铁素体合金表面复合尖晶石涂层的研究进展

doi:10.11896/cldb.20090087

Abstract
Figure/Table
References
Related Citation (1)

Download:

Full Text ( PDF ) (3632KB)
Export: BibTeX | EndNote (RIS)

Abstract Solid oxide fuel cells (SOFC) have been widely studied in recent years because they can efficiently use fossil fuels and also collect gas and waste heat. The interconnect is one of the key components of the SOFC, which directly affects the long-term stability of the stack. At present, the ferritic stainless steel is one of the most important interconnect materials, which has advantages of high thermal conductivity, suitable coefficient of thermal expansion, and so on. However, its applications are still limited by several problems such as cathode Cr poisoning, poor electrical conductivity and insufficient oxidation resistance at high temperature. The normal solution is to prepare protective coatings on the surface of the ferritic stainless steel, such as reactive element oxides (REOs) coatings, rare earth perovskite coatings, composite spinel coatings, etc. Composite spinel coatings are generally considered to be the most promising SOFC interconnect coatings. The research and performance optimization of composite spinel coatings mainly focus on the composition, preparation technology and interconnect. In terms of composition, it is found that Cu-Mn spinel coating has the highest electrical conductivity, while Co-Mn spinel has the best comprehensive performance considering the electrical conductivity, coefficient of thermal expansion (CTE), area specific resistance (ASR), oxidation rate constant (K_p) and other parameters. At the same time, the electrical conductivity of coatings can be improved by the doping of copper or iron, while the electrical resistance can be reduced and the high-temperature oxidation resistance can be improved by the doping of REOs. In terms of preparation technology, the coatings prepared by electrophoretic deposition, magnetron sputtering and other methods, have superior performance which are uniform and dense and adhere well to the surface of the substrate. In terms of the metallic interconnect, the performance of coatings is more stable, when the interconnect has less concave and flatter surface.
In this paper, the recent works on composite spinel protective coatings for SOFC metallic interconnects are summarized in detail. The optimization methods of coatings are discussed in terms of composition, preparation technology and metallic interconnect, and the direction of the development is predicted. This work can provide guidance for promoting the industrial application of metallic interconnects.

Key words： solid oxide fuel cell (SOFC) ferritic stainless steel composite spinel protective coatings performance optimization

Published: 10 September 2022 Online: 2022-09-10

CLC number:

TG174.44

Fund:supported by National Natural Science Foundation of China (51871158), Shanxi Applied and Basic Research Program (201801D121084), and UIT of Shanxi Province (2019359).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	YU Hongli
	YANG Honghao
	MA Zhangbo
	ZHANG Yuanshuo
	YANG Wen
	LI Yongtang

Cite this article:

YU Hongli,YANG Honghao,MA Zhangbo, et al. Composite Spinel Protective Coating for Ferritic Stainless Steel: a Review[J]. Materials Reports, 2022, 36(17): 20090087-8.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20090087 OR http://www.mater-rep.com/EN/Y2022/V36/I17/20090087

