Please wait a minute...
CLDB  2017, Vol. 31 Issue (9): 128-134    https://doi.org/10.11896/j.issn.1005-023X.2017.09.018
  材料综述 |
低成本钛合金研究现状与发展趋势*
冯秋元1, 2, 佟学文1, 2, 王俭1, 2, 王鼎春2, 高颀1
1 宝钛集团有限公司,宝鸡 721014;
2 宝鸡钛业股份有限公司,宝鸡 721014
Status Quo and Development Tendency on the Research of Low Cost Titanium Alloy
FENG Qiuyuan1, 2, TONG Xuewen1, 2, WANG Jian1, 2, WANG Dingchun2, GAO Qi1
1 Baoti Group Ltd., Baoji 721014;
2 Baoji Titanium Industry Co., Ltd., Baoji 721014
下载:  全 文 ( PDF ) ( 1302KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 钛合金较高的成本限制了其应用范围,低成本钛合金已成为当前钛合金研究的热点。概述了低成本钛合金国内外的研究现状,着重介绍了宝钛集团研发的低成本钛合金及钛合金的低成本化制备情况,新近研制的BTi31、Ti-3111、BTi-341、BTi-421111、BTi-61111S等低成本钛合金已在汽车、体育休闲等领域获得应用;在钛合金的低成本化制造方面,利用电子束冷床炉熔炼,大量添加返回料,熔炼的扁锭直接轧制板材,显著降低原料成本和加工成本。同时对低成本钛合金的发展方向进行展望,指出今后的研究重点是进一步优化熔炼和加工工艺,提升合金性能水平,提高成材率,拓展应用范围。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
冯秋元
佟学文
王俭
王鼎春
高颀
关键词:  钛合金  低成本  现状  发展趋势    
Abstract: The high cost of titanium alloy restrict its field of application, therefore, the research of low cost titanium alloy has become a hot spot. In this paper, the research status quo on the low cost titanium alloy at home and abroad is reviewed, and the research and manufacturing technology of the low cost titanium alloy in Baoti Group is introduced emphatically. The recently developed low cost titanium alloy, such as BTi31, Ti-3111, BTi-341, BTi-421111, BTi-61111S and so forth, have already applied in automobile, sports and leisure fields. In the aspect of low cost manufacturing, using electron beam cold hearth melting (EBCHM) and adding heavy return scraps, the slab ingots were melted and then directly rolled plates to obviously reduce raw materials cost and processing cost. Meanwhile, the future development is proposed, and the research emphasis will focus on optimizing the melting and processing technique to promote the performance level and yield for extending the application range of titanium alloy.
Key words:  titanium alloy    low cost    status quo    development tendency
出版日期:  2017-05-10      发布日期:  2018-05-03
ZTFLH:  TG146.2+3  
基金资助: *国家高技术研究发展计划(863计划)(2013AA09A108); 陕西省科技统筹创新工程计划项目(2012KTZB01-03)
作者简介:  冯秋元:男,1974年生,博士,高级工程师,主要从事新型钛、锆合金研发、金属材料表面改性及强韧化研究 E-mail:fengqiuyuan2003@163.com
引用本文:    
冯秋元, 佟学文, 王俭, 王鼎春, 高颀. 低成本钛合金研究现状与发展趋势*[J]. CLDB, 2017, 31(9): 128-134.
FENG Qiuyuan, TONG Xuewen, WANG Jian, WANG Dingchun, GAO Qi. Status Quo and Development Tendency on the Research of Low Cost Titanium Alloy. Materials Reports, 2017, 31(9): 128-134.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.09.018  或          https://www.mater-rep.com/CN/Y2017/V31/I9/128
[1] Guo Ruiping, Sun Baosen, Gao Binbin.Low cost manufacturing technology of titanium alloy used in ordnance equipment[J]. Ord Mater Sci Eng,2008,31(5):83(in Chinese).郭瑞萍, 孙葆森, 高彬彬. 兵器装备用钛合金的低成本制造技术[J]. 兵器材料科学与工程,2008,31(5):83.
[2] Gao Wa, Zhang Cunxin.Process of the low-cost titanium alloys and its military application[J]. Titanium Ind Prog ,2008, 25(3):6(in Chinese).高娃, 张存信. 低成本钛合金制备技术及其军事应用[J]. 钛工业进展,2008,25(3):6.
[3] Zhang Wenyu.Research progress of high-performance and low cost titanium alloy[J]. Aeronautical Manufacturing Technol, 2011(5):74(in Chinese).张文毓. 高性能低成本钛合金研究进展[J]. 航空制造技术,2011(5):74.
