黄铁矿型FeS<sub>2</sub>的制备及其储能应用

doi:10.11896/cldb.20080005

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Abstract Energy and environment are two important issues in today’s social development. With the depletion of fossil energy and the increasingly se-rious environmental pollution, it has become a consensus to search for clean alternative energy. New energy storage and conversion devices, such as secondary lithium/sodium batteries and supercapacitors, have become a research hotspot. Appropriate electrode materials are the key to improve electrochemical performance and realize industrialization. Pyrite iron disulfide(FeS₂) is a kind of transition metal sulfide with a high theoretical specific capacity, which exists in the form of pyrite in nature, with abundant reserves, wide distribution, environmental protection and non-toxic. FeS₂ has been widely applied in commercial high-energy Li-FeS₂ primary batteries and put into the market in large quantities at present. Moreover, FeS₂ shows great potential in secondary lithium/sodium batteries and supercapacitors, becoming the focus and hotspot of new energy industry research. The energy storage research of FeS₂ mainly includes two aspects: FeS₂ prepared by chemical synthesis methods and processing of natural FeS₂. However, the low conductivity of FeS₂ and poor stability during cycling are the urgent problems to be solved in the application of FeS₂ materials in energy storage. Nano design of FeS₂ is the main way to improve its electrochemical performance. In this paper, the crystal structure of FeS₂ is introduced, and the preparation methods of nanosized pyrite FeS₂ are briefly described, including the chemical synthesis of nanosized FeS₂ and the processing of natural pyrite. Besides, the energy storage mechanism and research progress of nanoscale FeS₂ in lithium/sodium batteries and supercapacitors are briefly reviewed.

Key words： pyrite iron disulfide hydrothermal/solvothermal method chemical vapor deposition method high temperature sulfuration hot injection natural pyrite lithium/sodium batteries supercapacitors

Published: 13 January 2022 Online: 2022-01-13

CLC number:

TQ152

Fund:This work was financially supported by the National Natural Science Foundation of China (51774016) and Peking University Open Test Foundation (0000012321).

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	LI Jianzhuo
	CHUAN Xiuyun
	YANG Yang
	LIU Fangfang
	QI Pengyue

Cite this article:

LI Jianzhuo,CHUAN Xiuyun,YANG Yang, et al. Synthesis and Energy Storage Application of Pyrite FeS₂[J]. Materials Reports, 2022, 36(1): 20080005-13.

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http://www.mater-rep.com/EN/10.11896/cldb.20080005 OR http://www.mater-rep.com/EN/Y2022/V36/I1/20080005

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