SrTiO<sub>3</sub>基可逆固体氧化物电池电极材料的研究进展

doi:10.11896/cldb.21040196

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Abstract Reversible solid oxide cell (RSOC) is an energy conversion device with high efficiency of reversible power generation and electrolytic hydrogen generation, which is considered as a new energy conversion device with good development prospects. However,there are still some technical problems to be solved, as the lack of highly active and stable electrode materials currently limits the wide application of RSOC. Traditionally, the fuel electrode generally uses nickel-yttrium-stabilized zirconia (Ni-YSZ) materials, while there are many types of oxides that can be used as the oxygen electrode. The electrochemical properties of both fuel electrodes and oxygen electrodes have to be further improved. In recent years lots of works reported that SrTiO₃-based perovskite material is a typical of electrode material with good performance in RSOC, which has become a popular candidate material to solve the RSOC electrode problem. However, there is a lack of systematic summary of this kind of materials. Therefore, the application progress of SrTiO₃-based perovskite materials as the RSOC electrode is reviewed in this paper. Firstly, the study of SrTiO₃-based perovskite materials used as RSOC fuel and oxygen electrodes is systematically analyzed, and the methods and measures commonly used for SrTiO₃ modification, such as doping, nonstoichiometric ratio, recombination and a new method: in situ precipitation, are introduced. Secondly, the feasibility of applying SrTiO₃-based perovskite for RSOC electrodes with a symmetrical structure is discussed. Finally, from the perspective of the construction of a new generation of high-performance RSOC for energy internet in the future, the application prospect and the problems to be solved of SrTiO₃-based perovskite materials in RSOC are predicted.

Key words： reversible solid oxide cell (RSOC) solid oxide fuel cell (SOFC) solid oxide electrolysis cell (SOEC) strontium titanate

Published: 10 November 2022 Online: 2022-11-03

CLC number:

TQ152

Fund:National Natural Science Foundation of China (51737011, 51877173), and the Science and Technology Program of the State Grid Corporation of China(SGSDJN00FZQT1700446).

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	Articles by authors
	LIU Zhengrong
	YANG Jiaming
	FU Lei
	ZHOU Likai
	WU Ke
	LI Qinghao
	WANG Xuan
	ZHOU Jun
	WU Kai

Cite this article:

LIU Zhengrong,YANG Jiaming,FU Lei, et al. Research Progress of SrTiO₃-based Electrodes for Reversible Solid Oxide Cells[J]. Materials Reports, 2022, 36(21): 21040196-8.

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http://www.mater-rep.com/EN/10.11896/cldb.21040196 OR http://www.mater-rep.com/EN/Y2022/V36/I21/21040196

