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《材料导报》期刊社  2018, Vol. 32 Issue (3): 473-482    https://doi.org/10.11896/j.issn.1005-023X.2018.03.019
     材料综述 ｜ |
多孔非晶合金及其复合材料的制备技术研究进展
付正容,王修昌,金青林,谭军
昆明理工大学材料科学与工程学院,昆明 650093
A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites
Zhengrong FU,Xiuchang WANG,Qinglin JIN,Jun TAN
School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093
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摘要 

多孔非晶合金材料是结合金属泡沫和非晶合金两者的优点发展起来的一类新型结构和/或功能材料,实现了轻质与强韧的完美统一。近年来国内外研究者对多孔非晶合金及其复合材料产生了极大的兴趣,这是因为它们有极优异的物理和化学性能,如高强度、低弹性模量、高的弹性应变和高的耐腐蚀性。简要综述了多孔非晶合金及其复合材料的制备技术研究进展。
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付正容
王修昌
金青林
谭军
关键词:  多孔非晶合金  熔体  渗流  非晶粉末  粉末烧结  去合金化  过冷液相区    
Abstract: 

Porous amorphous alloy is an emerging structural and/or functional material combined the both advantages of metallic foams and glassy alloys, which has reflected the light-weight, high-strength, and large-toughness are unified. Recently,porous amorphous alloys and their composites have exert tremendous fascination on researchers at home and abroad because of their excellent physical and chemical properties,such as high strength, low elastic modulus,high elastic strains,high corrosion resistance, and so on. In this paper,the research progress of porous amorphous alloys and their composites have been summarized.
Key words:  porous amorphous alloys    melt    infiltration    amorphous powder    powder sintering    dealloying    supercooled li-quid region
               出版日期:  2018-02-10      发布日期:  2018-02-10
ZTFLH:  TG14  
基金资助: 国家自然科学基金(51301078);国家自然科学基金(51461026);教育部博士点基金(20135314120002);昆明理工大学材料科学与工程学院优秀青年拔尖人才计划(20140102)
作者简介:  付正容:女,1993年生,硕士研究生,主要从事亚稳态材料研究 E-mail: 965208232@qq.com|谭军:通信作者,男,博士,副教授,主要从事亚稳态材料研究 E-mail: tanjuncn@gmail.com
引用本文:    
付正容,王修昌,金青林,谭军. 多孔非晶合金及其复合材料的制备技术研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 473-482.
Zhengrong FU,Xiuchang WANG,Qinglin JIN,Jun TAN. A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites. Materials Reports, 2018, 32(3): 473-482.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.03.019  或          http://www.mater-rep.com/CN/Y2018/V32/I3/473
Ingredient Porosity/% Aperture/μm E/GPa σ/MPa ε/% Year Reference
Pd43Ni10Cu27P20 84 100—1 000 2003 [11]
Pd42.5Cu30Ni7.5P20 65 125—250 5.2 75 1.8 2003 [12]
Zr57Nb5Cu15.4Ni12.6Al10 60 25—50 2004 [26]
Pd35Pt15Cu30P20 45 200 27 400 >30 2005 [15]
Ti36Y20Al24Co20 0.015—0.155 2006 [45]
Ni59Zr20Ti16Si2Sn3 40 10—50 350 3.25 2006 [49]
Cu47Ti33Zr11Ni8Si1 25 0.02—0.5 2006 [52]
Zr55Cu30Al10Ni5 33.5 16 93 >3 2006 [30]
Zr47Ti13Cu11Ni10Be16Nb3 80 150-200 820 1.3 2007 [31]
Fe48Cr15Mo14Y2C15B6 65 2007 [53]
Zr57Nb5Al10Ni12.6Cu15.4 60.4 50 17 180 >16 2007 [33]
Mg60Cu21Ag7Gd12 57.5 2 000 8.5 109 90 2007 [56]
Zr48Cu36Al8Ag8 13 71 1 390 0.02 2008 [34]
Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 60 45—106 62 70 2009 [25]
Hf44.5Cu27Ni13.5Ti5Al10 62 45—106 80 2012 [57]
Zr41.25Ti13.75Cu12.5Ni10Be22.5 65 30 0.29 2012 [37]
Pd40Cu30Ni10P20 20—550 2012 [22]
Zr56.3Nb5.1Cu15.6Ni12.9Al10 70 45-106 2013 [39]
Zr35Ti30Be26.75Cu8.25 20—550 2013 [44]
Ti45Zr10Cu31Pd10Sn4 60 125—250 2014 [46]
Ti42Zr40Ta3Si15 14 337 52 0.67 2016 [47]
Fe82Nb6B12 23—38 0.12 2017 [55]
表1  各种基体的多孔非晶合金及其复合材料的首次报道年份、孔结构参数及其力学性能
图1  原位气体发生法制备多孔非晶合金的工艺流程
图2  气体注入法制备多孔非晶合金的工艺流程
图3  易溶颗粒渗流铸造法制备多孔非晶合金的工艺流程
图4  粉末烧结法制备多孔非晶合金的工艺流程
图5  孔隙率为70%的Zr55Cu30Al10Ni5多孔非晶合金的SEM形貌图[32]:(a)热压成形泡沫形貌;(b)泡沫的孔结构;(c)泡沫内壁放大图(箭头表明颗粒之间连接的区域)
图6  孔隙率为86%的Pd43Ni10Cu27P20泡沫的压缩应力-应变曲线[17]
图7  烧结多孔样品Zr55Cu30Al10Ni5横截面的SEM形貌图:孔隙率(a)4.7%和(b)33.5%[30]
图8  孔隙度为25%的Cu47Ti33Zr11Ni8Si1多孔金属玻璃SEM形貌图[52]:(a)前驱体抛光横截面图;(b)多孔非晶合金宏观结构;(c)多孔非晶合金横截面;(d)(c)的放大图
图9  Zr58.5Nb2.8Cu15.6Ni12.8Al10.3多孔非晶合金的压缩应力-应变图[25]:(a)由Vit/Cu制备,孔隙率为57%和64%;(b)由Vit/Ni制备,孔隙率为57%和59%;(c)由Vit/W制备,孔隙率为59.5%和63%
图10  去合金化法制备多孔非晶合金的工艺流程
图11  过冷液相区加工法制备多孔非晶合金的工艺流程
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