[4] Zhu Zhishou, Shang Guoqiang, Wang Xinnan, et al.Research and development of low cost and high performance titanium alloys[J]. Titanium Ind Prog,2012,29(6):1(in Chinese).朱知寿, 商国强, 王新南, 等. 低成本高性能钛合金研究进展[J]. 钛工业进展,2012,29(6):1.
[5] Gazder A A, Vu V Q, Saleh A A.Recrystallisation in a cold drawn low cost beta titanium alloy during rapid resistance heating[J]. J Alloys Compd,2014,585:245.
[6] Zadra M, Girardini L.High-performance, low-cost titanium metal matrix composites[J]. Mater Sci Eng A,2014,608:155.
[7] Santos P F, Niinomi M, Cho K.Microstructures, mechanical pro-perties and cytotoxicity of low cost beta Ti-Mn alloys for biomedical applications[J]. Acta Biomater,2015,26:366.
[8] Yasser A, Mohamed A H G, Ahmed A M, et al. Compatibility assessment of new V-free low-cost Ti-4.7Mo-4.5Fe alloy for some biomedical applications[J]. Mater Des,2016,97:445.
[9] Bolzoni L, Ruiz-Navas E M, Gordo E. Understanding the properties of low-cost iron-containing powder metallurgy titanium alloys[J]. Mater Des,2016,110:317.
[10] Sherman A M, Sommer C J, Froes F H.The use of titanium in production automobiles: Potential and challenges[J]. J Minerals Metals Mater Soc,1997,49(5):38.
[11] Montgomery J, Wells M H, Roopchand B, et al.Low-cost titanium armors for combat vehicles[J]. J Minerals Metals Mater Soc,1997,49(5):45.
[12] Froes F H, Friedrich H, Kiese J, et al.Titanium in the family automobile: The cost challenge[J]. J Minerals Metals Mater Soc,2004,56(2):40.
[13] Kosaka Y, Faller K, Fox S.Newly developed titanium alloy sheets for the exhaust systems of motorcycles and automobiles[J]. J Mi-nerals Metals Mater Soc,2004,56(11):32.
[14] Kosaka Y, Fox S, Faller K, et al.Properties and processing of TIMETAL LCB[J]. J Mater Eng Perform,2005,14(6):792.
[15] Koike M, Ohkubo C, et al.Evaluation of cast Ti-Fe-O-N alloys for dental applications[J]. Mater Sci Eng C,2005,25(3):349.
[16] Chen Feng, Chen Zhanqian, Ding Changqin, et al.The new techno-logy of Ti-3111 ingot production by adding returned scraps[J]. Rare Metal Mater Eng,2005,34(S3):188(in Chinese).陈峰, 陈战乾, 丁长勤, 等. 添加合金返回炉料生产Ti-3111钛合金铸锭新工艺[J]. 稀有金属材料与工程,2005,34(S3):188.
[17] 王韦琪, 杨慧丽, 张平辉, 等. 一种近α型中强钛合金: 中国, CN101497951A [P].2009-08-05.
[18] Chen Binggang, Li Weiqing, Dong Jie, et al.Effects of heat treatment on microstructures and mechanical properties of BTi-341 tita-nium alloy[J]. China Titanium Ind,2012(4):36(in Chinese).陈秉刚, 李渭清, 董洁, 等. 热处理制度对BTi341钛合金组织与性能的影响[J].中国钛业,2012(4):36.
[19] 王小翔, 陈峰, 王永强, 等. 一种高塑中强钛合金: 中国, CN101407873A[P].2009-04-15.
[20] 王韦琪, 王小翔, 乔璐, 等. 一种中强高塑钛合金: 中国, CN101476059A [P].2009-07-08.
[21] Li Fengli, Qiao Enli, Wang Liying, et al.A newly type of moderate strength and high-ductility titanium alloy[J]. Light Ind Design,2011(6):21(in Chinese).李峰丽, 乔恩利, 王丽瑛, 等. 一种新型中强高塑钛合金[J]. 轻工设计,2011(6):21.
[22] Tan Min, Wang Juanhua, Wang Hongwu.Ti-1.5Al-0.5Fe-0.2Si alloy sheet cold reduction research[J]. China Titanium Ind, 2015(3):43(in Chinese).谭敏, 王娟华, 王红武. Ti-1.5Al-0.5Fe-0.2Si钛合金薄板冷轧变形量研究[J]. 中国钛业,2015(3):43.
[23] Zhu Ye, Wang Xin.Effects of cold deformation and heat treatment on microstructure and properties of BTi-421111 titanium alloy sheet[J]. Titanium Ind Prog,2014,31(1):29(in Chinese).朱晔, 王新. 冷变形量及热处理对BTi-421111钛合金薄板组织和性能的影响[J]. 钛工业进展,2014,31(1):29.
