INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Preparation and Characterization of Bi-SnO2/Carbon Membrane Electrocatalytic Membrane |
WANG Pengfei1,2, DENG Yu1, HAO Limei2, DENG Cheng2, ZHAO Lei2, ZHANG Xinqi2, ZHU Mengfu2
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1 College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457 2 Institute of Medical Support Technology, Academy of Military Science of Chinese PLA, Tianjin 300161 |
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Abstract The Bi-SnO2/CM electrocatalytic membrane of Bi-doped SnO2 was prepared by electrothermal reduction-hydrothermal oxidation method using carbon membrane as the substrate membrane. The structure and properties of the electrocatalytic membrane were characterized by XRS, LSV and CV. The removal performance of the electrocatalytic membrane was evaluated by the removal rate of E. coli. The results show that Bi-SnO2 can increase the active site of the electrocatalytic membrane. When the molar ratio of Bi/Sn is 0.15, the redox time is 60 min, and the current is 0.2 mA, the performance of the prepared electrocatalytic membrane is the best, the oxygen evolution potential reaches 1.74 V, the electrochemical corrosion time can reach 44.5 h, and the continuous treatment is 5 h. The removal rate of E. coli is still more than 96.1%. The chemical bond with the carbon membrane is combined with the carbon membrane. In addition, the electrocatalytic membrane treatment of E. coli shows superior removal performance. It is indicated that Bi-SnO2/CM electrocatalytic membrane has a good application prospect in wastewater treatment.
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Published: 31 July 2019
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Fund:This work was financially supported by the National Natural Science Foundation of China (51878659) and the Special Project of Military Medical Innovation(16CXZ037). |
About author:: Mengfu Zhu is a researcher, doctor and doctoral supervisor at the institute of medical support technology, Academy of Military Science of Chinese PLA. He mainly engaged in the study of separation engineering technology and equipment. In recent years, he has managed and participated in the state, the army and the Tianjin major key projects in research of separation membrane materials in particular. He acquired army and Tianjin science and technology progress 10 prize, more than 60 papers published research, has won more than 10 national patent. He was committee member of the multiple academic journal editors, and academic organizations, as well as an experts of science and technology plan and evaluation of scientific and technological achievements of the state, the army and the Tianjin. He has won the national excellent science and technology workers. Pengfei Wang, postgraduate, majored in chemical engineering, academy of chemical and materials, Tianjin University of Science and Technology, research direction is functional material. |
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[1] |
Ning W H, Chen Z L, Yang Y. Journal of Chongqing University of Technology(Natural Science), 2017(11), 141(in Chinese).宁苇杭, 陈志莉, 杨毅.重庆理工大学学报(自然科学), 2017(11),141.
|
[2] |
Meng X, Deng C, Zhu M F, et al. Materials Review B:Research Papers, 2017, 31(6), 16(in Chinese).孟仙, 邓橙, 朱孟府, 等. 材料导报:研究篇, 2017, 31(6), 16.
|
[3] |
Liu Z, Zhu M, Wang Z, et al. Materials, 2016, 9(5), 364.
|
[4] |
Zhang L, Li X, He J, et al. Electrochimica Acta, 2014, 117, 192.
|
[5] |
Yong Y A, Yang S Y, Choi C, et al. Catalysis Today, 2016, 282(1), 57.
|
[6] |
Park H, Bak A, Ahn Y Y, et al. Journal of Hazardous Materials, 2012, s211-212(2), 47.
|
[7] |
Wang L Z, Zhao Y M, Li P, et al. In: 2015 Chinese Society For Environmental Science Annual Meeting, 2015, pp. 2901(in Chinese).王立章, 赵跃民, 李鹏, 等. 中国环境科学学会年会,北京,2015, pp.2901.
|
[8] |
Vecitis C D, Schnoor M H, Rahaman M S, et al. Environmental Science and Technology, 2011, 45(8), 3672.
|
[9] |
Jiang S M, Song C W, Li L, et al. Membrane Science and Technology, 2015, 35(2), 20(in Chinese).姜士敏, 宋成文, 李琳, 等.膜科学与技术, 2015, 35(2), 20.
|
[10] |
Song C W, Wang T H, Qiu J S, et al. Chemical Industry and Enginee-ring Progress, 2003, 22(9), 961(in Chinese).宋成文, 王同华, 邱介山, 等.化工进展, 2003, 22(9), 961.
|
[11] |
Wang C, Meng F, Wang T, et al. Carbon, 2014, 67(2), 465.
|
[12] |
Yang Y. Study on treatment of acid orange II azo dye wastewater by nano-TiO2 supported plate carbon-based electrocatalytic membrane. Master’s Thesis, Tianjin Polytechnic University, China, 2015(in Chinese).杨映. 纳米二氧化钛负载平板炭基电催化膜处理酸性橙Ⅱ偶氮染料废水研究. 硕士学位论文, 天津工业大学, 2015.
|
[13] |
Grzeta B, Tkalcˇec E, Goebbert C, et al. Journal of Physics & Chemistry of Solids, 2002, 63(5), 765.
|
[14] |
Feng Y, Cui Y, Logan B, et al. Chemosphere, 2008, 70(9), 1629.
|
[15] |
Liu Z M, Zhu M F, Deng C, et al. Technology of Water Treatment, 2016, 42(12), 64(in Chinese).刘志猛, 朱孟府, 邓橙, 等.水处理技术, 2016,42(12), 64.
|
[16] |
Liu H, Vajpayee A, Vecitis C D. ACS Applied Materials Interfaces, 2013, 5(20), 10054.
|
[17] |
Liu Z, Zhu M, Zhao L, et al. Chemical Engineering Journal, 2017, 314, 59.
|
[18] |
Li H, Liu J, Qian J, et al. Chinese Journal of Chemistry, 2014, 35(9), 1578.
|
[19] |
Rechberger F, Ilari G, Niederberger M. Chemical Communications, 2014, 50(86), 13138.
|
[20] |
Fu J, Lin J, Deng G Q, et al. Journal of Hainan Normal University (Natural Sciences), 2000, 13(1), 28(in Chinese).傅军, 林吉, 邓广强, 等.海南师范大学学报(自然科学版), 2000, 13(1), 28.
|
[21] |
Jeong J, Kim J Y, Yoon J. Environmental Science & Technology, 2006, 40(19), 6117.
|
|
|
|