Please wait a minute...
材料导报  2018, Vol. 32 Issue (22): 3941-3947    https://doi.org/10.11896/j.issn.1005-023X.2018.22.018
  金属与金属基复合材料 |
焙烧Mg-Al水滑石水泥浆涂层对钢筋氯离子腐蚀的缓蚀性能
梅友静, 徐金霞, 蒋林华, 陈平, 谭启平
河海大学力学与材料学院,南京 210098
Protecting of Steel from Chloride-induced Corrosion by Cement Slurry Coatings with Calcined Mg-Al Layered Double Hydroxides
MEI Youjing, XU Jinxia, JIANG Linhua, CHEN Ping, TAN Qiping
College of Materials and Mechanics, Hohai University, Nanjing 210098
下载:  全 文 ( PDF ) ( 4495KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 本工作研究了焙烧Mg-Al水滑石(LDO)水泥浆涂层对钢筋氯离子腐蚀的缓蚀性能。将焙烧Mg-Al水滑石材料添加到水泥浆中制备了复合水泥浆涂层,并涂覆在钢筋表面。由等温吸附实验、线性极化测试(LP)、电化学阻抗谱测试(EIS)研究了在混凝土模拟孔溶液中复合水泥浆涂层对钢筋氯离子腐蚀的缓蚀性能;此外,采用X射线衍射仪(XRD)和傅里叶变换红外光谱(FT-IR)检测了吸附实验前后水泥浆的物相变化,探讨了焙烧Mg-Al水滑石水泥浆涂层对钢筋氯离子腐蚀的缓蚀机理。结果表明,LDO的掺入能显著提高水泥浆体对氯离子的饱和吸附量,且随着LDO掺量的增加,复合水泥浆涂层的综合阻锈效果增强。复合LDO涂层缓释机理归因于层状结构的复原使其能有效地吸附氯离子并释放氢氧根离子,从而能有效阻止氯离子的侵蚀。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
梅友静
徐金霞
蒋林华
陈平
谭启平
关键词:  焙烧Mg-Al水滑石  水泥浆涂层  氯离子吸附  缓蚀性能    
Abstract: This study explored the protection of steel from chloride-induced corrosion by cement slurry coatings with calcined Mg-Al layered double hydroxides. The calcined Mg-Al hydrotalcite material was added to the cement slurry to prepare a composite cement slurry coating on the steel bar surface. The corrosion inhibition performance of composite cement slurry coatings on chloride ion corrosion in concrete simulated pore solution was studied by the isothermal adsorption experiment, linear polarization test (LP) and electrochemical impedance spectroscopy (EIS). In addition, the phase change of the cement slurry before and after the adsorption experiment was observed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The results showed that the incorporation of LDO could significantly increase the saturated adsorption capacity of cement slurry, and with the increase of LDO content, the comprehensive effect of composite cement slurry coatings from chloride-induced was enhanced. LDO composite coatings controlled-release mechanism attributed to the recovery of lamellar mechanism could effectively adsorb chloride ions and release hydroxyl ions, which could effectively prevent the erosion of chloride ions.
Key words:  calcined Mg-Al layered double hydroxides    cement slurry coatings    chloride ions adsorption    corrosion inhibition performance
               出版日期:  2018-11-25      发布日期:  2018-12-21
ZTFLH:  TU52  
基金资助: 国家自然科学基金面上项目(51478164)
通讯作者:  徐金霞:通信作者,男,1972年生,博士,教授,主要从事混凝土结构耐久性等研究 E-mail:xujinxia@hhu.edu.cn   
作者简介:  梅友静:男,1993年生,硕士研究生,研究方向为混凝土结构耐久性 E-mail:1039402652@qq.com
引用本文:    
梅友静, 徐金霞, 蒋林华, 陈平, 谭启平. 焙烧Mg-Al水滑石水泥浆涂层对钢筋氯离子腐蚀的缓蚀性能[J]. 材料导报, 2018, 32(22): 3941-3947.
MEI Youjing, XU Jinxia, JIANG Linhua, CHEN Ping, TAN Qiping. Protecting of Steel from Chloride-induced Corrosion by Cement Slurry Coatings with Calcined Mg-Al Layered Double Hydroxides. Materials Reports, 2018, 32(22): 3941-3947.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.22.018  或          http://www.mater-rep.com/CN/Y2018/V32/I22/3941
1 Zheng L, Yang H. Influence of organic inhibitors on the corrosion behavior of steel rebar inside mortar specimens immersed in saturated NaCl solution[J]. Acta Physico-Chimica Sinica,2010(9):2354(in Chinese).
