the group technology, so considering the collaborative realization of two processes will also be one of the future research directions.
In recent years, fruitful results have been achieved in the modification of carbon materials and preparation of platinum-based catalysts by plasma. In the field of carbon material modification, the surface modification of carbon black, carbon nanotubes, graphene, carbon nanofibers and other carbon materials have been realized. And the advantages of modified carbon materials in improving the dispersion and catalytic activity of Pt catalysts have been summarized. In addition, in the preparation of platinum-based catalysts, based on the advantages of plasma green and fast, scholars in related fields have explored a variety of plasma methods, such as plasma reduction, plasma decomposition, plasma deposition, etc. These methods can partially or completely replace the traditional chemical methods and avoid the extensive use of chemical reagents. Meanwhile, the structure and electrochemical performance of platinum-based catalysts prepared by plasma methods have been studied, which is of great significance for reducing the amount of Pt metal, improving the activity of Pt catalysts and promoting the commercialization of fuel cells.
This paper summarized the application research progress of plasma in the modification of carbon carriers materials and preparation of platinum-based catalysts. The advantages and existing problems of each research work were evaluated, and corresponding solutions were put forward. Finally, the prospect of plasma methods to simultaneously realize the modification of carbon carriers and large-scale controllable preparation of platinum-based catalysts was illustrated.

Key words： plasma carbon carrier modification platinum-based catalyst

Published: 28 December 2022 Online: 2023-01-03

CLC number:	TB33
	TB34
	O539

Fund:National Natural Science Foundation of China (51676103, 52176076), Taishan Scholar Project of Shandong Province (ts20190937) and Graduates' Independent Research and Innovation Project of Qingdao University of Science and Technology(B2022KY006).

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	ZHANG Da
	ZHANG Chuanqi
	LI Shaolong
	HE Yan

Cite this article:

ZHANG Da,ZHANG Chuanqi,LI Shaolong, et al. Research Progress of Plasma Technology in the Modification of Carbon Carriers and Preparation of Platinum-based Catalysts[J]. Materials Reports, 2022, 36(24): 21030319-9.

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http://www.mater-rep.com/EN/10.11896/cldb.21030319 OR http://www.mater-rep.com/EN/Y2022/V36/I24/21030319

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