锆基金属-有机骨架呼吸道防护材料研究进展

doi:10.11896/cldb.19090073

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Abstract During the process of combat, emergency rescue and accident handling, both chemical warfare agents (CWAs) and toxic industrial chemicals (TICs) diffusion will pose a serious threat to the breathing safety of personnel. Therefore, the respirators are required to provide broad-spectrum protection against CWAs and TICs at the same time. The activated carbon impregnated with copper, silver, zinc, molybdenum, and triethy-lenediamine, known as the ASZM-TEDA carbon, is the main protection material used in current gas masks for military and emergency response personnel. Although a variety of chemicals are added, the ASZM-TEDA carbon still has some limitations such as poor protection performance against TICs and a high risk of physically adsorbed toxic molecules releasing at room temperature. It is thus urgent to develop novel respiratory protection materials with broad-spectrum protection and in-situ degradation capabilities against both CWAs and TICs.
Metal-organic frameworks (MOFs), characterized by their huge specific surface areas, diverse structures and on-demand modular design, are considered as the novel respiratory protection materials with the greatest potential to achieve broad-spectrum protection and in-situ degradation against toxic chemicals. In recent years, the zirconium-based metal-organic frameworks (Zr-MOFs) have been extensively studied due to their high specific surface areas, various surface active sites, remarkable stabilities, as well as excellent CWAs/TICs adsorption and catalytic degradation performance.
In terms of Zr-MOFs used for the adsorption removal of CWAs and TICs, current research work mainly focuses on UiO-66-NH₂. Researchers have systematically studied the adsorption properties of UiO-66-NH₂ powders and granules. They found that UiO-66-NH₂ powders shows excellent intrinsic adsorption capacities for many TICs, such as NH₃, Cl₂, and NO₂. The hierarchical structure was further developed in UiO-66-NH₂ to increase the diffusion rates of toxic molecules through the pores of UiO-66-NH₂ granules. In terms of Zr-MOFs used for the catalytic degradation of CWAs and TICs, current research work mainly focuses on a series of Zr-MOFs with different node connectivity. By optimizing the pore size, node connectivity and types of organic ligands, researchers have effectively regulated the catalytic degradation performance of Zr-MOFs against toxic chemicals. They further investigated the catalytic degradation behavior of toxic chemicals in heterogeneous buffer and pure liquid environment, so as to promote the practical application of Zr-MOFs as protection materials.
This review focuses on the Zr-MOFs respiratory protection materials. Based on analysis of the structures and surface chemistry of Zr-MOFs, this paper summarized the research progress on the application of Zr-MOFs in toxic chemicals adsorption and degradation. The structure-activity relationship of Zr-MOFs respiratory protection materials was discussed and the future research trend was also prospected.

Key words： zirconium metal-organic frameworks chemical warfare agents toxic industrial chemicals respiratory protection adsorption catalytic degradation

Published: 24 December 2020

CLC number:	TB34
	TJ92

Fund:This work was financially supported by the National Key Research and Development Project (2016YFC0204205), National Natural Science Foundation of China (21876204), Foundation of State Key Laboratory of NBC Protection for Civilian (SKLNBC2018-04).

About author:: Xinbo Wang received his B.S. degree in chemistry from University of Science and Technology of China in 2015 and received his M.S. degree in environmental engineering from the Academy of Military Science in 2018. He is currently pursuing his Ph.D. degree at the Academy of Military Science under the supervision of Prof. Hailing Xi and A/Prof. Kai Li. His research has focused on metal-organic frameworks respiratory protection materials.
Kai Li received his B.S. degree in applied chemistry from National University of Defense Technology in 1998 and received his Ph.D. degree in environmental engineering from the Research Institute of Chemical Defense in 2006. He is currently an associate professor at the Academy of Military Science. His research interests are porous materials, including activated carbons, carbon foams, molecular sieves, aerogels and metal-organic frameworks, for thermal management and chemical, biological, radiological and nuclear (CBRN) defense.
Hailing Xi received her B.S. degree in chemistry from Lanzhou University in 1985 and received her M.S. degree in Military Chemistry and Pyrotechnics from the Research Institute of Chemical Defense in 1988. She is currently a full professor at the Academy of Military Science. In 2016, she was appointed as the Deputy President of the Research Institute of Chemical Defense. In 2018, she was appointed as the director of the State Key Laboratory of NBC Protection for Civilian. Her research interests include CBRN defense, military environmental science and technology, porous materials, ionic liquid and photocatalysis.

