金属有机框架衍生物的制备及催化性能的研究进展

doi:10.11896/cldb.19040055

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Abstract The replacement of precious metal catalysts by non-precious metal catalysts has become a trend, but the catalytic activity of non-precious metals is difficult to meet demand. Metal-organic frameworks (MOFs) are organic-inorganic hybrid materials with clear crystal structure, adjustable topology, ultra-high surface area, and excellent customizability. The advantages of high specific surface area, adjustable structure, and porosity make MOFs materials show great development potential in the field of catalysis.
Porous carbon catalyst obtained by pyrolyzing metal-organic frameworks is a very promising catalyst. Pyrolysis not only activates metal ions, but also improves the stability of MOFs. The pyrolysis methods of MOFs can be roughly divided into direct pyrolysis, first load reheating, and MOFs composite pyrolysis. Direct pyrolysis is the simplest method for preparing porous carbon catalysts, but its catalytic effect is inferior to that of noble metal catalysts. Load pyrolysis is divided into pyrolysis after hot-dip and post-vapor deposition, and pyrolysis after wet impregnation can improve the type and content of the metal in the material, and further enhance the catalytic effect. The reaction oconditions of pyrolysis after vapor deposition are harsh and cannot be popularized. Combination of MOFs and other materials is an effective method to improve the stability of MOFs. The composites have excellent catalytic effects after pyrolysis.
The unique properties of MOFs have been gain increasing attention. At present, researchers prepared porous carbon catalysts such as monometallic, bimetallic, doped heteroatoms and composite materials. Furthermore, the catalytic properties and cycle stability were also explored.
This paper systematically reviews the preparation methods of MOFs and their derivatives, and their latest developments as porous carbon catalysts. Finally, the problems existing in the current research are pointed out and the future research directions are prospected.

Key words： metal organic framework pyrolysis catalyst

Published: 13 May 2020

CLC number:

TB34

Fund:This work was financially supported by National Natural Science Foundation of China(21666011).

About author:: Bo Hao, graduated from Northwest Minzu University in June 2018 with a bachelor degree in engineering. He is currently a master student in the Faculty of Chemical Engineering of Kunming University of Science and Technology. He is conducting research under the gui-dance of Professor Wenbo Zhao. His research has focused on metal-organic framework catalyzed epoxy compounds.
Wenbo Zhao is a professor and Ph.D. tutor in the Fa-culty of Chemical Engineering of Kunming University of Science and Technology. The first batch of "top ten thousand people" young talents in Yunnan Province He received his Ph.D. from the Institute of Coal Chemistry, Chinese Academy of Sciences in 2009. Mainly engaged in research and development of acid gas capture and utilization, molecular design of phase change solvents and green catalytic synthesis. As project leader, he presided over 2 projects of the National Natural Science Foundation of China, 2 projects of the Provincial Natural Science Foundation, 1 project of the New Teachers Joint Fund of the Ministry of Education, 2 projects of the National Key Laboratory Open Fund, and 1 project of the Provincial Department of Education. Published more than 30 papers as the first or corresponding author, including more than 20 SCI and EI papers, and more than 10 authorized patents.

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Cite this article:

HAO Bo,TANG Yitong,LI Xuefei, et al. Progress in Preparation and Catalytic Performance of Metal Organic Framework Derivatives[J]. Materials Reports, 2020, 34(11): 11035-11042.

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http://www.mater-rep.com/EN/10.11896/cldb.19040055 OR http://www.mater-rep.com/EN/Y2020/V34/I11/11035

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