1 Paolo D G, Umberto D. Energies, 2016, 9(8), 662.
2 Ferrero D, Lanzini A, Leone P, et al. Chemical Engineering Journal, 2015, 274, 143.
3 Wendel C H, Braun R J. Applied Energy, 2016, 172, 118.
4 Xu N, Li X, Zhao X, et al. Energy & Environmental Science, 2011, 4(12), 4942.
5 Singhal S C, Kendall K. High temperature solid oxide fuel cells fundamentals, design and applications, Science Press, China, 2007 (in Chinese).
辛格哈尔, 肯德尔.高温固体氧化物燃料电池原理、设计和应用, 科学出版社, 2007.
6 Jiao Y, Wang L Y, Zhang L Q, et al. Energy & Fuels, 2018, 32(4), 4547.
7 Da Silva A L, Heck N C. Journal of Power Sources, 2015, 296, 92.
8 Prakash B S, Kumar S S, Aruna S T. Renewable and Sustainable Energy Reviews, 2014, 36, 149.
9 Ma Z F, Lin W M, Huang C R, et al. Chinese Journal of Power Sources, 1994(1), 10(in Chinese).
马紫峰, 林维明, 黄传荣, 等. 电源技术,1994(1), 10.
10 Marina O A, Pederson L R, Williams M C, et al. Journal of the Electrochemical Society, 2007, 154(5), B452.
11 Wang W S, Huang Y Y, Jung S, et al. Journal of the Electrochemical Society, 2006, 153(11), A2066.
12 Jensen S H, Larsen P H, Mogensen M. International Journal of Hydrogen Energy, 2007, 32(15), 3253.
13 Fan H, Keane M, Li N, et al. International Journal of Hydrogen Energy, 2014, 39(26), 14071.
14 Laguna-Bercero M A, Kilner J A, Skinner S J. Solid State Ionics, 2011, 192(1), 501.
15 Li R P, Zhang C, Liu J H, et al. Journal of Kunming University of Science and Technology (Natural Science), 2019, 44(3), 6(in Chinese).
李润萍, 张程, 刘建华, 等. 昆明理工大学学报(自然科学版),2019,44(3),6.
16 Chang L L. Development and Application of Materials, 2014, 29(1), 89(in Chinese).
常亮亮.材料开发与应用, 2014, 29(1), 89.
17 Liu T, Zhao Y Q. Applied Chemical Industry, 2019, 48(9), 2162(in Chinese).
刘通, 赵怡茜.应用化工, 2019,48(9), 2162.
18 Shannon radii. http:∥abulafia.mt.ic.ac.uk/shannon/ptable.php.
19 Zhou X, Zhao H L, Xu N S, et al. Journal of the Chinese Ceramic Society, 2011, 39(6), 958(in Chinese).
周雄,赵海雷,徐南生,等. 硅酸盐学报, 2011, 39(6), 958.
20 Shang P P, Zhang B P, Li J F, et al. Rare Metal Materials and Enginee-ring, 2009, 38(S2), 315(in Chinese).
尚鹏鹏, 张波萍, 李敬锋, 等. 稀有金属材料与工程, 2009, 38(S2), 315.
21 Gao F, Zhao H L, Li X, et al. Journal of Power Sources, 2008,185, 26.
22 Cheng Y F, Zhao H L, Wang Z F, et al. Rare Metal Materials and Engineering, 2008, 37(12), 2069(in Chinese).
程云飞, 赵海雷, 王治峰, 等. 稀有金属材料与工程,2008,37(12), 2069.
23 Xu D. Preparation and properties of CeO₂ based composite electrolyte for medium temperature solid oxide fuel cell. Ph. D Thesis, Jilin University, China, 2008(in Chinese).
徐丹. 中温固体氧化物燃料电池CeO₂基复合电解质材料的制备和性能研究. 博士学位论文,吉林大学,2008.
24 Qin M J, Gao F, Cizek J, et al. Scripta Materialia, 2021,190, 118.
25 Li X, Zhao H L, Xu N S, et al. International Journal of Hydrogen Energy, 2009, 34 (15), 6407.
26 Chang W. Preparation of SOFC lanthanum-doped strontium titanate anode and study of electrode properties. Master's Thesis, Harbin Institute of Technology, China, 2015(in Chinese).
常文博. SOFC镧掺杂钛酸锶阳极材料制备及电极性能的研究. 硕士学位论文, 哈尔滨工业大学,2015.
27 Zhao H L, Huang X L, Li X, et al. Chinese Journal of Materials Research, 2007(3), 255(in Chinese).
