过渡金属氧化物非均相催化过硫酸氢盐(PMS)活化及氧化降解水中污染物的研究进展

doi:10.11896/j.issn.1005-023X.2018.13.013

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1353KB)
Export: BibTeX | EndNote (RIS)

Abstract In recent years, the enrichment of refractory pollutants in water has caused numerous environmental issues, which cannot be treated effectively by traditional water treatment process. Advanced oxidation techniques are recognized to be the most effective method to degrade refractory pollutants. An emerging advanced oxidation technique based on sulfate radical (SO₄^-·) generated from activating PMS catalyzed by heterogeneous catalysts (transition metal oxide) has been developed to degrade the refractory pollutants in wastewater. Compared with traditional advanced oxidation technique, the new technique features wider adaptability range of pH, stronger oxidizability under neutral conditions and longer half-life of free radicals. Besides, it overcomes the secondary pollution problem of metal ions in homogeneous catalytic system as well as their difficulty in recycling. This newly developed advanced oxidation technique has been drawn tremendous attention from scholars of environmental fields and are expected to provides new ideas and methods for removing refractory water pollutants like antibiotics and hormones etc. Nevertheless, due to the reduction of active sites, heterogeneous catalysis presents lower catalytic efficiency than that of homogeneous catalysis, with poor catalytic stability and poor recyclability as well. This urges intensive research endeavors to seek new transition metal oxide catalysts and modify existing catalysts for PMS activation, aiming at improving catalytic efficiency and recyclability of catalysts while exploiting economic and environmental advantages of heterogeneous catalysis. Impressive strides have been made in researches of heterogeneous transition metals for PMS activation in recent years, which greatly contribute to its practical application. In many transition metals, the oxides of cobalt, iron, and manganese have been proved to have catalytic activity on PMS activation. Cobalt oxides were studied first since cobalt ions show the strongest activation ability for PMS. Subsequently, the oxides of iron and manganese have gradually become the substitutes for cobalt oxides due to their environmental friendliness and cheapness. Research works in the past five years have established new methods to overcome the bottleneck of low catalytic efficiency and poor catalytic stability, which introduce various new materials like nanostructured carbon, mesoporous materials, metal organic frameworks in the preparation of catalysts to modify the transition metals oxides and result in an increased electron transfer speed and an enhanced chemical stability. Moreover, researchers also have demonstrated that binary composite materials containning two transition metal catalytic cores exhibit improvements in both catalytic efficiency and stability. The research progress and synthesis of Co-based, Mn-based and Fe-based monobasic catalysts are introduced in this article. The present researches of binary composite catalysts are reviewed. Finally, the current existing shortcomings and the prospects of this newly developed technique are discussed. There are reasons to believe that heterogeneous catalysis of PMS activation by transition metal oxide has a bright future in degradation of refractory pollutants in wastewater.

Key words： advanced oxidation technique heterogeneous catalysis transition metal oxide peroxymonosulfate (PMS) water pollution degradation

Published: 01 August 2018

CLC number:

X52

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LI Chenxu
	PENG Wei
	FANG Zhendong
	LIU Jie

Cite this article:

LI Chenxu,PENG Wei,FANG Zhendong, et al. Water Pollutants Oxidation Degradation Through the Activation ofPeroxymonosulfate (PMS) Heterogeneously Catalyzedby Transition Metal Oxide: a Review[J]. Materials Reports, 2018, 32(13): 2223-2229.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.13.013 OR http://www.mater-rep.com/EN/Y2018/V32/I13/2223

1 Glaze W H, Kang J W, Chapin D H. The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation[J].Ozone-science & Engineering,1987,9(4):335.
2 Guo X. Advanced treatment of papermaking wastewater by sulfate radical-based advanced oxidation process[D].Guangzhou: South China University of Technology,2013(in Chinese).
郭鑫.基于硫酸根自由基的高级氧化法深度处理造纸废水的研究[D].广州:华南理工大学,2013.
3 Ghanbari F, Moradi F. Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review[J].Chemical Engineering Journal,2017,310:41.
4 Chen X Y, Xu Z Y, Wu D, et al. The advanced oxidation technology based on sulfate radical and application in water treatment[J].Technology of Water Treatment,2009,35(5):16(in Chinese).
陈晓旸,薛智勇,吴丹,等.基于硫酸自由基的高级氧化技术及其在水处理中的应用[J].水处理技术,2009,35(5):16.
5 Hussain H, Green I, Ahmed I. Journey describing applications of PMS in synthetic chemistry[J].Chemical Reviews,2013,113:3329.
6 Stanislaw W, Holger V, Klaudiusz G. Chemistry of persulfates in water and wastewater treatment: A review[J].Chemical Engineering Journal,2017,330:44.
7 Anipsitakis G P, Dionysiou D D. Radical generation by the interaction of transition metals with common oxidants[J].Environmental Science & Technology,2004,38(13):3705.
8 Han Q, Yang S Y, Yang X. Cobalt catalyzed peroxymonosulfate oxidation: A review of mechanisms and applications on degradating organic pollutants in water[J].Progress in Chemistry,2012,24(1):145(in Chinese).
韩强,杨世迎,杨鑫.钴催化过一硫酸氢盐降解水中有机污染物机理及应用研究[J].化学进展,2012,24(1):145.
9 Anipsitakis G P, Dionysiou D D. Heterogeneous activation of oxone using Co₃O₄[J].The Journal of Physical Chemistry B,2005,109(27):13052.
10 Wang Y, Zhou L, Duan X, et al. Photochemical degradation of phenol solutions on Co₃O₄ nanorods with sulfate radicals[J].Catalysis Today,2015,258:576.
11 Deng J, Feng S F, Zhang K, et al. Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co₃O₄ for the degradation of chloramphenicol at neutral pH[J].Chemical Engineering Journal,2016,308:505.
12 Anbia M, Rezaie M. Synthesis of supported ruthenium catalyst for phenol degradation in the presence of peroxymonosulfate[J].Water, Air, & Soil Pollution,2016,227(9):349.
13 Qi F, Chu W, Xu B, Catalytic degradation of caffeine in aqueous solutions by cobalt-MCM41 activation of peroxymonosulfate[J].Applied Catalysis B: Environmental,2013,s134-135(9):324.
14 Lin K Y A, Chang H A. Zeolitic imidazole framework-67 (ZIF-67) as a heterogeneous catalyst to activate peroxymonosulfate for degradation of Rhodamine B in water[J].Journal of the Taiwan Institute of Chemical Engineers,2015,53:40.
15 Zhu Y P, Ren Z Y, Yuan Z Y. Co²⁺-loaded periodic mesoporous aluminum phosphonates for efficient modified Fenton catalysis[J].RSC Advances,2015,5(10):7628.
16 Zhang W, Tay H L, Lim S S, et al. Supported cobalt oxide on MgO: Highly efficient catalysts for degradation of organic dyes in dilute solutions[J].Applied Catalysis B: Environmental,2010,95:93.
17 Wang L P. Progress in application of metal-organic frameworks in photocatalytic reactions[J].Materials Review A: Review Papers 2017,31(13):51(in Chinese).
王丽苹.金属有机骨架材料在光催化反应中的应用研究进展[J].材料导报:综述篇,2017,31(13):51.
18 Zeng T, Zhang X, Wang S, et al. Spatial confinement of a Co₃O₄ catalyst in hollow metal-organic frameworks as a nanoreactor for improved degradation of organic pollutants[J].Environmental Science & Technology,2015,49(4):2350.
19 Lin K Y A, Chen Y C, Huang C F. Magnetic carbon-supported cobalt prepared from one-step carbonization of hexacyanocobaltate as an efficient and recyclable catalyst for activating PMS[J].Separation and Purification Technology,2016,170:173.
20 Xu P, Zeng G M, Huang D L, et al. Use of iron oxide nanomaterials in wastewater treatment: A review[J].Science of the Total Environment,2012,424:1.
21 Cundy A B, Hopkinson L, Whitby R L D. Use of iron-based technologies in contaminated land and groundwater remediation: A review[J].Science of the Total Environment,2008,400(1-3):42.
22 Chen D, Ma X, Zhou J, et al. Sulfate radical-induced degradation of acid orange 7 by a new magnetic composite catalyzed peroxymonosulfate oxidation process[J].Journal of Hazardous Materials,2014,279:476.
23 Wei X Y. Research of heterogenous Fe₂O₃ in activation of peroxymonosulfate for decolorization of Rhodamine B[D].Harbin: Harbin Institute of Technology,2013(in Chinese).
魏熙宇.三氧化二铁催化过硫酸氢钾降解罗丹明B的研究[D].哈尔滨:哈尔滨工业大学,2013.
24 Sun H, Zhou G, Liu S, et al. Nano-Fe⁰ encapsulated in microcarbon spheres: Synthesis, characterization, and environmental applications[J].ACS Applied Materials & Interfaces,2012,4(11):6235.
25 Gong F, Wang L, Li D, et al. An effective heterogeneous iron-based catalyst to activate peroxymonosulfate for organic contaminants removal[J].Chemical Engineering Journal,2015,267:102.
26 Du J, Bao J, Liu Y, et al. Efficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A[J].Journal of Hazardous Materials,2016,320:150.
27 Wang Y, Xie Y, Sun H, et al. 2D/2D nano-hybrids of γ-MnO₂ on reduced graphene oxide for catalytic ozonation and coupling peroxymonosulfate activation[J].Journal of Hazardous Materials,2016,301(6):56.
28 Wei M, Ruan Y, Luo S, et al. The facile synthesis of a magnetic OMS-2 catalyst for decomposition of organic dyes in aqueous solution with peroxymonosulfate[J].New Journal of Chemistry,2015,39(8):6395.
29 Liu C, Pan D,Tang X, et al. Degradation of rhodamine B by the α-MnO₂/peroxymono-sulfate system[J].Water, Air, & Soil Pollution,2016,227(3):92.
30 Saputra E, Muhammad S, Sun H, et al. Manganese oxides at diffe-rent oxidation states for heterogeneous activation of peroxymonosulfate for phenol degradation in aqueous solutions[J].Applied Catalysis B: Environmental,2013,142(3):729.
31 Saputra E, Muhammad S, Sun H, et al. Different crystallographic one-dimensional MnO₂ nano-materials and their superior perfor-mance in catalytic phenol degradation[J].Environmental Science & Technology,2013,47(11):5882.
32 Wang Y, Indrawirawan S, Duan X, et al. New insights into heterogeneous generation and evolution processes of sulfate radicals for phenol degradation over one-dimensional α-MnO₂ nanostructures[J].Chemical Engineering Journal,2015,266:12.
33 Saputra E, Muhammad S, Sun H, et al. Shape-controlled activation of peroxymonosulfate by single crystal α-Mn₂O₃ for catalytic phenol degradation in aqueous solution[J].Applied Catalysis B: Environmental,2014,154:246.
34 Zhang G C, Zhang J, Wan Z Q, et al. Degradation of acid orange 7 by peroxomonosulfate activated with Fe-MnO_x[J].Environmental Science and Pollution Research,2015,28(12):1902(in Chinese).
张古承,张静,万子谦等.铁锰双金属氧化物对过硫酸氢钾降解酸性橙7的催化效果[J].环境科学研究,2015,28(12):1902.
35 Wan Z, Wang J. Degradation of sulfamethazine antibiotics using Fe₃O₄-Mn₃O₄ nano-composite as a fenton-like catalyst[J].Journal of Chemical Technology and Biotechnology,2017,92(4):874.
36 Feng Y, Wu D L, Deng Y, et al. Sulfate radical-mediated degradation of sulfadiazine by CuFeO₂ rhombohedral crystal-catalyzed peroxymonosulfate: Synergistic effects and mechanisms[J].Environmental Science & Technology,2016,50(6):3119.
37 Liu J. Catalytic peroxide oxidation of chlorophenol in aqueous solution in presence of Fe₃O₄ nanoparticles or its composites[D].Harbin: Harbin Institute of Technology,2014(in Chinese).
刘杰.纳米Fe₃O₄及其复合材料催化过氧化物去除水中氯酚的研究[D].哈尔滨:哈尔滨工业大学,2014.
38 Saputra E, Muhammad S, Sun H, et al. A comparative study of spinel structured Mn₃O₄, Co₃O₄ and Fe₃O₄ nanoparticles in catalytic oxidation of phenolic contaminants in aqueous solutions[J].Journal of Colloid and Interface Science,2013,407:467.
39 Liu J, Zhao Z W, Shao P H. Activation of peroxymonosulfate with magnetic Fe₃O₄-MnO₂ core-shell nanocomposites for 4-chlorophenol degradation[J].Chemical Engineering Journal,2015,262(9):854.
40 Bard A J, Parsons R, Jordan J. Standard potentials in aqueous solution[M].CRC Press, New York,1985.
41 Nie G, Huang J, Hu Y, et al. Heterogeneous catalytic activation of peroxymonosulfate for efficient degradation of organic pollutants by magnetic CuO/Fe₃O₄ submicron composites[J].Chinese Journal of Catalysis,2017,38:227.
42 Feng Y, Liao C, Li H. Cu₂O-promoted degradation of sulfametho-xazole by α-Fe₂O₃-catalyzed peroxymonosulfate under circumneutral conditions: Synergistic effect, Cu/Fe ratios, and mechanisms[J].Environmental Technology,2017,39(1):1.
43 Zhang D W. Research on catalysis of CuO-CeO₂binary mixed oxides for PMS degradation of phenol[D].Harbin: Harbin Institute of Technology,2013(in Chinese).
张丹微.铜铈二元混合氧化物催化过硫酸氢钾降解苯酚研究[D].哈尔滨:哈尔滨工业大学,2013.
44 Ding Y B, Zhu L H, Wang N, et al. Sulfate radicals induced degradation of tetrabromobisphenol A with nanoscaled magnetic CuFe₂O₄ as a heterogeneous catalyst of peroxymonosulfate[J].Applied Catalysis B: Environmental,2013,129:153.
45 Ren Y, Lin L, Ma J, et al. Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe₂O₄(M=Co,Cu,Mn,and Zn) as heterogeneous catalysts in the water[J].Applied Catalysis B: Environmental,2015,165:572.
46 Feng Y, Liu J, Wu D, et al. Efficient degradation of sulfamethazine with CuCo₂O₄ spinel nanocatalysts for peroxymonosulfate activation[J].Chemical Engineering Journal,2015,280:514.
47 Tan C, Gao N, Fu D, et al. Efficient degradation of paracetamol with nanoscaled magnetic CoFe₂O₄ and MnFe₂O₄ as a heterogeneous catalyst of peroxymonosulfate[J].Separation and Purification Technology,2017,175:47.
48 Yao Y, Cai Y, Wu G, et al. Sulfate radicals induced from peroxymonosulfate by cobalt manganese oxides (Co_xMn_3-xO₄) for Fenton-Like reaction in water[J].Journal of Hazardous Materials,2015,296:128.
49 Oh W D, Lua S K, Dong Z L, et al. A novel three-dimensional spherical CuBi₂O₄ consisting of nanocolumn arrays with persulfate and peroxymonosulfate activation functionalities for 1H-benzotriazole removal[J].Nanoscale,2015,7(17):8149.
50 Oh W D, Chang V W, Lim T T. A comprehensive performance eva-luation of heterogeneous Bi₂Fe₄O₉/peroxymonosulfate system for sulfamethoxazole degradation[J].Environmental Science and Pollution Research International,2017:1.