METALS AND METAL MATRIX COMPOSITES |
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Research Status and Prospect of Separation and Enrichment Technology and Analysis Method of Rare Metal Ruthenium |
ZHANG Xiaoyan1,2 , CHEN Zhenbin1,2, LI Hui1,2, CHEN Yalan3, SUN Yuan4, LI Xiaoming5,6
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1 College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China 2 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China 3 School of Foreign Languages, Lanzhou University of Technology, Lanzhou 730050, China 4 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110000, China 5 Gansu Yinguang Chemical Industry Group Co.Ltd, Baiyin 730900, China 6 Baiyin Research Institute of Novel Materials of Lanzhou University of Technology, Baiyin 730900, China |
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Abstract Ruthenium (Ru),one of the platinum group metal elements, and always present with other platinum group metals, is studied less compared with the others. Because there are few mineral containing Ru and the contents of Ru in ores are very low, Ru becomes very expensive and is treated as a strategic resource, which makes the scope of application limited. However, with the rapid development of science and technology, the remarkable properties of Ru such as high hardness, high strength, excellent catalytic activity, high conductivity are discovered constantly and applied in fields like electronics, chemical industries, electrochemistry, aerospace etc, leading to the demand increasing quickly. The content of Ru is not only low in nature, but also a large amount of secondary resource Ru waste will be generated during the application process, which will inevitably lead to an imbalance between the supply and demand of ruthenium resources in China, and ultimately affect the development of China's science and technology and national security strategy. In recent times, however, there has been notable improvements in the development of the global precious metal recovery and reuse industry, a variety of efficient separation and recovery methods and precise detection technologies for ruthenium have also been developed, and are of great significance for achieving resource recycling, expanding the scope of application, controlling cost, and maintaining China's strategic security. After a long time of unremitting efforts, the separation and recovery methods and the detection techniques of Ru have achieved a relatively high level. According to reports, the most commonly adopted separation methods include ion exchange, extraction, adsorption, precipitation and ion imprinting, etc., and the detection methods include spectrophotometry, gravimetry, atomic absorption spectroscopy, X-ray fluorescence spectroscopy, and inductively coupled plasma-emission spectrometry, inductively coupled plasma-mass spectrometry, neutron activation method, chromatography and in-situ monitoring, etc. These technologies provide technical support for the research and application of China's circular economy and sustainable development. This paper reviews the research status of ruthenium in recent years, summarizes the existing separation and enrichment methods and analysis methods based on the current development status, and prospects the future separation and recovery technology and analysis methods of ruthe-nium, so as to provide reference for future research.
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Published: 10 December 2021
Online: 2021-12-23
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Fund:Joint Fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals (18LHZD003, 18LHPY004) |
Corresponding Authors:
zhenbinchen@163.com
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About author: Xiaoyan Zhang is currently pursuing a master's degree at the Institute of Materials, Lanzhou University of Technology, under the supervision of Prof. Zhenbin Chen. Her research has focused on separation and purification of rare and noble metals in superalloy scrap. Zhenbin Chen, is a professor of materials science at Lanzhou University of Technology. He obtained his Ph.D. degree at Lanzhou University from 2002 to 2007, and has taught at the School of Materials Science and Technology of Lanzhou University of Technology since 2007. During 2008—2011, he worked as a postdoctoral researcher at Lanzhou Compound of the Chinese Academy of Sciences. He has been engaged in the research of adsorption-separating functional polymer materials for a long time. He has completed one project of Gansu Natural Science Foundation and one funded master's tutor fund project of Gansu Provincial Education Department. He is a technical person in charge of the National Natural Science Foundation of China and two higher education institutions in Gansu Province. He has one basic research fund, one teaching achievement award from Gansu Provincial Education Department, and 2 patent applications, and published more than 50 papers, including 32 articles in SCI and EI. In 2012, he won the third prize of the “Kesen Kenen”, the third national college student energy conservation and emission reduction social practice and science and technology competition, the “Instructor Award” of the Lanzhou University of Technology graduation thesis, and the “Excellent Instructor” award of the Lanzhou University of Technology Student Business Plan Competition. He participated in the “polymer physics” national courseware production competition in 2013, and won the third price of the competition. |
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