石墨烯复合材料在空气净化中的应用研究进展

材料导报

2020, Vol. 34

Issue (Z2): 104-111

无机非金属及其复合材料

石墨烯复合材料在空气净化中的应用研究进展

侯若梦^1,2, 贾瑛¹, 黄远征¹, 沈可可¹

1 火箭军工程大学导弹工程学院,西安 710025
2 中国人民解放军96037部队,宝鸡 721006

Review on Graphene Composites in Air Purification

HOU Ruomeng^1,2, JIA Ying¹, HUANG Yuanzheng¹, SHEN Keke¹

1 School of Missile Engineering,Rocket Force University of Engineering,Xi'an 710025, China
2 The PLA Unit 96037, Baoji 721006, China

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摘要石墨烯作为一种新型材料,具有比表面积大、光电性能优异、稳定性好的特点,可以和功能材料复合,如无机半导体、金属-有机骨架材料、纳米纤维、石墨相氮化碳等,通过吸附、催化和过滤等作用来净化空气。本文主要分析了石墨烯基复合材料的特点和优势,总结了其制备方法,重点论述了其在空气净化中的应用研究进展,从带隙宽度和电子结构等热力学的角度,以及增加活性位点、建立异质结、加强气体传质和提高表面电荷传递等动力学的角度,深入探讨了复合材料净化空气的机理,并对未来实用化、低成本、大吸附容量石墨烯基复合材料的发展前景进行了展望。通过总结发现,现在单一组分和二元组分石墨烯复合材料逐渐难以满足高效复杂的净化要求;且大部分粉末状石墨烯复合材料在应用中存在易聚集、易流失的问题。而新型石墨烯气凝胶复合材料和多元石墨烯复合材料具有三维特殊结构,能协同发挥多种材料的特性,在应用中有明显优势。

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	侯若梦
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关键词: 石墨烯空气净化复合材料

Abstract: Graphene is a new material, which features large specific surface area, excellent photoelectric performance and good stability. The common functional materials, such as inorganic semiconductor, metal organic framework material, nanofiber, graphite phase carbon nitride can combine with graphene to purify the air through adsorption, catalysis or filtration. The characteristics and merits of the formed graphene-based composites were analyzed and the preparation methods were summarized. And the focus is placed on the research progress of their applications in air purification. The mechanisms of purification were thoroughly analyzed from the perspective of thermodynamics, such as band gap width and electron structure. What's more, the dynamical mechanisms to enhance the air purification were discussed, such as increasing active sites, establishing heterojunction, strengthening gas mass transfer and improving surface charge transfer. Then the future prospects for developing practical, low-cost and high-adsorption capacity graphene-based composites were presented. By comparing these graphene-based composites, we find that single component and binary component graphene composites are increasingly unable to meet the high efficiency and complex purification requirements. And most powdered graphene compositeshave the disadvantages of aggregation and bleeding in application. The multi-component graphene composites can develop the advantages of various materials and graphene aerogel composites have the blocky three-dimensional structure, which meet the various need and have obvious advantages in air purification application.

Key words: graphene air purification composites

出版日期: 2020-11-25 发布日期: 2021-01-08

ZTFLH:	TB33
	X51
	O649

基金资助: 国家自然科学基金(21875281)

通讯作者: jyingsx@163.com

作者简介: 侯若梦,现为火箭军工程大学博士研究生,目前主要研究领域为液体推进剂废水废气的处理。贾瑛,火箭军工程大学教授,主要从事特种能源污染控制方面的研究工作。

引用本文:

侯若梦, 贾瑛, 黄远征, 沈可可. 石墨烯复合材料在空气净化中的应用研究进展[J]. 材料导报, 2020, 34(Z2): 104-111.
HOU Ruomeng, JIA Ying, HUANG Yuanzheng, SHEN Keke. Review on Graphene Composites in Air Purification. Materials Reports, 2020, 34(Z2): 104-111.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ2/104

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