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材料导报  2019, Vol. 33 Issue (11): 1821-1824    https://doi.org/10.11896/cldb.18040160
  核材料 |
铅铋合金气相氧含量控制初步实验研究
秦博, 付晓刚, 马浩然, 张金权, 任丽霞, 龙斌
中国原子能科学研究院,北京 102413
Preliminary Experiment Study on Control of Oxygen Concentration via Gas Phase in Liquid Lead-Bismuth Alloy
QIN Bo, FU Xiaogang, MA Haoran, ZHANG Jinquan, REN Lixia, LONG Bin
China Institute of Atomic Energy, Beijing 102413
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摘要 由于铅铋共晶合金(LBE)对结构材料具有较强的腐蚀性,为了防止PbO的析出和形成一层稳定的Fe3O4保护层,LBE中的氧需要控制在一个特定的范围内。本研究基于气相氧控的原理,设计和构建了铅铋合金气相氧控静态高温试验装置,用于铅铋合金气相氧控技术研究。初步实验结果显示:氧传感器电动势随着LBE覆盖气体中H2/H2O比(体积比)的增大而升高且响应快速, 表明LBE中氧的含量逐渐降低;对特定的H2/H2O比,LBE中氧含量能够稳定在一个特定的范围。因此,通过控制和调节LBE覆盖气体中H2/H2O比可以实现将LBE中的氧含量控制在一个特定的范围。该技术有望应用于铅铋合金与结构材料的相容性实验中,以及在液态铅铋动态回路中用于铅铋合金中氧含量的控制。
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秦博
付晓刚
马浩然
张金权
任丽霞
龙斌
关键词:  铅铋共晶合金  气相氧控  氧传感器  H2/H2O比    
Abstract: In order to avoid the precipitation of PbO and form a stable Fe3O4 protective layer, the oxygen in lead-bismuth eutectic (LBE) alloy need be controlled in a certain range due to the heavy corrosion of LBE on structural materials. In this study, based on the principle of oxygen control via gas phase, an oxygen control facility for stagnant LBE is designed and assembled used to investigate the gas oxygen control technology. The preliminary test results show that the eletromotive force (EMF) of oxygen sensor increases with the increment of the H2/H2O ratio in volume, indicating the decreases of oxygen concentration in LBE, and that at a specific H2/H2O ratio the oxygen concentration can be stabilized at a certain level. Therefore, through controlling and adjusting the H2/H2O ratio in cover gas of LBE, the oxygen concentration can be controlled in a certain range. This technique is expected to be used for the oxygen concentration control in the compatibility tests of LBE with structural materials and LBE dynamic loops.
Key words:  lead-bismuth eutectic    oxygen control via gas phase    oxygen sensor    H2/H2O ratio
                    发布日期:  2019-05-21
ZTFLH:  TL34  
基金资助: 国家自然科学基金(91426301)
通讯作者:  bin.long@hotmail.com     D   
作者简介:  秦博,中国原子能科学研究院,高级工程师。2006年毕业于大连理工大学,获得工学学士学位,2010年毕业于清华大学材料系,获得工学硕士学位。现就职于中国原子能科学研究院,从事铅铋合金工艺技术、铅铋合金材料防腐、铅铋合金试验装置运行技术研究等工作。龙斌,中国原子能科学研究院研究员,核工业研究生院教授,毕业于瑞士洛桑联邦理工大学,获得理学博士学位,主要从事反应堆结构材料以及快堆液态金属冷却剂技术研究。
引用本文:    
秦博, 付晓刚, 马浩然, 张金权, 任丽霞, 龙斌. 铅铋合金气相氧含量控制初步实验研究[J]. 材料导报, 2019, 33(11): 1821-1824.
QIN Bo, FU Xiaogang, MA Haoran, ZHANG Jinquan, REN Lixia, LONG Bin. Preliminary Experiment Study on Control of Oxygen Concentration via Gas Phase in Liquid Lead-Bismuth Alloy. Materials Reports, 2019, 33(11): 1821-1824.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.18040160  或          http://www.mater-rep.com/CN/Y2019/V33/I11/1821
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