1 Zhang W W. Electrophoresis deposition of (Mn,Co)₃O₄ coating and study of characteristics. Master's Thesis, Kunming University of Science and Technology, China, 2013 (in Chinese).
张卫伟. 电泳沉积(Mn,Co)₃O₄涂层制备及其特性的研究. 硕士学位论文, 昆明理工大学, 2013.
2 Zhang H. Elements diffusion and optimization design of protective coatings for SOFC metallic interconnects. Master's Thesis, Harbin Institute of Technology, China, 2012 (in Chinese).
张辉. 固体氧化物燃料电池连接板保护膜扩散研究与优化设计. 硕士学位论文, 哈尔滨工业大学, 2012.
3 Zhang L Z. Study of electrodeposited Ni-Co alloy coating on ferritic stainless steel. Master's Thesis, Northeastern University, China, 2012 (in Chinese).
张琳珠. 铁素体不锈钢表面电镀Ni-Co合金涂层的研究. 硕士学位论文, 东北大学, 2012.
4 Hua B. Oxidation, conductivity and surface modification of metallic interconnect materials for solid oxide fuel cells. Ph.D. Thesis, Huazhong University of Science and Technology, China, 2010 (in Chinese).
华斌. 固体氧化物燃料电池金属连接体材料的氧化和导电性以及表面改性. 博士学位论文, 华中科技大学, 2010.
5 Wu Y S. LCO-based proton conducting electrolyte and related materials of solid oxide fuel cells. Ph.D. Thesis, University of Science and Technology of China, China, 2019 (in Chinese).
武煜森. 固体氧化物燃料电池LCO基质子传导电解质及相关材料研究. 博士学位论文, 中国科学技术大学, 2019.
6 Gao Z, Mogni V L, Miller C E, et al. Energy & Environmental Science, 2016, 9, 1602.
7 Mahato N, Banerjee A, Gupta A, et al. Progress in Materials Science, 2015, 72, 141.
8 Gao B. The research of preparation processes of Y-doped CuMn₂O₄ coa-ting for SOFC alloy interconnect. Master's Thesis, Chang'an University, China, 2019 (in Chinese).
高彬. SOFC合金连接体Y掺杂CuMn₂O₄涂层制备工艺研究. 硕士学位论文, 长安大学, 2019.
9 Wang A Q. Study on preparation and characterization of Mn/Co protective coatings for SOFC interconnect. Master's Thesis, Harbin Institute of Technology, China, 2011 (in Chinese).
王安祺. SOFC金属连接体Mn/Co保护膜层的制备及其性能研究. 硕士学位论文, 哈尔滨工业大学, 2011.
10 Shaigan N, Qu W, Ivey G D, et al. Journal of Power Sources, 2010, 195, 1529.
11 Zhang H. Study on compatibility of new ceramic interconnects with SOFC electrode materials. Master's Thesis, Qingdao University, China, 2019 (in Chinese).
张昊. 新型陶瓷连接体材料与SOFC电极材料相容性研究. 硕士学位论文, 青岛大学, 2019.
12 Mah C W J, Muchtar A, Somalu R M, et al. International Journal of Hydrogen Energy, 2017, 42, 9219.
13 Zhang H, Zhan Z L, Liu X B. Journal of Power Sources, 2011, 196, 8041.
14 Li Y L, Song J L, Zhu J H, et al. Electropating & Finishing, 2019, 38(13), 647 (in Chinese).
李晔珑, 宋建丽, 朱家红, 等. 电镀与涂饰, 2019, 38(13), 647.
15 Li Y L, Song J L, Zhu J H, et al. Materials Protection, 2019, 52(7), 75 (in Chinese).
李晔珑, 宋建丽, 朱家红, 等. 材料保护, 2019, 52(7), 75.
16 Hua B, Kong Y H, Lu F S, et al. Chinese Science Bulletin,2010, 55(33), 3831.
17 Jia C, Wang Y H, Molin S, et al. Journal of Alloys and Compounds, 2019, 787, 1327.
18 Smeacetto F, Miranda D A, Polo C S, et al. Journal of Power Sources, 2015, 280, 379.
19 Molin S, Sabato G A, Javed H, et al. Materials Letters, 2018, 218, 329.
20 Brylewski T, Kruk A, Bobruk M, et al. Journal of Power Sources, 2016, 333, 145.
21 Xiao J H, Zhang W Y, Xiong C Y, et al. International Journal of Hydrogen Energy, 2016, 41, 9611.
22 Xu Y J, Wen Z Y, Wang S R, et al. Solid State Ionics, 2011, 192, 561.
