INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Preparation and Properties of Aluminum Phosphate Composite Cured by Spinel |
YANG Xiaobo1, LYU Yi1, WANG Huadong1, ZHANG Bingqing1, YING Guobing2
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1 Aerospace Institute of Advanced Materials & Processing Technology, Beijing 100074 2 College of Mechanics and Materials, Hohai University, Nanjing 211100 |
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Abstract Aluminum phosphate composites were prepared by compression processing technology, using quartz textile as reinforcing part, aluminum phosphate hydrosol as matrix and spinel MgAl2O4 as curing agent, respectively. The flowing power of the aluminum phosphate hydrosol was studied. The spinel MgAl2O4 powders, synthesized by solid state reaction, was identified by X-ray powders diffraction. Microstructures of the composites were observed by scanning electron microscope. And the influences of MgAl2O4 contents on the mechanical and dielectric properties of aluminum phosphate composites were investigated. It was found that the viscosity of aluminum phosphate hydrosol was less than 200 mPa·s when content of water arrived at 50wt%. While the content of spinel MgAl2O4 reached 18wt% with a matrix ratio of 50 wt%, the composite obtained the highest mechanical properties, which the flexural strength, compression strength and interlaminar shearing strength were 167 MPa, 14 MPa and 40 MPa, respectively. The dielectric constant and loss tangent of the composite at room temperature were 3.35 and 0.009, respectively. However, the dielectric parameters increased gradually when crystalline phase of aluminum phosphate was changed with increasing temperature. And the dielectric properties of composites would be improved while the crystalline phase of aluminum phosphate was changed from B-AlPO4 into C-AlPO4.
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Published: 31 July 2019
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About author:: Xiaobo Yang received his M.S. degree in engineering from Harbin Institute of Technology in July 2005. He is currently a senior engineer in Aerospace Institute of Advanced Materials & Processing Technology and mainly engages in material research in functional/structural ceramics. |
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[1] |
Gu H, Liu Y Y, Wu B H, et al. Journal of Functional Materials, 2013,44(S2),250(in Chinese).顾昊, 刘元云, 吴秉横, 等. 功能材料, 2013,44(S2),250.
|
[2] |
Sun Y B, Zhang Y M, Hang J C. Aerospace Materials and Technology, 2008,38(3),11(in Chinese).孙银宝, 张宇民, 韩杰才. 宇航材料工艺, 2008,38(3),11
|
[3] |
Song M L, Fu L K. Materials Review, 2012,26(S1),226(in Chinese).宋麦丽, 傅利坤. 材料导报,2012,26(专辑19),226.
|
[4] |
Cary R H. Avionic radome materials, National Technical Information Service, UK, 1974.
|
[5] |
Sambasivan S, Steiner K A. U.S.patent, US6461415B1, 2002.
|
[6] |
Marshall D W. Sampe Journal, 2001,37(5), 53.
|
[7] |
Wang F, Wang J H, Xiao Y D. Aerospace Materials and Technology, 2006, 36(6),26(in Chinese).王锋, 王继辉, 肖永栋. 宇航材料工艺, 2006, 36(6),26.
|
[8] |
Wang Y G, Liu J L. Applied Ceramic Technology, 2009,6(2),190.
|
[9] |
Lyu Z Y, Zhang M X, Geng H R, et al. Chinese Science Bulletin,2008,53(13), 1608(in Chinese).吕震宇, 耿浩然, 张明习, 等. 科学通报, 2008,53(13),1608.
|
[10] |
Huang X, Chen N, Huo J C, et al. Journal of Functional Materials, 2014, 45(8), 08111(in Chinese).黄鑫, 陈宁, 霍冀川, 等. 功能材料, 2014, 45(8), 08111.
|
[11] |
Tian S, Huo J C, Lei Y H, et al. Journal of Functional Materials, 2013,44(7),979(in Chinese).田帅, 霍冀川, 雷永林, 等. 功能材料,2013,44(7),979.
|
[12] |
Deng S F, Zhou Y, Huang F R, et al. Journal of Functional Materials, 2009, 40(4),650(in Chinese).邓诗峰, 周燕, 黄发荣, 等. 功能材料, 2009, 40(4),650.
|
[13] |
Wang C P, Liu H L, Huo Y L, et al. Journal of Materials Engineering, 2010(S2),141(in Chinese).王春朋, 刘海林, 霍艳丽, 等. 材料工程, 2010(S2),141.
|
[14] |
Wu X J, Li J S, Wang M Y, et al. Ordnance Material Science and Engineering, 2015,38(3),136(in Chinese).武小娟, 李俊寿, 王明远, 等. 兵器材料科学与工程, 2015,38(3), 136.
|
[15] |
Zhan W, Wang Z F, Zhang B G, et al. Rare Metal Materials and Engineering, 2009,38(S2),34(in Chinese).占文, 王周福, 张保国, 等. 稀有金属材料与工程, 2009,38(S2),34.
|
[16] |
Ma P, Luo J W, Guo W H, et al. Fiber Composites, 2004,21(2),15(in Chinese).麻平,罗进文,郭卫红, 等. 纤维复合材料, 2004,21(2),15.
|
[17] |
Wang Z Y, Xu M X, Liang H, et al. Rare Metal Materials and Enginee-ring, 2008,37(S1),565(in Chinese).王政阅, 徐明霞, 梁辉, 等. 稀有金属材料与工程, 2008,37(S1),565.
|
[18] |
Wang X P, Tian S. Rare Metal Materials and Engineering, 2005,34 (S1), 716(in Chinese).王新鹏, 田莳. 稀有金属材料与工程. 2005,34(S1),716.
|
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