赵海雷, 黄贤良, 李雪, 等. 材料研究学报, 2007(3), 255.
28 Hashimoto S, Kindermann L, Larsen P H, et al. Journal of Electrocera-mics, 2006, 16(2), 103.
29 Shang Y F. Preparation and properties of La and Fe double-doped SrTiO₃ oxide anode materials. Master's Thesis, Harbin Institute of Technology, China, 2011(in Chinese).
尚玉芬. La和Fe双掺杂SrTiO₃氧化物阳极材料的制备与性能研究.硕士学位论文,哈尔滨工业大学,2011.
30 Marina O A, Canfield N L, Stevenson J W. Solid State Ionics, 2002, 149, 21.
31 Silva E R, Curi M, Furtado J G, et al. Ceramics International, 2019, 45(8), 9761.
32 Sun X F, Guo R S, Li J, et al. Chinese Journal of Power Sources, 2006(4), 282(in Chinese).
孙秀府, 郭瑞松, 李娟, 等. 电源技术,2006(4), 282.
33 Li X, Zhao H L, Shen W, et al. Journal of Power Sources, 2007, 166(1), 47.
34 Hui S, Petric A. Journal of the European Ceramic Society, 2002, 22(9-10), 1673.
35 Hui S, Petric A. Journal of the Electrochemical Society, 2002, 149(1), J1.
36 Blennow P, Hagen A, Hansen K K, et al. Solid State Ionics, 2008, 179(35-36), 2047.
37 Blennow P, Hansen K K, Wallenberg L R, et al. Solid State Ionics, 2009, 180(1), 63.
38 Sudireddy B R, Blennow P, Nielsen K A. Solid State Ionics, 2012, 216, 44.
39 Xiao G L, Nuansaeng S, Lei Z, et al. Journal of Materials Chemistry A, 2013, 1, 10546.
40 Singh S, Singh P, Viviani M, et al. International Journal of Hydrogen Energy, 2018, 43(41), 19242.
41 Huang Y Z, Chen J G, Dong J, et al. Rare Metal Materials and Enginee-ring, 2009, 38(S1), 178(in Chinese).
黄永珍, 程继贵, 董洁, 等. 稀有金属材料与工程, 2009, 38(S1), 178.
42 Wu D. Preparation and properties of lanthanum doped strontium titanate as anode material for solid oxide fuel cells. Master's Thesis, Jilin University, China, 2009 (in Chinese).
吴迪. 固体氧化物燃料电池阳极材料镧掺杂钛酸锶的制备和性能研究. 硕士学位论文,吉林大学,2009.
43 Li X, Zhao H L, Feng G, et al. Electrochemistry Communications, 2008, 10(10), 1567.
44 Huang X L, Zhao H L, Wei S, et al. Journal of Physics & Chemistry of Solids, 2006, 67(12), 2609.
45 Smith B H, Holler W C, Gross M D. Solid State Ionics, 2011, 192(1), 383.
46 Yang L, Stefan B, Falk S K, et al. Journal of the European Ceramic So-ciety, 2018, 38(15), 5058.
47 Steinsvik S,Bugge R,GjØnnes J, et al. Journal of Physics ＆ Chemistry of Solids, 1997, 58(6), 969.
48 Kharton V V, Kovalevsky A V, Viskup A P, et al. Journal of Solid State Chemistry,2001,156, 437.
49 E W J. Study on the properties of La and Cr double-doped SrTiO₃ anode materials. Master's Thesis, Harbin Institute of Technology, China, 2012(in Chinese).
鄂文晶. La和Cr双掺杂SrTiO₃阳极材料的性能研究. 硕士学位论文,哈尔滨工业大学,2012.
50 Lei S H, Fan H Q, Chen W N, et al. Journal of the American Ceramic Society, 2017, 100(1), 235.
51 Fagg D P, Kharton V V, Kovalevsky A V, et al. Journal of the European Ceramic Society, 2001, 21(10), 1831.
52 Fagg D P, Kharton V V, Frade J R, et al. Solid State Ionics, 2003, 156(1), 45.
53 Yoon J S, Yi E J, Choi B H, et al. Ceramics International, 2014, 40(1), 1525.
54 Yoon J S, Yoon M Y, Kwak C, et al. Materials Science and Engineering B, 2012, 177(2), 151.
55 Guo X M. Materials Letters, 2014, 121, 251.
