INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Advances in Catalyst Materials for the Hydrogen Peroxide Production by Electrocatalytic Oxygen Reduction |
LEI Jing1, CHEN Zixi1, LI Yizhao1,2,*, CAO Yali1,*
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1 Key Laboratory of Energy Materials Chemistry of Ministry of Education, Key Laboratory of Advanced Functional Materials(Autonomous Region), Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi 830046, China 2 College of Chemical Engineering, Xinjiang University, Urumqi 830046, China |
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Abstract H2O2 shows strong oxidizing properties and is widely used in papermaking, sewage treatment, and disinfection. The global demand for H2O2 is increasing, but the anthraquinone method for production of H2O2 is complicated, high cost, and low efficient. The direct hydrogen-oxygen synthesis is great safety risks. Therefore, electrocatalytic oxygen reduction reaction, as an emerging, green and safe in-situ synthesis of H2O2, has attracted widespread attention in recent years. Oxygen reduction reaction (ORR) is a multi-electron reaction, the intermediates are complex and difficult to measure, which makes it hard to study the mechanism. There are two competing reaction paths in ORR, two electron paths get H2O2, and four electron paths generate H2O. The efficiency of two-electron oxygen reduction reaction (2e- ORR) depends on the activity, selectivity, and stability of catalyst. At present, the noble metal catalysts, such as Au and Pd, show good performance in 2e- ORR to produce H2O2, but they are expensive and rare. Therefore, three strategies have been proposed. (Ⅰ) Decreasing the loading of noble metal. Integrating the inert metals with the active me-tals to obtain many high-performance alloy materials, such as Pt-Hg. (Ⅱ) Developing noble metal-free catalysts. The defects, surface oxygenic functional groups (C=O, C-O), heteroatom doping (N-, S-) and transition metal doping (Co, Fe) in carbon-based catalysts can all improve the selectivity and catalytic activity towards H2O2. (Ⅲ) Developing non-noble metal composite catalysts. Non-noble metal composite catalysts (such as MnO2/C, CoS2/C) can promote electron transfer and improve H2O2 selectivity. Herein, the mechanism and test methods of 2e- ORR are systematically introduced. The catalysts included noble metal-based catalysts, carbon-based catalysts, and non-noble metal composite catalysts in 2e- ORR for generation of H2O2 in the recent years are summarized. The outlook of future research directions of electrochemical generation of hydrogen peroxide is also suggested.
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Published: 31 May 2021
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Fund:National Natural Science Foundation of China (21766036), Natural Science Foundation of Xinjiang Uygur Autonomous Region (2017D01C076). |
About author:: Jing Lei received her bachelor of science degree from Xinjiang University in June 2019. She is currently a postgraduate student in the College of Chemistry, Xinjiang University, and conducting research under the guidance of professor Yali Cao and associate professor Yizhao Li. Her research has focused on electrocatalytic oxygen reduction reaction. Yizhao Li received his M.S. and Ph.D. degrees in Chemical Engineering and Technology from Xinjiang University in 2012 and 2015, respectively. In 2017, he became a associate professor at Xinjiang University. His research interests include nanomaterials and catalysis. Yali Cao received her Ph.D. degree in material science and engineering from Xi'an Jiaotong University in 2009. In 2013, she became a professor at Xinjiang University. Her research interests include nanomaterials and catalysis. |
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