Effect of Al Content on Microstructure and Properties of TiAlN Coating
YANG Hongtai1, DAI Mingjiang2, LI Hong2, LIN Songsheng2, HOU Huijun2, SHI Qian2, WEI Chunbei2
1 School of Material and Energy, Guangdong University of Technology, Guangzhou 510006; 2 The Key Laboratory for Modern Materials Surface Engineering, National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangdong Research Institution of New Materials, Guangzhou 510651;
Abstract: TiAlN coating (Ti/Al ratio were 1∶2,1∶1.5,1∶1) was deposited on the surface of M35 high speed steel by arc ion plating technique. The microstructure and property of the coating was characterized by scanning electron microscopy (SEM), micro-hardness tester, X-ray diffraction (XRD), three-dimensional surface profiler, multi-functional surface performance tester and high temperature oxidation test. The result shows that with the increase of Al content, the roughness of TiAlN coating increased while the surface quality of the coating decreased and the anti-oxidation property decreased under the same process conditions. TiO2 and Al2O3 appeared on the surface after oxidation at 800 ℃. The Ti0.5Al0.5N coating showed the best comprehensive mechanical properties among the TiAlN coatings with different Al content, which also showed the most excellent anti-oxidation performance at 800 ℃ in 10 h.
杨鸿泰, 代明江, 李洪, 林松盛, 侯慧君, 石倩, 韦春贝. Al含量对TiAlN涂层组织结构和性能的影响[J]. 材料导报, 2018, 32(20): 3573-3578.
YANG Hongtai, DAI Mingjiang, LI Hong, LIN Songsheng, HOU Huijun, SHI Qian, WEI Chunbei. Effect of Al Content on Microstructure and Properties of TiAlN Coating. Materials Reports, 2018, 32(20): 3573-3578.
1 Zhou J L. A study on preparation and oxidation resistance property of CrAlTiN film deposited by arc ion plating [D]. Guangzhou: Guangdong University of Technology,2008(in Chinese). 周君灵.电弧离子镀CrAlTiN膜的制备与性能研究[D].广州:广东工业大学,2008. 2 Luo Z C, Wang J T. Research on influencing factors of TiAlN tool coating [J]. Hot Working Technology,2012,41(2):173(in Chinese). 罗自成,王钧涛.TiAlN刀具涂层影响因素的研究[J].热加工工艺,2012,41(2):173. 3 Zhu H L, Hu T, Peng X, et al. Effect of Al content on adhesion strength of TiAlN coatings [J]. Transactions of Materials and Heat Treatment,2015,36(3):154(in Chinese). 朱慧丽,胡涛,彭笑,等.Al含量对TiAlN涂层结合强度的影响[J].材料热处理学报,2015,36(3):154. 4 Wang J T, Liu P, Li W, et al. Research progress of Ti AlN hard coating [J]. Hot Working Technology,2010,39(20):104(in Chinese). 王均涛,刘平,李伟,等.TiAlN硬质涂层的研究进展[J].热加工工艺,2010,39(20):104. 5 梁启超,王天国,王贵强,等.Al含量对TiAlN涂层结构性能影响的研究进展[J].江西建材,2016(4):16. 6 Zhang Y M, Zhu L H, Ni W Y, et al. Effect of Al content on thermal stability of TiAlN coatings [J]. Journal of Central South University,2013,44(7):2697(in Chinese). 张雨萌,朱丽慧,倪旺阳,等,Al含量对TiAlN涂层热稳定性能的影响[J].中南大学学报,2013,44(7):2697. 7 Liu J H, Deng J X, Zhang Q Y. Development and application of TiAlN coated tools [J].Tool Engineering,2006,40(4):9(in Chinese). 刘建华,邓建新,张庆余.TiAlN涂层刀具的发展与应用[J].工具技术,2006,40(4):9. 8 Zeng K. High temperature tribological behavior of the TiAlN,AlTiN and AlTiN/TiSiN coating deposited by arc ion plating [D]. Guangzhou: Guangdong University of Technology,2016(in Chinese). 曾琨.电弧离子镀TiAlN、AlTiN和AlTiN/TiSiN涂层的高温摩擦磨损行为研究[D].广州:广东工业大学,2016. 9 Wang S Q,Chen L,Yang B,et al. Effect of Si addition on microstructure and mechanical properties of TiAlN coating [J]. International Journal of Refractory Metals and Hard Materials,2010,28(5):593. 10 Zhu P Z, Zhu Y, Li L H.Development and application of TiAlSiN coated tools [J].New Technology & New Process,2014(5):105(in Chinese). 朱鹏志,朱颖,李刘合.TiAlSiN涂层刀具的发展与应用[J].新技术新工艺,2014(5):105. 11 Zhang E G, Chen Q. Research on the performance of TiAlN and TiAlSiN coatings prepared by the cathode arc technology [J]. China Ceramics,2015,51(11):15(in Chinese). 张而耕,陈强.阴极电弧技术制备TiAlN与TiAlSiN涂层的性能研究[J].中国陶瓷,2015,51(11):15. 12 Wang S Q,Chen K H,Chen L,et al. Effect of Al and Si addtions on microstructure and mechanical properties of TiN coatings [J]. Journal of Central South University of Technology,2011,18:310. 