Structure and Performance of Multilayer Graphene Oxide Membrane and Its Application in Water Treatment: a Review
YAO Qingda1,2, WEN Huitao1,3, YANG Changkai3, LIANG Yongxian1,2, WANG Xiaozhuo1,2, DAN Weihua1,3
1 Fujian Key Laboratory of Green Design and Manufacture of Leather, Jinjiang 362271, China 2 Xingye Leather Technology Co., Ltd., Jinjiang 362261, China 3 National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China
Abstract: The pollution of industrial wastewater to the environment and the harm to human body are becoming more and more serious, and this problem needs to be dealt with urgently. Among many industrial wastewater treatment methods, membrane treatment is widely used because of its good selectivity and separation efficiency. Membrane treatment, including ultrafiltration, nanofiltration, reverse osmosis and positive osmosis, is mainly based on the principles of size screening and electrostatic exclusion. However, traditional membrane materials, such as polyvinylidene fluoride, polysulfone and polyamide, have some defects, for instance, low rejection rate of pollutants, poor mechanical strength and poor chlorine resistance, which make membrane treatment face enormous difficulties and pressures. In recent years, the research and application of graphene materials have promoted the development of membrane materials. Graphene oxide separation membranes have become one of the research hotspots due to their excellent comprehensive properties. The multilayer structure assembled by graphene oxide nanosheets has shown great potential in enhancing the separation performance of membrane. Unlike graphene oxide modified conventional separation membranes, multilayer graphene oxide membranes exhibit superior physical and mechanical properties and chemical stability, and can be improved by structural design such as layer number, oxidation degree, modification status and interlayer spacing. The permeability of multilayer graphene oxide membrane is related to the number of separated layers, and increasing the number of membrane layers can improve their penetration resistance and selectivity. The number of layers, hydrophilicity and charge characteristic of GO are determined by the oxidation degree of graphene, plus, the increase of reduction degree is beneficial to the improvement of membrane permeability, while the oxidation degree is beneficial to the improvement of separation performance. The modification of GO membrane can change the charge characteristic, thus enhancing the interaction between GO and target molecules or ions. The structure of GO nanochannels affect the morphology and transport of water molecules, and the molecular dynamics can simulate and predict the separation performance of multilayer GO membrane. Here the preparation methods of multi-layer graphene oxide membranes are briefly introduced, and the relationship between structure control and separation performance of graphene oxide membranes is discussed. The effects of layer number, oxidation degree, modification and interla-yer spacing of graphene oxide membranes on separation performance are introduced in detail. The separation performance of multilayer graphene oxide membranes is simulated and analyzed by molecular dynamics. The application progress of multilayer graphene oxide membrane in removing heavy metal ions, desalination and organic matter is reviewed, and the opportunities and challenges in water treatment are prospected.
姚庆达, 温会涛, 杨长凯, 梁永贤, 王小卓, 但卫华. 多层氧化石墨烯膜的结构、性能及在水处理中的应用进展[J]. 材料导报, 2020, 34(15): 15047-15058.
YAO Qingda, WEN Huitao, YANG Changkai, LIANG Yongxian, WANG Xiaozhuo, DAN Weihua. Structure and Performance of Multilayer Graphene Oxide Membrane and Its Application in Water Treatment: a Review. Materials Reports, 2020, 34(15): 15047-15058.
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2020, Vol. 34 