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	WANG Xinbo
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Cite this article:

WANG Xinbo,SU Ruyue,LI Li, et al. Research Progress on Zirconium-based Metal-organic Frameworks Respiratory Protection Materials[J]. Materials Reports, 2020, 34(23): 23121-23130.

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http://www.mater-rep.com/EN/10.11896/cldb.19090073 OR http://www.mater-rep.com/EN/Y2020/V34/I23/23121

1 Kim K, Tsay O G, Atwood D A, et al. Chemical Reviews,2011,111(9),5345.
2 Hincal F, Erkekoglu P. FABAD Journal of Pharmaceutical Sciences,2006,31(4),220.
3 Zhou L L, Tang L H, Ning P, et al. Materials Reports A: Review Papers,2017,31(10),112(in Chinese).
周玲玲,汤立红,宁平,等.材料导报:综述篇,2017,31(10),112.
4 Khan N A, Hasan Z, Jhung S H. Journal of Hazardous Materials,2013,244-245,444.
5 Decoste J B, Peterson G W. Chemical Reviews,2014,114(11),5695.
6 Bobbitt N S, Mendonca M L, Howarth A J, et al. Chemical Society Reviews,2017,46(11),3357.
7 Liu Y, Howarth A J, Vermeulen N A, et al. Coordination Chemistry Reviews,2017,346,101.
8 Vellingiri K, Philip L, Kim K H. Coordination Chemistry Reviews,2017,353,159.
9 Kim K C. Journal of Organometallic Chemistry,2018,854,94.
10 Hönicke I M, Senkovska I, Bon V, et al. Angewandte Chemie International Edition,2018,57(42),13780.
11 Li S, Han K, Li J, et al. Microporous and Mesoporous Materials,2017,243,291.
12 Teo E Y L, Muniandy L, Ng E P, et al. Electrochimica Acta,2016,192,110.
13 Britt D, Tranchemontagne D, Yaghi O M. Proceedings of the National Academy of Sciences,2008,105(33),11623.
14 Peterson G W, Mahle J J, Balboa A, et al. Evaluation of metal-organic frameworks for the removal of toxic industrial chemicals, Edgewood Chemical Biological Center Aberdeen Proving Ground, USA,2008.
15 Peterson G W, Rossin J A. Impregnated metal-organic frameworks for the removal of toxic industrial chemicals, Edgewood Chemical Biological Center Aberdeen Proving Ground, USA,2008.
16 Glover T G, Peterson G W, Schindler B J, et al. Chemical Engineering Science,2011,66(2),163.
17 Peterson G W, Wagner G W, Balboa A, et al. The Journal of Physical Chemistry C,2009,113(31),13906.
18 Peterson G W, Wagner G W. Journal of Porous Materials,2014,21(2),121.
19 Decoste J B, Denny Jr M S, Peterson G W, et al. Chemical Science,2016,7(4),2711.
20 Peterson G W, Browe M A, Durke E M, et al. ACS Applied Materials & Interfaces,2018,10(49),43080.
21 Kim M, Cohen S M. CrystEngComm,2012,14(12),4096.
22 Bai Y, Dou Y, Xie L H, et al. Chemical Society Reviews,2016,45(8),2327.
23 Rimoldi M, Howarth A J, Destefano M R, et al. ACS Catalysis,2017,7(2),997.
24 Drout R J, Robison L, Chen Z, et al. Trends in Chemistry,2019,1(3),304.
25 Cavka J H, Jakobsen S, Olsbye U, et al. Journal of the American Chemical Society,2008,130(42),13850.
26 Bárcia P S, Guimarães D, Mendes P A P, et al. Microporous and Mesoporous Materials,2011,139(1),67.
27 Karwacki C J, Browe M A, Mahle J J, et al. Baselining structure-reactivity relationships for selected metal-organic framework and metal oxide catalysts for adsorption and decomposition, Edgewood Chemical Biological Center Aberdeen Proving Ground, USA,2018.
28 Katz M J, Brown Z J, Colón Y J, et al. Chemical Communications,2013,49(82),9449.
29 Mondloch J E, Bury W, Fairen-Jimenez D, et al. Journal of the American Chemical Society,2013,135(28),10294.
30 Feng D, Gu Z Y, Li J R, et al. Angewandte Chemie International Edition,2012,51(41),10307.
31 Furukawa H, Gándara F, Zhang Y B, et al. Journal of the American Chemical Society,2014,136(11),4369.