23 Bednarz M, Molin S, Bobruk M, et al. Materials Chemistry and Physics, 2019, 225, 227.
24 Zanchi E, Molin S, Sababto G A, et al. Journal of Power Sources, 2020, 455, 227910.
25 Mosavi A, Ebrahimifar H. International Journal of Hydrogen Energy, 2020, 45(4), 3145.
26 Lewis J M. Synthesis and evaluation of electrolytically-deposited coatings to protect ferritic stainless steels for solid oxide fuel cell interconnect application. Master's Thesis, Tennessee Technological University, USA, 2011.
27 Gavrilov V N, Ivanov V V, Kamenetskikh S A, et al. Surface & Coatings Technology, 2011, 206, 1252.
28 Balland A, Gannon P, Deibert M, et al. Surface & Coatings Technology, 2009, 203, 3291.
29 Tseng H P, Yung T Y, Liu C K, et al. International Journal of Hydrogen Energy, 2020, 45, 12555.
30 Ranjbar-Nouri Z, Soltanieh M, Rastegari S. Surface & Coatings Technology, 2018, 334, 365.
31 Geng S J, Zhao Q Q, Li Y H, et al. International Journal of Hydrogen Energy, 2017, 42, 10298.
32 Sun Z H, Gopalan S, Pal B U, et al. Surface & Coatings Technology, 2017, 323, 49.
33 Sun Z H, Wang R F, Nikiforov Y A, et al. Journal of Power Sources, 2018, 378, 125.
34 Wang R F, Sun Z H, Pal B U, et al. Journal of Power Sources, 2018, 376, 100.
35 Guo P Y, Lai Y B, Shao Y, et al. Metals, 2017, 7(12), 522.
36 Zhang L L. Preparation and high temperature properties of Cu-Mn spinel coatings. Master's Thesis, Xi'an University of Science and Technology, China, 2017 (in Chinese).
张路路. Cu-Mn尖晶石涂层的制备与高温性能的研究. 硕士学位论文, 西安科技大学, 2017.
37 Joshi S, Silva C, Wang P, et al. Journal of the Electrochemical Society, 2014, 161(3), 233.
38 Joshi S, Petric A. International Journal of Hydrogen Energy, 2017, 42(8), 5584.
39 Geng S J, Li Y D, Ma Z H, et al. Journal of Power Sources, 2010, 195, 3256.
40 Zhao Q Q, Geng S J, Chen G, et al. Journal of Alloys and Compounds, 2018, 769, 120.
41 You P F, Zhang X, Zhang H L, et al. International Journal of Hydrogen Energy, 2018, 43, 7492.
42 You P F, Zhang X, Zhang H L, et al. Oxidation of Metals, 2020, 93, 465.
43 Zhang X, You P F, Zhang H L, et al. International Journal of Hydrogen Energy, 2018, 43, 3273.
44 Zhao Z Y. The preparation and performance study of NiMn₂O₄ coating on the rare earth modified Fe-Cr ferritic alloy interconnection for SOFC. Master's Thesis, Chang'an University, China, 2015 (in Chinese).
赵之彧. SOFC稀土改性Fe-Cr合金连接体NiMn₂O₄涂层的制备及性能研究. 硕士学位论文, 长安大学, 2015.
45 Hua B, Zhang W Y, Wu J, et al. Journal of Power Sources, 2010, 195, 7375.
46 Zhu H M, Geng S J, Chen G, et al. Journal of the Electrochemical Society, 2020, 167(4), 041506.
47 Jalilvand G, Faghihi-Sani M. International Journal of Hydrogen Energy, 2013, 38, 12007
48 Hosseini N S, Karimzadeh F, Enayati H M, et al. Solid State Ionics, 2016, 289, 95
49 Pan Y, Geng S J, Chen G, et al. Corrosion Science, 2020, 170, 108680.
50 Masi A, Bellusci M, McPhail J S, et al. Journal of the European Ceramic Society, 2017, 37(2), 661.
51 Talic B, Wulff C A, Molin S, et al. Surface & Coatings Technology, 2019, 380, 125093.
52 Miguel-Pérez V, Martínez-Amesti A, Nó L M, et al. Corrosion Science, 2012, 60, 38.
53 Öztürk B, Topcu A, Öztürk S, et al. International Journal of Hydrogen, 2018, 43, 10822.