56 Ma Q, Tietz F, Stöver D. Solid State Ionics, 2011, 192(1), 535.
57 Fu Q S, Mi S B, Wessel E, et al. Journal of the European Ceramic Society, 2008, 28(4), 811.
58 Zhao H L, Feng G, Li X, et al. Solid State Ionics, 2009, 180(2-3), 193.
59 Shan K, Guo X M. Materials Letters, 2013, 113, 126.
60 Shan K, Guo X M. Electrochimica Acta, 2015, 154, 31.
61 Luo D W, Xiao W D, Lin F, et al. Advanced Powder Technology, 2016, 27(2), 481.
62 Chen H L, Zhu T L, Chen X Y, et al. Journal of the Electrochemical Society, 2020, 167(16), 164507.
63 Puenjinda P, Muroyama H, Mastui T, et al. Journal of Power Sources, 2012, 204, 67.
64 Ma Q L, Iwanschitz B, Dashjav E, et al. Solid State Ionics, 2014, 262(9), 465.
65 Neagu D, Tsekouras G, Miller D N, et al. Nature Chemistry, 2013, 5, 916.
66 Neagu D, Oh T S, Miller D N, et al. Nature Communications, 2015, 6, 8120.
67 Li S S, Li Y X, Yun G, et al. Journal of Power Sources, 2012, 218, 244.
68 Xie K, Zhang Y Q, Meng G Y, et al. Energy and Environmantal Science, 2011, 4(6), 2218.
69 Cao Z Q, Wei B, Miao J P, et al. Electrochemistry Communications, 2016, 69, 80.
70 Dogu D, Gunduz S, Meter K E, et al. Catalysis Letters, 2019, 149(7), 1743.
71 Yang X X, Sun K N, Ma M J, et al. Applied Catalysis B: Environmental, 2020, 272, 118968.
72 Zhang L Y, Wang Z H, Cao Z Q, et al. International Journal of Hydrogen Energy, 2017, 42(17), 12104.
73 Zhang L Y, Zhu X B, Cao Z Q, et al. Electrochimica Acta, 2017, 232, 542.
74 Zhang L J. Study on the performance of solid oxide electrolytic cell with Pr_0.3Sr_0.7Ti_0.3Fe_0.7O_3-δ cathode. Master's Thesis, Harbin Institute of Technology, China, 2017(in Chinese).
张丽娟. 应用Pr_0.3Sr_0.7Ti_0.3Fe_0.7O_3-δ 阴极的固体氧化物电解池性能研究.硕士学位论文,哈尔滨工业大学,2017.
75 Qi W T, Ruan C, Wu G J, et al. International Journal of Hydrogen Energy, 2014, 39(11), 5485.
76 Zhang J, Xie K, Gan Y, et al. New Journal of Chemistry, 2014, 38(8), 88.
77 Qin Q Q, Wu G J, Chen S G, et al. Electrochimica Acta, 2014, 127, 215.
78 Gan Y, Qin Q Q, Chen S G, et al. Journal of Power Sources, 2014, 245, 245.
79 Canales-Vazquez J, Ruiz-Morales J C, Marrero-Lcpez D, et al. Journal of Power Sources, 2007, 171(2), 552.
80 Martinez-Coronado R, Agudero A, Perez-Coll D, et al. International Journal of Hydrogen Energy, 2012, 37(23), 18310.
81 Rath M, Kossenko A, Michael Z, et al. Journal of Power Sources, 2020, 476, 228630.
82 Niu B B, Jin F J, Zhang L L, et al. Electrochimica Acta, 2018, 263, 217.
83 Molin S, Lewandowska-Iwaniak W, Kusz B,et al. Journal of Electroceramics, 2012, 28(1), 80.
84 Zhao H, Teng D Q, Zhang X H, et al. Journal of Power Sources, 2009, 186(2), 305.
85 Xu J, Zhou X L, Pan L, et al. Journal of Power Sources, 2017, 371, 1.
86 Xu J, Zhou X L, Cheng J H, et al. Electrochimica Acta, 2017, 257, 64.
87 Cao Z Q, Zhang Y H, Miao J P, et al. International Journal of Hydrogen Energy, 2015, 40(46), 16572.
88 Fu L, Zhou J, Yang J M, et al. Materials Letters, 2020, 279, 128503.
89 Niu B B, Lu C L, Yi W D, et al. Applied Catalysis B: Environmental, 2020, 270, 118842.
90 Ling Y H, Chen L Y, Lin B, et al. RSC Advances, 2015, 5(22), 17000.