32 Jiang J, Gándara F, Zhang Y B, et al. Journal of the American Chemical Society,2014,136(37),12844.
33 Burtch N C, Jasuja H, Walton K S. Chemical Reviews,2014,114(20),10575.
34 Howarth A J, Liu Y, Li P, et al. Nature Reviews Materials,2016,1(3),1.
35 Decoste J B, Peterson G W, Schindler B J, et al. Journal of Materials Chemistry A,2013,1(38),11922.
36 Kandiah M, Nilsen M H, Usseglio S, et al. Chemistry of Materials,2010,22(24),6632.
37 Cmarik G E, Kim M, Cohen S M, et al. Langmuir,2012,28(44),15606.
38 Cohen S M. Chemical Reviews,2012,112(2),970.
39 Deria P, Mondloch J E, Karagiaridi O, et al. Chemical Society Reviews,2014,43(16),5896.
40 Petit C, Bandosz T J. Advanced Materials,2009,21(46),4753.
41 Yang Q, Xu Q, Jiang H L. Chemical Society Reviews,2017,46(15),4774.
42 Ghosh P, Colón Y J, Snurr R Q. Chemical Communications,2014,50(77),11329.
43 Gutov O V, Hevia M G, Escudero-Adán E C, et al. Inorganic Chemistry,2015,54(17),8396.
44 Shearer G C, Chavan S, Bordiga S, et al. Chemistry of Materials,2016,28(11),3749.
45 Wu H, Chua Y S, Krungleviciute V, et al. Journal of the American Chemical Society,2013,135(28),10525.
46 Peterson G W, Destefano M R, Garibay S J, et al. Chemistry-A European Journal,2017,23(63),15913.
47 Klet R C, Liu Y, Wang T C, et al. Journal of Materials Chemistry A,2016,4(4),1479.
48 Jasuja H, Peterson G W, Decoste J B, et al. Chemical Engineering Science,2015,124,118.
49 Decoste J B, Browe M A, Wagner G W, et al. Chemical Communications,2015,51(62),12474.
50 Peterson G W, Mahle J J, Decoste J B, et al. Angewandte Chemie International Edition,2016,55(21),6235.
51 Peterson G W, Decoste J B, Glover T G, et al. Microporous and Mesoporous Materials,2013,179,48.
52 Peterson G W, Decoste J B, Fatollahi-Fard F, et al. Industrial & Engineering Chemistry Research,2014,53(2),701.
53 Browe M A, Napolitano A, Decoste J B, et al. Journal of Hazardous Materials,2017,332,162.
54 Decoste J B, Rossin J A, Peterson G W. Chemistry-A European Journal,2015,21(50),18029.
55 Wong K Y, Gao J. Biochemistry,2007,46(46),13352.
56 Bigley A N, Raushel F M. Biochimica et Biophysica Acta (BBA)-Proteins and Proteomics,2013,1834(1),443.
57 Katz M J, Mondloch J E, Totten R K, et al. Angewandte Chemie International Edition,2014,53(2),497.
58 Katz M J, Moon S Y, Mondloch J E, et al. Chemical Science,2015,6(4),2286.
59 Islamoglu T, Ortuño M A, Proussaloglou E, et al. Angewandte Chemie International Edition,2018,57(7),1949.
60 Moon S Y, Wagner G W, Mondloch J E, et al. Inorganic Chemistry,2015,54(22),10829.
61 Peterson G W, Moon S Y, Wagner G W, et al. Inorganic Chemistry,2015,54(20),9684.
62 Mondloch J E, Katz M J, Isley III W C, et al. Nature Materials,2015,14(5),512.
63 Li P, Klet R C, Moon S Y, et al. Chemical Communications,2015,51(54),10925.
64 Moon S Y, Liu Y, Hupp J T, et al. Angewandte Chemie International Edition,2015,54(23),6795.
65 Yang Y C, Baker J A, Ward J R. Chemical Reviews,1992,92(8),1729.
66 Giannakoudakis D A, Bandosz T J. Detoxification of chemical warfare agents, Springer, USA,2018.
67 Liu Y, Howarth A J, Hupp J T, et al. Angewandte Chemie International Edition,2015,54(31),9001.
68 Liu Y, Moon S Y, Hupp J T, et al. ACS Nano,2015,9(12),12358.
69 Liu Y, Buru C T, Howarth A J, et al. Journal of Materials Chemistry A,2016,4(36),13809.
70 Moon S Y, Proussaloglou E, Peterson G W, et al. Chemistry-A European Journal,2016,22(42),14864.
71 Ryu S G, Kim M K, Park M, et al. Microporous and Mesoporous Mate-rials,2019,274,9.
72 Wang H, Mahle J J, Tovar T M, et al. ACS Applied Materials & Interfaces,2019,11(23),21109.