激光加工制备金属基体超疏水表面的研究进展

doi:10.11896/cldb.19090218

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Abstract Metal materials are widely used, but are susceptible to corrosion. The super-hydrophobic coating prepared on the surface of the metal substrate can corrode the corrosive medium and improve the corrosion resistance and stain resistance of the metal. In addition, the super-hydrophobic coating can also be applied in anti-icing and antibacterial applications, giving the metal material a wider range of functions and application scenarios.
In order to achieve superhydrophobicity, firstly, low surface free energy is required, so that the droplets are not easily spread on the surface; secondly, it is necessary to construct a rough micro-nano structure in order to retain air and increase the gas-liquid contact area. There are many methods for preparing superhydrophobic coatings, but many conventional processing methods are not suitable due to the high hardness of the metal materials and the high melting point. For metal materials, common superhydrophobic surface preparation methods are: chemical etching, electrochemical methods, hydrothermal methods, vapor deposition, and so on. However, these methods have poor controllability and stability, and it is often difficult to process the desired surface structure. As a method for preparing super-hydrophobic surface, laser etching has the cha-racteristics of environmental protection, controllability and stability. It can directly form specific micro-nano structures on the surface and is suitable for metal material processing and has received extensive attention in recent years.
Different laser processing parameters and scanning paths can be used to machine different surface micro-nano structures. Research on the effects of various laser processing parameters on surface structure has been carried out. Common laser processing parameters include: spot parameters, energy density, number of pulses, scanning speed, scanning pitch, and spot lap rate. These parameters will have different effects on the surface structure. At present, surface micro-nanostructures prepared by laser using good hydrophobic properties include micro-square column structure, micro-mesh structure, micro-groove structure, micro-sinusoidal protrusion structure, Gaussian lattice structure, and laser-induced periodic surface structure.
Based on the theory of super-hydrophobicity, this paper introduces the influence of various laser parameters on the surface structure, the characteristics and hydrophobic properties of different micro-nanostructures, and the surface treatment after etching. Finally, this paper summarizes the main points of laser preparation of super-hydrophobic surface of metal matrix, and sorts out some existing problems.

Key words： laser etching super-hydrophobic metal matrix process parameters micro/nano structure

Published: 24 December 2020

CLC number:

TN24

Fund:This work was financially supported by the Frontier Exploration Project of National Defense Science and Technology Innovation Zone of China(19-163-21-TS-001-009-01), and National Defense Science and Technology Foundation Strengthening Program Technology Field Fund Project of China(2020-JCJQ-JJ-378).

About author:: Boyuan Zheng, graduated from China University of Geosciences (Beijing) in 2017 with a bachelor’s degree, and is currently pursuing a master’s degree at China University of Geosciences (Beijing). His main research areas are superhydrophobic materials.
Yuelan Di, Ph.D., assistant researcher, born in 1986. Her research direction is surface engineering and rema-nufacturing engineering.
Haidou Wang, received his Ph.D. degree in Department of Mechanical Engineering from Tsinghua University in 2003. He joined the National Key Laboratory for Remanufacturing at Academy of Army Armored Forces from then on. He is a professor and the deputy director of the laboratory. His current research areas cover the surface engineering, remanufacturing and tribology, especially in service life evaluation of surface coatings and solid film lubrication.

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	ZHENG Boyuan
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Cite this article:

ZHENG Boyuan,DI Yuelan,WANG Haidou, et al. Research Progress in Preparation of Super-hydrophobic Surface of Metal Matrix by Laser Processing[J]. Materials Reports, 2020, 34(23): 23109-23120.

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http://www.mater-rep.com/EN/10.11896/cldb.19090218 OR http://www.mater-rep.com/EN/Y2020/V34/I23/23109

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