镧系金属有机框架化合物在发光传感检测领域的研究进展

doi:10.11896/cldb.21030231

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Abstract Lanthanide metal-organic frameworks (Ln-MOFs) are porous crystalline materials composed of lanthanide metal ions and organic ligands by coordination bonding interactions. They are a novel group of functional sensing materials that have been increasingly developed in recent years. Ln-MOFs possess advantages in constructing luminescent sensors with high selectivity and sensitivity due to their excellent features such as high specific surface area, adjustable pore size, controllable structure and broad application prospects, which have been attracting the growing interests of numerous researchers.
Furthermore, high coordination and charge number of lanthanide metal ions make it accessible to combine with oxygen or nitrogen provided by the ligands. Except for La³⁺ and Lu³⁺, the incompletely filled 4f electron layer structures of other Ln³⁺ can produce f-f or f-d transition emissions. The synergistic effect of ionic centers and the ligands can be used for the synthesis of multiple Ln-MOFs with excellent luminescent performance and diverse structures. Permanent holes of Ln-MOFs can accommodate various guest substances interacting with the framework. The perturbation of the external environment and the presence of guest substances will change the light-emitting wavelength or intensity of Ln-MOFs, resulting in visible color changes to the naked eye. The ligands can be designed as light-emitting sites to promote a better sensing effect. The excellent structures and photoluminescence properties of Ln-MOFs provide an essential basis for the development of novel sensing materials.
The most common form of detection in Ln-MOFs is the light-induced emission quenching (turn off) and enhancement (turn on) caused by external environmental factors and detection substances. When the analyte and Ln-MOFs compete for energy, the energy transfer process is changed by interacting with ligand and analyte. Partial energy is transferred from the ligand to the analyte, which leads to the reduction of energy transfer efficiency and ultimately results in emission quenching. In case the analyte increases the rigidity of the framework structure, the efficiency of energy transfer and the luminescence intensity of Ln-MOFs will be effectively enhanced.
This paper focuses on recent research work and progress of Ln-MOFs on ions, pH, small organic molecules, nitroaromatic compounds, gas and temperature in luminescence sensing and detection. The selection and design of ligands, sensitivity, reusability and applicability in complex environments of Ln-MOFs have been prospected.

Key words： lanthanide metal-organic frameworks luminescence detection chemical sensing temperature

Published: 10 March 2023 Online: 2023-03-14

CLC number:

TB34

Fund:Yunnan Fundamental Research Projects-General Project (202201AT070206) and Top Young Talents of Yunnan Province Ten Thousand Talents Plan (109720190004).

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	LIU Weisai
	CHEN Xiaoyi
	ZHI Wenke
	WANG Xuquan
	WANG Fei

Cite this article:

LIU Weisai,CHEN Xiaoyi,ZHI Wenke, et al. Research Progress of Lanthanide Metal-Organic Frameworks in the Field of Luminescence Sensing and Detection[J]. Materials Reports, 2023, 37(5): 21030231-12.

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http://www.mater-rep.com/EN/10.11896/cldb.21030231 OR http://www.mater-rep.com/EN/Y2023/V37/I5/21030231

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