两电子氧还原电催化合成过氧化氢的研究进展

doi:10.11896/cldb.22030010

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Abstract Hydrogen peroxide (H₂O₂) is a versatile and environmental-friendly oxidant, which is widely used in chemical synthesis, wastewater treatment, and pulp/textile bleaching. Current industrial manufacturing of H₂O₂ is mainly based on an anthraquinone method, which has disadvantages such as high energy consumption, tedious process, and potential safety concern for its storage and transportation. Electrocatalytic H₂O₂ production through two-electron oxygen reduction reaction (2e^-ORR) has recently emerged as an intriguing alternative, enabling on-site H₂O₂ generation according to practical demands. The efficiency of 2e^-ORR directly depends on electrocatalysts’ activity, selectivity, and stability. This review would briefly introduce the ORR mechanism and performance evaluation methods of 2e^-ORR catalysts. Then, an overview of the recent advance in precious metal and carbon-based electrocatalysts for 2e^-ORR is provided, emphasizing structure optimization, compositional doping, active site regulation, and surface/interface design of these catalysts. Furthermore, the present challenges and critical issues to be solved in the future are prospected to guide further development toward the electrocatalytic synthesis of H₂O₂.

Key words： hydrogen peroxide oxygen reduction reaction electrocatalytic synthesis catalyst

Published: Online: 2023-12-19

CLC number:

O646

Fund:National Natural Science Foundation of China (21401145).

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	XU Wenjie
	LIU Dan
	QU Deyu
	LI Xi

Cite this article:

XU Wenjie,LIU Dan,QU Deyu, et al. Research Progress on Electrocatalytic Synthesis of Hydrogen Peroxide by Two-electron Oxygen Reduction[J]. Materials Reports, 2023, 37(24): 22030010-12.

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http://www.mater-rep.com/EN/10.11896/cldb.22030010 OR http://www.mater-rep.com/EN/Y2023/V37/I24/22030010

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