金属镁的氧化及氧化机理研究进展

doi:10.11896/cldb.20040174

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Abstract As the lightest commercial metal structure material, magnesium alloy shows a wide application prospect in aerospace, automobile, 3C pro-ducts and other fields. At the same time, it is of great strategic significance to promote the application of magnesium alloy materials, in the face of the increasing shortage of iron and aluminum resources in the world and the dilemma of a large number of imported iron and aluminum ores.
Compared with common steel and aluminum alloy, the research and development of magnesium alloy are not enough, and its application is also limited. The poor corrosion resistance of magnesium alloy is partly due to the high chemical activity of magnesium and the lack of protective effect of the film formed on the surface. Especially at high temperature, magnesium and its alloys are easy to oxidize, even burn, and release a lot of heat, which has become one of the bottlenecks limiting the extensive application of magnesium alloys.
In recent years, a lot of researches have been carried out on the oxidation mechanism and influencing factors of magnesium and its alloys. It is considered that the oxidation of magnesium alloy is affected by factors, such as P-B value of oxide film, evaporation and diffusion of magnesium and so on. At present, the oxidation resistance of magnesium is improved by alloying. This provides theoretical support for the preparation of magnesium alloy with high oxidation resistance. At the same time, it expands the application prospect of magnesium alloy at high temperature, and will bring huge economic benefits to magnesium alloy industry.
This paper summarizes the research progress of oxidation characteristics and mechanism of magnesium and its alloys at home and abroad. Firstly, the oxidation of magnesium is briefly introduced. Secondly, the mechanism and influencing factors of magnesium oxidation are analyzed, and the influence rules and mechanism of P-B value, diffusion, evaporation, microstructure and alloy elements on the oxidation behavior of magnesium are emphatically discussed. Finally, the shortcomings of the current research are summarized, and suggestions on the research direction of magnesium oxidation resistance are put forward.

Key words： magnesium alloy oxidation characteristics oxidation mechanisms alloying element

Published: 03 November 2021

CLC number:

TB31

Fund:Dongguan Key Technology Key Project (2019622134013), Chongqing University Large-scale Instrument and Equipment Open Fund (201903150016, 202003150150).

About author:: Yue Ming received her M.S. degree from Chongqing University in 2016. She is currently pursuing her Ph.D. at the School of Materials Science and Enginee-ring, Chongqing University. She went to Lund University for joint training from 2020 to 2021. Her research has focused on oxidation mechanism of Magnesium alloy.
Guoqiang You received his Ph.D. degree from Chongqing University in 2007, and he visited University of Queensland, Australia from 2014 to 2015. Now, he is an associate professor and doctoral supervisor of the School of Materials Science and Engineering, Chongqing University. He is currently the research backbone of the National Magnesium Alloy Materials Engineering Technology Research Center, a member of the National Foundry Standardization Technical Committee, the deputy director of the Chongqing Engineering Laboratory of Cash Casting, and a member of the 10th Composite Materials Technical Committee of the China Mechanical Engineering Degree Casting Branch. He has been engaged in the research of high-performance Magnesium alloy machine for-ming technology for a long time, and has obtained a large number of innovative research results, and has published more than 60 papers in related fields.

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	MING Yue
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	YAO Fanjin
	ZENG Sheng
	ZHAO Jianhua
	LI Weirong

Cite this article:

MING Yue,YOU Guoqiang,YAO Fanjin, et al. Research Progress on Oxidation and Oxidation Mechanism of Magnesium[J]. Materials Reports, 2021, 35(19): 19134-19141.

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http://www.mater-rep.com/EN/10.11896/cldb.20040174 OR http://www.mater-rep.com/EN/Y2021/V35/I19/19134

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