无机-有机杂化微胶囊:制备技术及在抗磨耐腐蚀涂层中的应用

doi:10.11896/cldb.21060113

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Abstract Microcapsules' combination with the coating substrate is considered to be an effective way to enhance the anti-wear and anti-corrosion pro-perties of coatings, which is of great significance to the research of anti-wear and anti-corrosion of coatings. Common microcapsules are made of organic materials, such as polysulfone (PSF), polyurea formaldehyde (PUF), polymelamine formaldehyde (PMF), polyurea (PU), etc. When they combined with inorganic materials to make hybrid shells, the temperature resistance and compatibility of microcapsules are promoted, can adjust permeability as well as mechanical strength effectively.
Nano clay, nano-SiO₂, nano-CaCO₃, nano-Al₂O₃ and carbon nanotubes become good materials for the synthesis of hybrid shell. The inorga-nic-organic hybrid microcapsules have strong temperature resistance, simultaneously mechanical and physical stability are improved. Microcapsules coated with oily substances or ionic liquids are often used to prepare coatings with self-lubricating and self-healing properties, which are widely used in anti-wear and corrosion resistance.
At present, the preparation methods of inorganic-organic hybrid microcapsules are mainly solvent evaporation, Pickering emulsion polymerization, in situ polymerization and interfacial polymerization. The solvent evaporation method is simple and easy to operate. Pickering emulsion method can effectively improve the entrapment efficiency. In situ polymerization is easy balling, large coating amount and no by-products. Interfacial polymerization has the advantages of high speed, mild reaction process.
In this paper, the preparation methods of inorganic-organic hybrid microcapsules are discussed, and the anti-wear and anti-corrosion mechanism of microcapsules is briefly described. Based on the classification of preparation methods, the specific application of microcapsules in enhancing the related properties of polymer organic coatings is summarized. Finally, the preparation and application of inorganic-organic hybrid microcapsules are prospected, in order to provide reference for the application of microcapsules in more fields.

Key words： inorganic-organic hybrid shell microcapsules anti-wear anti-corrosion self-lubrication self-healing

Published: 10 May 2023 Online: 2023-05-04

CLC number:

TB33

Fund:National Natural Science Foundation of China (51908092), Exceptional Young Talents Project (CQYC2020057871), the Postdoctoral Science Fund Project of Chongqing Natural Science Foundation (cstc2019jcyj-bshX0085), and the Joint Funds of the National Natural Science Foundation of China-Guangdong (U1801254).

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	Articles by authors
	LIU Xiaoying
	RUAN Wenlin
	ZHANG Yuxin
	RAO Jinsong
	YIN Changqing
	ZHANG Xianming
	LIU Yunqi

Cite this article:

LIU Xiaoying,RUAN Wenlin,ZHANG Yuxin, et al. Inorganic-Organic Hybrid Microcapsules:Preparation Technology and Applications in Anti-wear and Corrosion-resistant Coatings[J]. Materials Reports, 2023, 37(9): 21060113-9.

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http://www.mater-rep.com/EN/10.11896/cldb.21060113 OR http://www.mater-rep.com/EN/Y2023/V37/I9/21060113

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