13 Wang C X. The effect of alloying on structural stability and properties of TiAlN coatings [D]. Guangzhou: South China University of Technology,2013(in Chinese). 王成蹊.合金化对TiAlN涂层结构稳定性及性能影响的研究[D].广州:华南理工大学,2013. 14 Jin L. Study on the preparation and properties of Ti1-xAlxN films deposited by the multi-arc techniques [D]. Wuhan: Wuhan University of Science and Technology,2006(in Chinese). 金犁.多弧离子镀制备Ti1-xAlxN薄膜的工艺及其性能研究[D].武汉:武汉科技大学,2006. 15 Cao Y. Research progress of multi-arc ion plating TiAlN coating [J]. Technology Innovation and Application,2014(5):24(in Chinese). 曹娅.多弧离子镀TiAlN涂层的研究进展[J].科技创新与应用,2014(5):24. 16 Khrais S K,Lin Y J.Wear mechanisms and tool performance of TiAlN PVD coated inserts during machining of AISI 4140 steel [J]. Wear,2007,262(1):64. 17 Ru Qiang, Hu Shejun. Properties of TiAlCrN coatings prepared by vacuum cathodic arc ion plating [J]. Rare Metals,2008,27(3):251. 18 Li G F, Wang S F, Shi Z L,et al.The latest research into the inf-luence of Al content on the structure and properties of(Ti,Al)N film [J]. Rare Metals and Cemented Carbides,2007,35(6):48(in Chinese). 李国芳,王顺芳,石宗利,等.A1含量对(Ti,Al)N膜结构性能影响的研究进展[J].稀有金属与硬质合金,2007,35(6):48. 19 Jiang T. Study on technology and properties of multi-arc ion pla-ting TiAlN/TiN composite coating on 40Cr surface [D]. Zhenjiang: Jiangsu University of Science and Technology,2009(in Chinese). 蒋涛.40Cr表面多弧离子镀TiAlN/TiN复合膜层的工艺及性能研究[D].镇江:江苏科技大学,2009. 20 Du R S. Preparation of high Al content TiAlN hard coating and its antioxidant activity [D]. Guangzhou: South China University of Technology,2011(in Chinese). 杜日昇.高Al含量TiAlN系硬质涂层的制备及其抗氧化性能的研究[D].广州:华南理工大学,2011. 21 Liu A H. Friction and wear behaviors of PVD nitride coatings at elevated temperatures [D]. Jinan: Shandong University,2012(in Chinese). 刘爱华.PVD氮化物涂层的高温摩擦磨损特性及机理研究[D].济南:山东大学,2012. 22 Chen J R, Zhu L H, Ni W Y, et al. Effect of Al content on microstucture and oxidation resistance of TiAlN coatings [J]. Shanghai Metals,2010,32(3):11(in Chinese). 陈佳荣,朱丽慧,倪旺阳,等.Al含量对TiAlN涂层的组织和抗氧化性能的影响[J].上海金属,2010,32(3):11. 23 Zhang J, Han J L, Guo C A, et al. Influence of Y addition for oxidation performance of arc ion plated (Ti,Al)N films on gun steel[J]. Journal of Functional Materials,2015,46(13):13144(in Chinese). 张健,韩继龙,郭策安,等.添加Y对炮钢表面电弧离子镀(Ti,Al)N薄膜氧化性能的影响[J].功能材料,2015,46(13):13144. 24 Escudeiro Santana A, Karimi A, Derflinger V H, et al. The role of hcp-AlN on hardness behavior of Ti1-xAlxN nanocomposite during annealing [J].Thin Solid Films,2004,469-470:339. 25 Song Q G, Xin H. Effect of V content of magnetron sputtered TiAlVN film on its structure and corrosion resistance [J].Materials Protection,2011,44(2):61(in Chinese). 宋庆功,辛慧.磁控溅射TiAlVN薄膜V含量对其结构和抗腐蚀性能的影响[J].材料保护,2011,44(2):61.26 Yu D H, Wang C Y,Zhang F L. Research progress on tool coating materials [J]. Tool Engineering,2007,41(6):25(in Chinese). 余东海,王成勇,张凤林.刀具涂层材料研究进展[J].工具技术,2007,41(6):25. 27 Audy J, Harris S G, Audy K, et al. Performance evaluation of cathodic arc Evaporated(CAE) TiAlCrN coated general purpose twist drills when dry machining grey cast iron [C]∥5th Conference on “Behaviour of Materials in Machining”. Chester, UK,2002:11. 28 Hu Z J, Li Z X, Wang B Y, et al. Effect of process parameters on properties of TiAlN arc ion coating on Ti alloy surface [J].Hot Working Technology,2008,37(12):109(in Chinese). 胡志杰,李争显,王宝云,等.工艺参数对Ti合金表面电弧离子镀TiAlN涂层的性能影响[J].热加工工艺,2008,37(12):109. 29 Mao Y F, Lan X Z, Zhou L, et al. Effect of V element on high temperature oxidation behavior of TiAlN coatings [J]. Rare Metals Letters,2008,27(5):27(in Chinese). 毛延发,兰新哲,周廉,等.V元素对TiAlN涂层高温氧化行为的影响[J].稀有金属快报,2008,27(5):27. 30 Mo J L, Ren Y, Zhu M H. Preparation and drilling properties of TiAlN coated HSS twist drill [J].China Surface Engineering,2010,23(2):26(in Chinese). 莫继良,任元,朱旻昊.TiAlN涂层高速钢刀具的制备及钻削性能研究[J].中国表面工程,2010,23(2):26.