郑雷刚,杨怀玉.饱和NaCl溶液浸泡下混凝土试块中有机阻锈剂对钢筋腐蚀行为的影响[J].物理化学学报,2010(9):2354.
2 汪红.浅谈钢筋保护层的重要性及控制[J].中国新技术新产品,2016(16):110.
3 Mahmoud M R, Soliman M A, Rashad G M. Performance appraisal of foam separation technology for removalof Co(Ⅱ)-EDTA com-plexes intercalated into in-situ formed Mg-Al layered double hydro-xide from radioactive liquid waste[J]. Chemical Engineering Journal,2017,326:781.
4 Lv L,He J, Wei M, et al. Uptake of chloride ion from aqueous solution by calcined layered double hydroxides: Equilibrium and kinetic studies[J]. Water Research.2006,40:735.
5 Hu Y C, Ren Y H, Rong M X, et al. Study on removal performance of chlorine anion by calcined hydrotalcite[J]. Chemical Engineer,2005(2):7(in Chinese).
胡玉才,任玉华,荣明霞,等.焙烧水滑石对氯离子的去除性能研究[J].化学工程师,2005(2):7.
6 Tang L, Nilsson L O. Chloride binding capacity and binding isotherms of OPC pastes and mortars[J]. Cement and Concrete Research,1993,23(2):247.
7 Xu J, Song Y, Tan Q, et al. Chloride absorption by nitrate, nitrite and aminobenzoate intercalated layered double hydroxides[J]. CrossMark,2017,52(10):5908.
8 Hwang I, Batchelor B. Reductive dechlorination of chlorinated methanes in cement slurries containing Fe(Ⅱ)[J]. Chemosphere,2002,48(2):1019.
9 Rivera-Corral J O, Fajardo G, Arliguie G, et al. Corrosion behavior of steel reinforcement bars embedded in concrete exposed to chlorides: Effect of surface finish[J]. Construction and Building Mate-rials,2017,147:815.
10 Wu Y H, Luo S X, Fu Y Y, et al. EIS characteristics of the steel in concrete in environment containing chloride ion[J]. Surface Techno-logy,2011(3):65(in Chinese).
伍远辉,罗宿星,付盈盈,等.氯离子环境下混凝土钢筋的电化学阻抗谱特征[J].表面技术,2011(3):65.
11 Menezes Dos Santos R M, Lima Gonsalves R G, Leopoldo Constantino V R, et al. Adsorption of Acid Yellow 42 dye on calcined layered double hydroxide: Effect of time, concentration, pH and temperature[J]. Applied Clay Science,2017,140:132.
12 Shi J J, Sun W. Equivalent circuits fitting of electrochemical impe-dance spectroscopy for corrosion of reinforcing steel in concrete[J]. Corrosion Science and Protection Technology, 2011(5): 387(in Chinese).
施锦杰,孙伟.等效电路拟合钢筋锈蚀行为的电化学阻抗谱研究[J].腐蚀科学与防护技术,2011(5):387.
13 Geng G Q, Shi J J, Sun W. Comparison of electrochemical measurements for steel corrosion in simulated concrete pore solution[J]. Journal of Southeast University (Natural Science Edition), 2011(2): 382(in Chinese).
耿国庆,施锦杰,孙伟.混凝土模拟液中钢筋腐蚀电化学测试结果比较[J].东南大学学报(自然科学版),2011(2):382.
14 Sigircik G, Tuken T, Erbil M. Assessment of the inhibition efficiency of 3,4-diaminobenzonitrile against the corrosion of steel[J]. Corrosion Science,2016,102:437.
15 Jiang S, Jiang L, Wang Z, et al. Deoxyribonucleic acid as an inhi-bitor for chloride-induced corrosion of reinforcing steel in simulated concrete pore solutions[J]. Construction and Building Materials,2017,150:238.
16 Liang Y, Huang J, Lin X, et al. The effect of chloride on concrete under sulfate attack[J]. Journal of Fuzhou University,2011,39(6):947.
[1] 谢婉晨, 李建三. 木质素磺酸钠在混凝土模拟孔隙液中对碳钢的缓蚀与吸附作用[J]. 材料导报, 2019, 33(8): 1401-1405.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed