三维石墨烯及其复合材料的制备及在超级电容器中的研究进展<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.05.002

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Abstract Three dimensional (3D) graphene and its composite have recently attracted great interests in the field of materials science because of its superior properties such as good flexibility, large specific surface area, high power density, stable mechanical properties, fast electron transport and so on. In this paper, the basic properties of the three dimensional graphene materials are summarized. The preparation methods of the composite materials and their applications in supercapacitor are reviewed. The widely used preparation methods include self-assembly method, template method and 3D printing technique and so on. The performances of porous structure, pore size, flexibility and electron transport rate can be optimized by improving the preparation methods. The composite composed of three dimensional (3D) graphene,transition metal compounds and conductive polymer showed a remarkable application potential as supercapacitor electrode materials.

Key words： three dimensional graphene transition metal conducting polymer supercapacitor

Published: 02 May 2018

CLC number:

TB333

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	Articles by authors
	FU Shenna
	MA Li
	GAN Mengyu
	WANG Shiyong

Cite this article:

FU Shenna,MA Li,GAN Mengyu, et al. Recent Advances in Preparation of Three-dimensional Graphene and Relevant Composites and Their Applications in Supercapacitors[J]. Materials Reports, 2017, 31(5): 9-15.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.05.002 OR http://www.mater-rep.com/EN/Y2017/V31/I5/9

1 Li F, Jiang X, Zhao J J, et al. Graphene oxide: A promising nanomaterial for energy and environmenttal applications[J]. Nano Energy,2015,16:488.
2 Zhu T, Wang J, Ho G W. Self-supported yolk-shell nano colloids towards high capacitance and excellent cycling performance[J]. Nano Energy,2015,18:273.
3 Conway B, Birss V, Wojtowicz J. The role and utilization of pseu-docapacitance for energy storage by supercapacitors[J]. J Power Sources,1997,66(1):1.
4 Zhou G J, Ye Z K, Shi W W, et al. Applications of three dimensio-nal graphene and its composite materials[J].Prog Chem,2014,26(6):950(in Chinese).
周国珺,叶志凯,石微微. 三维(3D) 石墨烯及其复合材料的应用[J]. 化学进展,2014,26(6):950.
5 Huang C C, Li C, Shi G Q.Graphene based catalysts[J]. Energy Environ Sci,2012,5:8848.
6 Huang X D, Qian K, Yang J, et al. Functional nanoporous graphene foams with controlled pore sizes[J]. Adv Mater,2012,24:4419.
7 Zhu X Y, Sakineh C, Xia Y D, et al. Preparation of 3D graphene-based architectures and their applications in supercapacitors[J]. Mater Int,2015,25:554.
8 Li Z S, Ye L T, Lei F L, et al. Enhanced electro-photo synergistic catalysis of Pt (Pd)/ZnO/graphene composite for methanol oxidation under visible light irradiation[J]. Electrochim Acta,2016,188:450.
9 Hai Z Y, Gao L B, Zhang Q, et al. Facile synthesis of core-shell structured PANI-Co₃O₄ nanocomposites with superior electrochemical performance in supercapacitors[J]. Appl Surf Sci,2016,361:57.
10 Capasso A, Castillo A E D R, Sun H, et al. Ink-jet printing of graphene for flexible electronics: An environmentally-friendly approach[J]. Solid State Commun,2015,224:53.
11 Ionita M, Crica L E, Vasile E, et al. Effect of carboxylic acid functionalized graphene on physical-chemical and biological performances of polysulfone porous films[J]. Polymer,2016,92(1):1.
12 Li X Y, Tan X C, Yan J, et al. A sensitive electrochem iluminescence folic acid sensor based on a 3D graphene/CdSeTe/Ru(bpy) doped silica nanocomposite modified electrode[J]. Electrochim Acta,2016,187(1):433.
13 Kim J H, Chang W S, Kim D, et al. 3D printing of reduced graphene oxide nanowires[J]. Adv Mater,2015,27:157.
14 Zhu C, Han T Y J, et al. Highly compressible 3D periodic graphene aerogel micro lattices[J]. Nat Commun,2015,6:8.
15 Lee K G, Jeong J M, Lee S J, et al. Sono chemical-assisted synthesis of 3D graphene/nanoparticle foams and their application in supercapacitor[J]. Ultrason Sonochem,2015,22:422.
16 Xu Y X, Sheng K X, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. ACS Nano,2010,4:4324.
17 Lee S H, Kim H W, Hwang J O,et al. Three-dimensional self-assembly of graphene oxide platelets into mechanically flexible macroporous carbon films[J]. Angew Chem,2010,122:10282.
18 Zhang N S, Fu C P, Liu D, et al. Three dimensional pompon-like MnO₂/graphene hydrogel composite for supercapacitor[J]. Electrochim Acta,2016,210:804.
19 Xu Y, Wu Q, Sun Y, et al. Three-dimensional self-assembly of graphene oxide and DNA into multifunctional hydrogels[J]. ACS Nano,2010,4:7358.
20 Xie R H, Ren P G, Hui J, et al. Preparation and properties of graphene oxide regenerated cellulose/polyvinyl alcohol hydrogel with pH-sensitive behavior[J]. Carbohydr Polym,2016,138(15):222.
21 Jiang X, Ma Y, Li J, et al. Self-assembly of reduced graphene oxide into three-dimensional architecture by divalent ion linkage[J]. J Phys Chem C,2010,114:22462.
22 Sheng K X, Xu Y X, Li C, et al. High performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide[J]. New Carbon Mater,2011,26:9.
23 Xu Y, Lin Z, Zhong X, et al. Holey graphene frameworks for highly efficient capacitive energy storage[J]. Nat Commun,2014,5:4554.
24 Luo J W, Zhong J W, Zou Y B, et al. Preparation of morphology-controllable polyaniline and polyaniline/graphene hydrogels for high performance binder-free supercapacitor electrodes[J]. J Power Sources,2016,319:73.
25 Zhang C C, Wang L G, Zhao Y Z, et al. Self-asse-mbly synthesis of graphene oxide double shell hollow spheres decorated with Mn₃O₄ for electrochemical supercapacitors[J]. Carbon,2016,107:100.
26 Chen C M, Yang Q H, et al. Self-assembled free-standing graphite oxide membrane[J]. Adv Mater,2009,21:1.
27 Shao J J, Wu S D, Zhang S B, et al. Graphene oxide hydrogel at so-lid/liquid interface[J]. Chem Commun,2011,47(20):5771.
28 Chen Z P, Ren W C, Gao L B, et al. Three dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nat Mater,2011,10:424.
29 Wang J, Chao D L, Liu J L, et al. Ni₃S₂@MoS₂ core/shell nanorod arrays on Ni foam for high-perfor-mance electrochemical energy sto-rage[J]. Nano Energy,2014,7(7):151.
30 Ito Y, Tanabe Y, Qiu H J, et al. High-quality three-dimensional nanoporous graphene[J]. Angew Chem,2014,53(19):4822.
31 Ruan Y Y, Jiang J J, Wan H Z, et al. Rapid self-assembly of porous square rod-like nickel persulfide via a facile solution method for high-performance supercapacitors[J]. J Power Sources,2016,301(1):122.
32 Xiong C Y, Li T H, Dang A L, et al. Two-step approach of fabrication of three-dimensional MnO₂-graphene-carbon nanotube hybrid as a binder-free supercapacitor electrode[J].J Power Sources,2016,306(2):602.
33 Yang S, Feng X, Wang L, et al. Graphene-based nano sheets with a sandwich structure[J]. Angew Chem,2010,122(28):4905.
34 Wang S Y, Ma L, Gan M Y, et al. Free-standing 3D graphene/polyaniline composite film electrodes for high-performance supercapacitors[J]. J Power Sources,2015,299(12):347.
35 Chen C M, Zhang Q, Huang C H, et al. Macroporous ‘bubble’ graphene film via template dire-cted ordered-assembly for high rate supercapacitors[J]. Chem Commun,2012,48(57):7149.
36 He Z M, Liu J, Qiao Y, et al. Architecture engineering of hierarchically porous chitosan/vacuu-m-stripped graphene scaffold as bioanode for high performance microbial fuel cell[J]. Nano Lett,2012,12(9):4738.
37 Vinod S, Tiwary C S, Autretol P A D, et al. Low-density three-dimensional foam using self-reinfo-rced hybrid two-dimensional atomic layers[J]. Nat Commun,2014,5:4541.
38 Zhu Y, Murali S, Stoller M D, et al. Carbon-based supercapacitors produced by activation of graphene [J]. Science,2011,332(6037):1537.
39 Wang H, Zhang D, Yan T, et al. Three dimen-sional macro-porous graphene architectures as high performance electrodes for capacitive deionization [J]. J Mater Chem A,2013,1(38):11778.
40 Chang Z L, Gao Z Y, Liu X, et al. Hierarchically porous carbons with graphene incorporation for efficient supercapacitors[J]. Electrochim Acta,2016,213:382.
41 Xie Y H, Sheng X X, Xie D L, et al.Fabricating graphene hydrogels with controllable pore structure via one-step chemical reduction process [J]. Carbon,2016,109:673.
42 Liu D, Fu C P, Zhang N S, et al.Three-dimensional porous nitrogen doped graphene hydrogel for high energy density supercapacitors[J].Electrochim Acta,2016,213:291.
43 Xu Y X, Lin Z Y, Huang X Q, et al. Flexible solid-state supercapacitors based on three-dimensional graphene hydrogel films[J]. ACS Nano,2013,7:4042.
44 An H R, Li Y, Long P, et al.Hydrothermal preparation of fluorinated graphene hydrogel for high-performance supercapacitors[J]. J Power Sources,2016,312:146.
45 Hwang J Y,El-Kady M F,et al. Direct preparation and processing of graphene/RuO₂ nano-composite electrodes for high-performance capacitive energy storage[J]. Nano Energy,2015,18:57.
46 Li Z J, Zhang W Y, Sun C Y, et al. Controlled synthesis of Ni-(OH)₂/graphene composites and their transformation to NiO/graphene for energy storage[J]. Electrochim Acta,2016,212:390.
47 Nguyen V H, Shim J J. The 3D Co₃O₄/graphene/nickel foam electrode with enhanced Electrochemical performance for supercapacitors[J]. Mater Lett,2015,139:377.
48 Xu J, Sun H J, Li Z L, et al. Synthesis and elec-trochemical properties of graphene/V₂O₅ xerogels nanocomposites as supercapacitor electrodes[J]. Solid State Ionics,2014,262:234.
49 Huang Y S, Wu D Q, Wang J Z, et al. Amphiphilic polymer promoted assembly of macroporous graphene/SnO₂ frameworks with tunable porosity for high-performance lithium storage[J]. Small,2014,10(11):2226.
50 Gopalakrishnan K, Sultan S, Govindaraj A, et al. Supercapacitors based on composites of PANI with nanosheets of nitrogen-doped RGO, BC_1.5N, MoS₂ and WS₂[J]. Nano Energy,2015,12:52.
51 Li X F, Shen J F, Li N, et al. Fabrication of γ-MnS/rGO composite by facile one-pot solvothermal approach for supercapacitor applications[J]. J Power Sources,2015,282(15):194.
52 Wang H L, Casalongue H S, Liang Y Y, et al.Ni(OH)₂ nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials [J]. J Am Chem Soc,2010,132:7472.
53 Choi B G, Yang M H, Hong W H, et al. 3D macroporous graphene frameworks for supercapacitors with high energy and power densities[J]. ACS Nano,2012,6(5):4020.
54 Hassan M, Reddy K R, Haque E, et al. Hierarchical assembly of graphene/polyaniline nanos-tructures to synthesize free standing supercapacitor electrode[J]. Compos Sci Technol,2014,98:1.
55 Tang W, Li P, Yuan C Q, et al. Facile synthesis of 3D reduced graphene oxide and its polyaniline compo-site for supercapacitor application[J]. Synth Met,2015,202:140.
56 Ma C L, Peng L, Feng Y F, et al. Polyfurfuryl alcohol spheres template synthesis of 3D porous graphene for high-performance supercapacitor application [J]. Synthe Met,2016,220:227.
57 Shu K W, Wang C Y, Zhao C, et al. A free standing graphene-polypyrrole hybrid paper via electropolymerization with an enhanced areal capacitance[J]. Electrochim Acta,2016,212:561.
58 Lin H L, Huang Q, Wang J Z, et al. Self assembled graphene/ polyaniline/Co₃O₄ ternary hybrid aerogels for supercapacitors[J]. Electrochim Acta,2016,191:444.
59 Yu L, Gan M Y, Ma L, et al. Facile synthesis of MnO₂/polyaniline nanorod arrays based on graphene and its electrochemical perfor-mance[J]. Synthe Met,2014,198:167.
60 Sha C H, Lu B,Mao H Y, et al. 3D ternary nanocomposites of molybdenum disulfide/polyaniline/reduced graphene oxide aerogel for high performance supercapacitors[J].Carbon,2016,99:26.
61 Gao Z, Yang W L, Wang J, et al. Flexible all-solid-state hierarchical NiCo₂O₄/porous graphene paper asymmetric supercapacitors with an exceptional combination of electrochemical properties[J]. Nano Energy,2015,13:306.
62 Chen Y P, Liu B, Liu Q, et al. Flexible all-solid-state asymmetric supercapacitor assembled using coaxial NiMoO₄ nanowire arrays with chemically integrated conductive coating[J]. Electrochim Acta,2015,178:429.
63 Nguyen V H, Lamiel C, Shim J J. Mesoporous 3D graphene@NiCo₂O₄ arrays on nickel foam as electrodes for high-performance supercapacitors[J]. Mater Lett,2016,170:105.