POLYMERS AND POLYMER MATRIX COMPOSITES |
|
|
|
|
|
Research Progress on the Preparation of Nanomaterials and MesoporousMaterials Using Gemini Surfactants |
BAO Yan, LIU Pan, GUO Jiajia
|
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021 |
|
|
Abstract The special structure of nanomaterials determines their large specific surface area and high surface activity. They are widely used in mecha-nics, thermals, optics and electromagnetism. It is a common method to prepare nanomaterials by using micelles and emulsions formed by surfactants as a template. This method can greatly reduce the surface tension of the solvent and change the interface composition and structure, which has attracted the researchers' attention. Ordered mesoporous materials have regularly adjustable nanoscale pores, so they can be used as adsorbents, catalysts, catalyst supports or templates. Using the aggregates self-assembled by surfactant molecules as template to synthesis the ordered mesoporous materials, the process is more simple and the channel distribution is more uniform. Therefore, this method become very po-pular. However, traditional single-chain surfactants are commonly used as template in the preparation of nanomaterials and mesoporous materials. The as-prepared nanomaterials and mesoporous materials have many defects, such as single appearance and difficulty in controlling structure, due to the single structure of traditional single-chain surfactants. Gemini surfactants have special micellar self-assembly behavior, high surface activity and adjustablity of the composition of hydrophobic chain and spacer. Thus, the preparation of nanomaterial and mesoporous materials with good dispersion and unique morphologies can be realized using gemini surfactants as dispersing agent and template. In this paper, the preparation of nanomaterials using gemini surfactants as template or microreactor was reviewed, from the perspective of various ordered aggregates of gemini surfactants in the solution, such as micelles (reverse micelles), vesicles and liquid crystals. And the progress of the preparation of nanomaterials with gemini surfactants as stabilizers was overviewed. Then, the influence of structural parameters of gemini surfactants on the morphology of mesoporous materials was summarized. Finally, some perspectives on the future research of nanomaterials and mesoporous materials prepared by gemini surfactants were put forward.
|
Published: 12 September 2019
|
|
Fund:This work was financially supported by National Natural Science Foundation of China (21878181), Science and Technology Program of Xi'an City (201805023YD1CG7(2)) |
About author:: Yan Bao received her Ph.D degree in leather chemistry and engineeringfrom Shaanxi University of Science and Technology in 2008. Her research interests are organic/inorganic nanocomposite functional chemicals and the synthesis of green leather chemicals and the role of collagen fibers. She has published more than 80 papers in recent years (including 30 articles by SCI). |
|
|
1 Seybolt, Sheila E J.Schizophrenia Research, 2014, 160 (1-3),222. 2 Jr B M, Moronne M, Gin P, et al. Science, 2013, 281(5385),2013. 3 Maynar A D. Nature, 2011, 475 (7354),31. 4 Malgars V, Ji Q, Kamamchi Y, et al. Bulletin of the Chemical Society of Japan, 2015, 88(9),1171. 5 Hsueh H Y, Yao C T, Ho R M. Chemical Society Reviews, 2015, 44 (7),1974. 6 Zhao T, Xin L, Li Y, et al. Journal of Colloid & Interface Science, 2016, 490,436. 7 Zhang X, Li Y, Cai Y, et al. Science of Advanced Materials, 2017, 490, 436. 8 Zhai L, Zhang J, Li X K, et al.Journal of Inorganic Materials, 2016, 31(6),588. 9 Yu X J. Synthesis, characterization and formation mechanism of mesoporous molybdenum and tungsten oxides based on gemini surfactants.Ph.D. Thesis,Shandong University, China, 2009(in Chinese). 于小娟. 基于Gemini表面活性剂的介孔钼、钨氧化物材料的制备、表征及机理研究.博士学位论文,山东大学, 2009. 10 Nandiyanto A B D, Kim S G, Iskandar F, et al. Microporous & Mesoporous Materials, 2009, 120 (3),447. 11 Bao Yan, Guo Jiajia, Ma Jianzhong, et al. Journal of Industrial & Engineering Chemistry, 2017, 53,51. 12 Wang Xiaoqin, Tong Debin, Peng Yufeng,et al. Chongqing University of Technology (Natural Science),2019, 33(3),150(in Chinese). 汪晓琴,童德彬,彭玉凤,等.重庆理工大学学报(自然科学),2019, 33(3),150. 13 Cheng Fa, Wang Jun, Zhu Sen. Fine Chemicals, 2005,22 (4),261(in Chinese). 