碳基非贵金属电催化剂研究进展

doi:10.11896/cldb.19110130

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Abstract The technologies of new type battery and electrolytic water have the advantages of clean, high conversion efficiency and so on, which the key is hydrogen evolution reaction (HER), oxygen reduction reaction (ORR) or oxygen evolution reaction (OER) that happened on anode or cathode. With the discovery of new carbon materials, their properties and applications in electrocatalytic oxidation or reduction reactions have attracted the attention. In addition, non-noble metals have developed rapidly in the field of new energy. The research and development of electroca-talyst materials have gone through initial single precious metal material to carbon composite with advantages of high utilization, high activity, strong toxicity resistance and low cost. All aspects of carbon composite electrocatalyst on performance, structure, cost, preparation technology and others have been significantly developed, which greatly promotes the possibility of application.
The key design of electrocatalyst is that increases the active site on catalyst surface and the movement of free electrons. The number of active sites on materials surface increases with the specific surface area, which can be controlled by the methods of changing the material shape, adjusting the particle size of material and preparing composite material. The movement of free electrons on the surface of material is improved by the structures of polycrystalline, core-shell and alloy. The new carbon materials such as graphene, carbon nanotube, porous carbon and others have the advantages of good stability, adjustable pore, high specific surface area, excellent conductivity, which are good composite matrix materials. The non-noble metals such as Fe, Co, Ni, Cu, Mo with high catalytic active, good stability, strong toxicity resistance and low coat can be sui-tably employed as catalytic active component. The non-noble metal is loaded onto the new carbon matrix materials, resulting in increasing the asymmetric density of electrons of carbon nano-materials or breaking electric neutrality on the surface of carbon, which the more adsorption active sites are produced, and the free movement of π electrons is improved on the surface of SP² hybridization carbon. Thus, the electron distribution and spatial structure of the composites are changed, which effectively improved the electrocatalytic activity of the composites.
This review firstly offers advances of the research efforts with respect to the carbon based non-noble metal electrocatalyst between China and abroad, on the base of this retrospection, then contrastive analyzes the carbon matrix materials and active component of carbon based non-noble metal electrocatalyst, finally, concludes the developing advantages and existing problems, and prospects the bright future.

Key words： carbon-based materials non-noble metal electrocatalysis active component catalytic performance

Published: 24 December 2020

CLC number:	TB34
	TB333

Fund:This work was financially supported by the National Natural Science Foundation of China (51604310), the Natural Science Foundation Program of Shaanxi Province (2017ZDJC-33,2019JLP-17), Innovation Capability Support Program of Shaanxi (2020TD-028) and Open Foundation of State Key Laboratory of Iron & Steel Industry Environmental Protection (YZC2019ky01).

About author:: Lei Wu received his M.S. degree in chemical technology from Xi’an University of Architecture and Technology in 2014. He engaged in chemical design from from2014 to 2017. He is currently pursuing his Ph.D. at Xi’an University of Architecture and Technology under the supervision of Prof. Jun Zhou. His research has focused on the preparation and optimization of carbon based non-noble metal catalyst.
Ben Peng received his Ph.D degree in metallurgical engineering from University of Science and Technology Beijing in 2016. He currently is secretary and deputy general manager of environmental protection department, Central Research Institute of Building and Construction, MCC Group, Co., Ltd. His research interests are industrial production, environmental protection and comprehensive utilization of resources.
Jun Zhou received his B.E. degree in chemical equipment and machinery from Northwest University in 1999. After he received his M.S. degree in physical chemistry in metallurgy from Xi’an University of Architecture and Technology, he became a college teacher in 2002, and he received his Ph.D. degree in materials science in 2013. His research interests are efficient green catalyst preparation. He has successively presided over several national and provincial projects, and published over 50 academic papers. He has won many awards in science and technology, such as Shaanxi province, the Nonferrous Metals Society of China, and China Industry-University-Research Institute Collaboration Association, etc.
^?These authors contributed equally to this work.

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	WU Lei
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Cite this article:

WU Lei,PENG Ben,ZHOU Jun, et al. Advances on Carbon-based Non-noble Metal Electrocatalyst[J]. Materials Reports, 2020, 34(23): 23009-23019.

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http://www.mater-rep.com/EN/10.11896/cldb.19110130 OR http://www.mater-rep.com/EN/Y2020/V34/I23/23009

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