| REVIEW PAPER |
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| Advances in Synthesis of Functionally-terminated Polymer by Controlled/Living Radical Polymerization |
| MIAO Qing1,2, QU Jianbo1, ZHANG Feifei1, TIAN Huilin1, ZHANG Haitao1
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1 School of Leather Chemistry and Engineering, Qilu University of Technology, Jinan 250353;
2 Yantai Hua Da Chemical Industry Co., Ltd,Yantai 264002 |
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Abstract Functionally-terminated polymer, defined as macromolecules that contain two reactive terminal groups, are used as cross-linkers, chain extenders and important building blocks for various macromolecular structures, including block and graft copolymers, star, hyperbranched or dendritic polymers. This review describes the general techniques for preparing functionally-terminated polymer via controlled/living radical polymerization, including initiator-transfer agent-terminator (inifenter) method, atom transfer radical polymerization, nitroxide mediated radical polymerization, reversible addition-fragmentation chain transfer polymerization. We also provide a prospect upon this field.
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Published: 04 May 2018
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2017, Vol. 31 