程发,王军,朱森.精细化工,2005,22(4),261. 14 Alargova R G, Kochijashky I I. Sierra M L, et al. Journal of Colloid and Interface Science, 2001, 235, 119. 15 Zhu Deyu, Cheng Fa, Chen Yu, et al.Colloids and Surfaces A: Physicochem Engeering Aspects, 2012, 397,1. 16 Peng Zhongli, Wu Qing, Cai Tao,et al.Colloids and Surfaces A: Physicochem and Engeering Aspects, 2009, 342,127. 17 Brown G H. CRC Critical Reviews in Solid State Sciences, 1970, 1(3), 303. 18 Bangham A D, Standdish M M, et al.Journal of Molecular Biology, 1965, 13,328. 19 Kaler E W, KamalakaraM A, Rodiguez B E, et al.Science, 1989, 245,4924. 20 Xu Jian, Han Xia, Zhou Lihui, et al. The Chinese Journal of Process Engineering, 2006, 6 (2),323(in Chinese). 徐建,韩霞,周丽绘,等.过程工程学报, 2006, 6(2),323. 21 Xu F, Hou H, Gao Z. Chemphyschem A European Journal of Chemical Physics & Physical Chemistry, 2014, 15 (18),3979. 22 Sau T K, Murphy C J.Journal of American Chemical Society, 2004, 126,8648. 23 Gomezgrana S, Hububert F, Testard F, et al. Langmuir the ACS Journal of Surfaces & Colloids, 2012, 28 (2),1453. 24 Alami E, Levy H, Zana R, et al. Langmuir, 1993, 9 (4),940. 25 Oda R, Hue I, Candau S J. ChemCommun, 1997, (21),2105. 26 Bakshi M S, Sharma P, Banipal T S. Materials Letters, 2007, 61 (28),5004. 27 Li M, Zhang C, Yang X L, et al.RSC Advances,2013, 3(37),16304. 28 Li Bing, Zhang Qi, Xia Yan, et al. Colloids and Surfaces A: Physicochem and Engeenring Aspects, 2015, 470,211. 29 Wang Guoyong, Li Xiang, Du Zhiping, et al. Journal of Molecular Li-quids, 2014, 197,197. 30 Lawrence M J.European Journal of Drug Metabolism & Pharmacokinetics, 1994, 19 (3),257. 31 Wang W, Han Y, Tian M, et al.ACS Applied Materials & Interfaces, 2013, 5 (12),5709. 32 Murawska M, Wiatr M, Nowakowski P, et al. Radiation Physics & Che-mistry, 2013, 93 (93),160. 33 Anne B G, Raoul Z A, Yeshayahu T. Journal of Physical Chemistry B, 2000, 104 (17),4005. 34 Beaun P V, Stupp S I. Materials Research Bulletin, 1999, 34 (3),463. 35 Chang W, Shen Y, Xie A, et al. Applied Surface Science, 2010, 256 (13),4292. 36 Bskshi M S, Possmayer F, Petersen N O. Journal of Physical Chemistry C, 2008, 112 (22),8259. 37 Song W W, Li N B, Luo H Q. Analytical Biochemistry, 2012, 422 (422),1. 38 Xu Jian, Zhou Lihui, Liu Honglai, et al. Journal of Experimental Nanoscience, 2006, 1 (1),103. 39 Liu D, Li M, Cheng M. Journal of Jiamusi University, 2005, 23(3), 451. 40 Xu J, Han X, Liu H, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2006, 273 (1-3),179. 41 Weng B, Shepherd R, Chen J, et al. Journal of Materials Chemistry, 2010, 21(6),1918. 42 Chen Q, Sakamoto Y, Terasaki O, et al.Microporous & Mesoporous Materials, 2007, 105(1),24. 43 Chen L, Shang Y, Liu H, et al. Materials & Design, 2010, 31 (4),1661. 44 Liu Y, Yu L, Zhang S, et al.Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2010, 359 (1-3),66. 45 Li D, Fang W, Wang H, et al.Industrial & Engineering Chemistry Research, 2013, 52 (24),8109. 46 Kuo C F J, Dong M Y.Journal of Surfactants and Detergents, 2012, 15 (4),471. 47 Fereidooni M T, Azizian S, Wetting S. Journal of Colloid & Interface Science, 2017, 486,204. 48 Negm N A, Mohamed D E, et al. Journal of Industrial & Engineering Chemistry, 2014, 24,34. 49 He S, Chen H, Guo Z, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2013, 429 (10),98. 50 Siddiq A M, Parandhaman T, Begam A F, et al. Enzyme & Microbial Technology, 2016, 95,118. 51 Feng J, Wu S, Wang H, et al.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2017,516, 94. 52 Huo Q S, Leon R, Petroff P M. et al.Science,1995, 268,13224. 53 Xu J, Han S, Hou W, et al. Colloids & Surfaces A: Physicochemical and Engineering Aspects, 2004, 248 (1-3),75. 54 Han S, Hou W, Xu J, et al.ChemPhysChem, 2006, 7 (2),394. 55 Lyu Y, Seung H Y, Jeong K S, et al.Journal of the American Chemical Society, 2004, 126 (8),2310. 56 Voort V D, Mathieu M, Mees F, et al. Journal of Physical Chemistry B,1998, 102,8847. 57 Kang H, Jun Y, Park J, et al. Cheminform, 2000, 12,3530. 58 Chen S,Wu D, Song C, et al. Materials Review A:Review Papers, 2013, 27(8),47. 陈思,吴东清,宋春芃,等. 材料导报:综述篇, 2013, 27(8), 47. 59 Chen Q R, Sakamoto Y, Terasaki O, et al. Microporous and Microporous Materials, 2007, 105 (1-2), 24. 60 Liang Y, Hanzlik M, Anwander R.Journal of Materials Chemistry, 2005, 15 (35-36),3919. |
|
|
|