纳米增强水泥基复合材料抗氯离子迁移及固化性能综述

doi:10.11896/cldb.22090138

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Abstract The application of advanced carbon-based nanomaterials in the field of cement-based materials has broken through the performance limits of traditional cement-based materials, as a hot field in the future research of high-performance cement-based composites. At present, there have been many studies on the hydration, microstructure and mechanic properties of nano-reinforced cement-based composites. However relatively few studies have focused on the long-term durability properties, especially resistance to the chloride induced corrosion. The chloride induced corrosion resistance of nano reinforced cement-based materials mainly contains two aspects: firstly, from pore structure aspect, nanomaterials could refine the pore structure of cement paste by reducing the overall porosity and increasing the proportion of nano and micro pores at the same time, leading to reduced penetration rate of external chloride ions. Secondly, from chloride binding aspect, nanomaterials could increase both the physical and chemical chloride binding capacity at the pore-solution interface, by promoting and modifying cement hydration, leading to reduced free chloride content remaining in the pore solution. Above mentioned two beneficial effects of nanomaterials can both reduce the corrosion risk by preventing the free chloride concentration around the surface of reinforcing steel bars reaching critical corrosion concentration. However, the pre-paration of stable nano-reinforced cement-based composites and mechnisms of hydration modification brought by different dimensional nanomaterials need to be further studied. This paper summarizes the research progress on chloride induced corrosion resistance of nano-reinforced cement-based materials in recent years. Effects and mechanisms of various nano materials with different dimensions, different preparation methods and different chemical compositions on chloride ion migration resistance and chloride ion binding performance are reviewd. Future prospect on the development and application of nano-reinforced high corrosion resistance cement-based composites are also proposed.

Key words： nano-reinforced cement-based composites durability chloride ion migration chloride binding

Published: 10 April 2024 Online: 2024-04-11

CLC number:

TU528

Fund:National Natural Science Foundation of China-Shandong United Fund (U2006223), Shenzhen Science and Technology Plan Project (JCYJ20190808151011502), the Key-Area Research and Development Program of Guangdong Province (2019B111107003).

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	LONG Wujian
	YU Yang
	HE Chuang
	LI Xueqi
	XIONG Chen
	FENG Ganlin

Cite this article:

LONG Wujian,YU Yang,HE Chuang, et al. Review on Chloride Ion Ingress Resistance and Chloride Binding Performance of Nano-reinforced Cement-based Composites[J]. Materials Reports, 2024, 38(7): 22090138-10.

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http://www.mater-rep.com/EN/10.11896/cldb.22090138 OR http://www.mater-rep.com/EN/Y2024/V38/I7/22090138

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