利用双子表面活性剂辅助制备纳米材料和介孔材料的研究进展

doi:10.11896/cldb.18050316

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Abstract The special structure of nanomaterials determines their large specific surface area and high surface activity. They are widely used in mecha-nics, thermals, optics and electromagnetism. It is a common method to prepare nanomaterials by using micelles and emulsions formed by surfactants as a template. This method can greatly reduce the surface tension of the solvent and change the interface composition and structure, which has attracted the researchers' attention. Ordered mesoporous materials have regularly adjustable nanoscale pores, so they can be used as adsorbents, catalysts, catalyst supports or templates. Using the aggregates self-assembled by surfactant molecules as template to synthesis the ordered mesoporous materials, the process is more simple and the channel distribution is more uniform. Therefore, this method become very po-pular. However, traditional single-chain surfactants are commonly used as template in the preparation of nanomaterials and mesoporous materials. The as-prepared nanomaterials and mesoporous materials have many defects, such as single appearance and difficulty in controlling structure, due to the single structure of traditional single-chain surfactants.
Gemini surfactants have special micellar self-assembly behavior, high surface activity and adjustablity of the composition of hydrophobic chain and spacer. Thus, the preparation of nanomaterial and mesoporous materials with good dispersion and unique morphologies can be realized using gemini surfactants as dispersing agent and template. In this paper, the preparation of nanomaterials using gemini surfactants as template or microreactor was reviewed, from the perspective of various ordered aggregates of gemini surfactants in the solution, such as micelles (reverse micelles), vesicles and liquid crystals. And the progress of the preparation of nanomaterials with gemini surfactants as stabilizers was overviewed. Then, the influence of structural parameters of gemini surfactants on the morphology of mesoporous materials was summarized. Finally, some perspectives on the future research of nanomaterials and mesoporous materials prepared by gemini surfactants were put forward.

Key words： gemini surfactant template stabilizer nanomaterials mesoporous materials

Published: 12 September 2019

CLC number:

TQ314

Fund:This work was financially supported by National Natural Science Foundation of China (21878181), Science and Technology Program of Xi'an City (201805023YD1CG7(2))

About author:: Yan Bao received her Ph.D degree in leather chemistry and engineeringfrom Shaanxi University of Science and Technology in 2008. Her research interests are organic/inorganic nanocomposite functional chemicals and the synthesis of green leather chemicals and the role of collagen fibers. She has published more than 80 papers in recent years (including 30 articles by SCI).

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Cite this article:

BAO Yan,LIU Pan,GUO Jiajia. Research Progress on the Preparation of Nanomaterials and MesoporousMaterials Using Gemini Surfactants[J]. Materials Reports, 2019, 33(21): 3678-3685.

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http://www.mater-rep.com/EN/10.11896/cldb.18050316 OR http://www.mater-rep.com/EN/Y2019/V33/I21/3678

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