磷酸基功能化二氧化硅材料的制备、性能和应用

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (3503KB)
Export: BibTeX | EndNote (RIS)

Abstract In recent years, silica materials have great application value due to their low density, low toxicity, good biocompatibility, excellent chemical and thermal stability, and excellent morphology and structure controllability. Modifying it and introducing organic functional groups to prepare functionalized silica materials will help to further improve its performance and expand its scope of application. Because of its excellent performance and potential application value, functionalized silica materials have attracted the attention of many researchers, and phosphate-based functiona-lized silica materials are one of the research hotspots.
This article summarizes the research progress of phosphate-based functionalized silica materials, and introduces its preparation and application. The preparation method mainly includes phosphoric acid silane coupling method and post phosphorylation method. In phosphoric acid silane coupling method, based on the introduction of phosphoric silane, it is divided into post grafting method and copolycondensation method.The post grafting method is mainly through phosphoric silane to two modification of silicon oxide materials, forming Si-O-Si bonds on the surface of the material to introduce phosphoric acid groups. The copolycondensation method is mainly to hydrolyze and condense phosphoric silane and other silanes to form a silicon-oxygen silicon network to introduce phosphoric acid groups: post-phosphorylation based on the chemical bonds formed in the reaction, it is mainly divided into Si-O-P bonding method, C-P bonding method, and C-O-P bonding method. Among them, the Si-O-P bon-ding method uses phosphoric acid or phosphoric acid derivatives to affect silicon on the surface of silica materials. Hydroxyl modification introduces phosphoric acid groups by forming siloxyphosphorus bonds. The C-P bond method is mainly to perform Arbuzov reaction or Mannich reaction on functionalized silica to form C-P bond to introduce phosphoric acid groups. The C-O-P bond method mainly involves the modification of epoxy-functionalized silica with phosphating reagents, and the introduction of phosphoric acid groups in the form of C-O-P bonds through epoxy ring opening reaction. With the excellent complexing ability of phosphoric acid groups, sufficient acidic sites, excellent proton self-detachment ability, good biological activity and excellent performance of silica itself, phosphoric acid-based functionalized silica materials have excellent performance and broad application value in adsorption, catalysis, electrical conductivity and biomedicine. Finally, we looke forward to the future development of phosphate-based functionalized silica materials.

Key words： phosphate-based functional silica

Published: 16 July 2021

CLC number:

TB332

About author:: Bo Lyu, graduated from Ji'nan University in June 2018 with a bachelor of science degree. He is currently a graduate student in the School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, conducting research under the guidance of Associate Professor Chen Lianxi. At present, the main research field is organic-inorganic hybrid materials.Lianxi Chen, an associate professor and postgraduate tutor in the School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology. He graduated from the Department of Chemistry of Wuhan University in July 1985, and graduated from the Department of Chemistry of Wuhan University in 1988. From 1988 to this year, he worked in the Hubei Provincial Institute of Chemistry, Chinese University of Hong Kong, Wuhan University of Technology Biomaterials, Engineering Research Center and the department of chemistry of Wuhan University of Technology. He has been engaged in chemistry and chemical engineering research for nearly 30 years and has rich experience in theoretical and applied research. He has successively engaged in the research of agricultural chemicals, natural products and drugs, functional polymer materials and organic-inorganic hybrid materials. He has had many years of cooperative relations with enterprises in Guangdong Province and has served as the Guangdong Science and Technology Commissioner twice. Presided over and participated in many scientific research projects including National Science and Technology Research Projects, National Natural Science Foundation of China, Provincial and Ministerial Science and Technology Projects, Military Industry Projects, etc., and published more than 60 articles, of which more than 20 articles were included by SCI and EI, and won the scientific and technological progress of Hubei Province the third prize once and nearly ten patents were authorized.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LYU Bo
	CHEN Lianxi

Cite this article:

LYU Bo,CHEN Lianxi. Preparation, Performance and Application of Phosphate-based Functionalized Silica Material[J]. Materials Reports, 2021, 35(Z1): 143-150.

URL:

http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/143

1 Han L, Ruan J, Li Y S, et al.Chemistry of Materials, 2007, 19, 2860.
2 Wang X, Wang P, Jiang Y, et al. Composites Science and Technology, 2014, 104,1.
3 Xu W, Gao Q, Xu Y, et al. Journal of Solid State Chemistry, 2008, 181, 2837.
4 Yang Y, Liu J, Li X B, et al.Chemistry of Materials, 2011, 23, 3676.
5 Zhu Y F, Fang Y, Borchardt L, et al. Microporous and Mesoporous Materials, 2011, 141, 199.
6 Shen Q H, Liu M, Yu D D, et al. Journal of the Chinese Chemical Society, 2018, 65, 591.
7 Antochshuk V, Olkhovyk O, Jaroniec M, et al.Langmuir, 2003, 19, 3031.
8 Teng M M, Wang H T, Li F T, et al. Journal of Colloid and Interface Science, 2011, 355, 23.
9 Heidari A, Younesi H, Mehraban Z. Chemical Engineering Journal, 2009, 153, 70.
10 Benitez M, Das D, Ferreira R, et al. Chemistry of Materials, 2006, 18, 5597.
11 Bala T, Prasad B L, Sastry M, et al. Journal of Physical Chemistry A, 2007, 111, 6183.
12 Xu G, Zhao Y L, Hou L P, et al. Chemical Engineering Journal, 2017, 325, 533.
13 Illy N, Fache M, Menard R, et al. Polymer Chemistry, 2015, 6,6257.
14 韩帅元, 岳宝华, 严六明. 物理化学学报, 2014, 30 (1), 8.
15 Dai Q G, Zhang Z Y, Yan J R, et al. Journal of Environmental Science and Technology, 2018, 52, 13430.
16 Ravi S, Lee Y R, Yu K, et al. Microporous and Mesoporous Materials, 2018, 258, 62.
17 Weinberger C, Heckel T, Schnippering P, et al. Nanomaterials, 2019, 9, 249.
18 He G W, Nie L L, Han X, et al. Journal of Power Sources, 2014, 259, 203.
19 Encinas N, Angulo M, Astorga C, et al. Acta Biomaterialia, 2019, 84, 317.
20 陈凯玲, 赵蕴慧, 袁晓燕.化学进展, 2013, 25(1), 95.
21 刘健, 杨启华, 张磊, 等.化学进展, 2005, 17(5), 809.
22 Lee Y G, Park J H, Oh C,et al. Langmuir, 2007, 23(22), 10875.
23 Zhou L M, Zou H B, Wang Y, et al. Journal of Radioanalytical and Nuclear Chemistry, 2016, 310, 1155.
24 Wang Y L, Zhu L, Guo B L, et al. New Journal of Chemistry, 2014, 38, 3853.
25 Sarafraz H, Minuchehr A, Alahyarizadeh G, et al. Scientific Reports, 2017, 7, 11675.
26 Corriu R J P, Datas L, Guari Y, et al. Chemical Communications, 2001, 8, 763.
27 Wang P Y, Zhao L, Wu R A, et al. Journal of Physical Chemistry C, 2009, 113, 1359.
28 Gunathilake C, Kadanapitiye M S, Huang S D, et al. ACS Applied Materials & Interfaces, 2015, 7, 23144.
29 Billamboz M, Banaszak E. Journal of the Iranian Chemical Society, 2019, 16, 1029.
30 Wang Y, Wang H N, Meng X S, et al. Solar Energy Materials & Solar Cells, 2014, 130, 71.
31 Kovalchuk T V, Sflhi H, Korchev A S, et al. Journal of Physical Chemistry B, 2005, 109, 13948.
32 Gao Q, Xie J F, Shao Y T, et al. Chemical Engineering Journal, 2017, 313, 197.
33 Zheng S K, Feng J W, DiVerdi J A, et al. Inorganic Chemistry, 2006, 45, 6073.
34 Sobhani S, Falatooni Z M, Honarmand M. RSC Advances, 2014, 4, 15797.
35 Wei Y Q, Zhang L X, Shen L, et al. Journal of Molecular Liquids, 2016, 221, 1231.
36 Jin Y G,Qiao S Z, da Costa J C D, et al. Advanced Functional Materials, 2007, 17, 3304.
37 Kostenko L, Kobylinska N, Khainakov S, et al. Microchim Acta, 2019, 186, 474.
38 Yin P, Chen W, Liu W, et al. Bioresource Technology, 2013, 140, 146.
39 Chen C, Shen C H, Kong G J, et al. Materials Chemistry and Physics, 2013, 140, 24.
40 Zhao Y N, Jiang Z Y, Lin D S, et al. Journal of Power Sources, 2013, 224, 28.
41 Zhao Y N, Yang H, Wu H, et al. Journal of Membrane Science, 2014, 469, 418.
42 Yuan L Y, Liu Y L, Shi W Q, et al. Dalton Transactions, 2011, 40, 7446.
43 Okabe F, Mochizuki C, Takei T, et al. Journal of the Ceramic Society of Japan, 2017, 125, 732.
44 Fetisova Y S, Dudarko O A, Bauman M, et al. Journal of Sol-Gel Science and Technology, 2018, 88, 66.
45 Liu E X, Chen L, Dai J D, et al. Journal of Molecular Liquids, 2019, 277, 786.
46 Yang P P, Liu Q, Liu J Y, et al. Journal of Hazardous Materials, 2019, 363, 248.
47 Melnyk I V, Goncharyk V P, Kozhara L I, et al. Microporous and Mesoporous Materials, 2012, 153, 171.
48 Deka J R, Liu C L, Wang T H, et al. Journal of Hazardous Materials, 2014, 278, 539.
49 Kawi S, Shen S C, Chew P L. Journal of Materials Chemistry, 2002, 12, 1582.
50 Zhang D S, Wang R J, Yang X X, et al. Reaction Kinetics Mechanisms and Catalysis, 2010, 101,455.
51 Wang R, Li Y H. Catalysis Communications, 2010, 11, 705.
52 Xu S Q, Pan D H, Wu Y F, et al. Industrial & Engineering Chemistry Research, 2019, 58, 13013.
53 Jin Y G, Qiao S Z, Xu Z P, et al. Journal of Materials Chemistry, 2009, 19(16), 2363,
54 Jin Y G, Qiao S Z, Xu Z P, et al. Journal of Physical Chemistry, 2009, 113, 3157.
55 Lou L D, Pu H T. International Journal of Hydrogen Energy, 2011, 36, 3123.
56 何晓晓, 海罗, 王柯敏, 等. 高等学校化学学报, 2009, 30(2), 283.
57 Lu J, Liong M, Zink J I, et al. Small, 2007, 3(8), 1341.
58 Menon N, Leong D T. ACS Applied Materials & Interfaces, 2016, 8, 2416.
59 Liong M, Lu J, Zink J I. ACS Nano, 2008, 2(5), 889.
60 Mumin A M, Barrett J W, Zhang J. Journal of Colloid and Interface Science, 2011, 353, 156.