[24] Wang Guo, Hui Songxiao, Ye Wenjun, et al.Hot compressive behavior of Ti-3.0Al-3.7Cr-2.0Fe low cost titanium alloy[J]. Chinese J Nonferrous Metals,2012,22(8):2223(in Chinese).王国, 惠松骁, 叶文君, 等. Ti-3.0Al-3.7Cr-2.0Fe低成本钛合金的热压缩变形行为[J]. 中国有色金属学报,2012,22(8):2223.
[25] Jia Weiju, Zeng Weidong, Duan Fengchuan, et al.Study on fatigue crack propagation behavior of low cost titanium alloy Ti8LC[J]. Rare Metal Mater Eng,2009,38(12):2171(in Chinese).贾蔚菊, 曾卫东, 段风川, 等. Ti8LC低成本钛合金疲劳裂纹扩展行为研究[J]. 稀有金属材料与工程,2009,38(12):2171.
[26] Yin Yanfei, Li Silan, Hou Zhimin, et al.Influence of heat treatment on microstructure and mechanical properties of Ti12LC low-cost titanium alloy[J]. Titanium Ind Prog,2015,32(4):13(in Chinese).尹雁飞, 李思兰, 侯智敏, 等. 热处理对Ti12LC低成本钛合金组织和性能的影响[J]. 钛工业进展,2015,32(4):13.
[27] Kalinyuk A N, Trigub N P, Zamkov V N, et al.Microstructure, texture, and mechanical properties of electron beam melted Ti6Al4V[J]. Mater Sci Eng A,2003,346(1-2):178.
[28] Wood J R, Fanning J C.Direct production of Ti-6Al-4V alloy plate from electron beam cold hearth melted slab ingot[C]//Lütjering G, Albrecht J. Ti-2003 Science and Technology, Proceedings of the 10th World Conference on Titanium, Volume I, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim,2003:181.
[29] Ma Rongbao, Chen Feng, Guo Bin.Development of EBCHR and discussion of its remelting process[J]. Titanium Ind Prog, 2008,25(5):37(in Chinese).马荣宝, 陈峰, 国斌. 电子束冷床熔炼发展简况及熔炼工艺探讨[J]. 钛工业进展, 2008,25(5):37.
[30] Yu Lanlan, Mao Xiaonan, Zhang Yingming, et al.Development of electron-beam cold hearth single melt process for titanium alloy ingots[J]. Titanium Ind Prog,2009,26(2):14(in Chinese).于兰兰, 毛小南, 张英明, 等. 电子束冷床炉单次熔炼钛合金铸锭研究进展[J]. 钛工业进展,2009,26(2):14.
[31] Chen Feng, Chen Li, Guo Bin, et al.Advantages and disadvantages of electron beam cold hearth melting[J]. Chinese J Nonferrous Me-tals,2010,20(S1):s873(in Chinese).陈峰, 陈丽, 国斌, 等. 电子束冷床熔炼的优与劣[J]. 中国有色金属学报,2010,20(S1):s873.
[32] Feng Qiuyuan, Pang Hong, Qiao Lu, et al.Preparation of low-cost TC4 titanium alloy sheet[J]. Chinese J Nonferrous Metals,2013,23(S1):s353(in Chinese).冯秋元, 庞洪, 乔璐, 等. 低成本TC4钛合金板材的研制[J]. 中国有色金属学报, 2013, 23(S1): s353.
[33] 佟学文, 惠松骁, 乔璐, 等. 一种高动态承载性能、低成本钛合金的制备方法: 中国, CN 104451213 A [P].2015-03-25.
[34] Li Bin, Feng Qiuyuan, Zhang Lei, et al.Effects of heat treatment on microstructures and properties of low cost TC4 titanium alloy sheets[J]. China Titanium Ind,2014(4):29(in Chinese).李斌, 冯秋元, 张磊, 等. 热处理对低成本TC4合金板材组织和性能的影响[J]. 中国钛业,2014(4):29.
[35] Feng Qiuyuan, Zhang Lei, Pang Hong, et al.Microstructure and properties of low cost TC4 titanium alloy sheet[J]. Heat Treatment Metals,2016,41(6):85(in Chinese).冯秋元, 张磊, 庞洪, 等. 低成本TC4钛合金板材的组织和性能[J]. 金属热处理,2016,41(6):85.
[1] 程东海, 张夫庭, 陶玄宇, 余超, 龚浩, 李海涛, 王德, 熊震宇. 稀土元素对钛合金激光焊接头组织及性能的影响[J]. 材料导报, 2025, 39(3): 23060020-5.
[2] 李冲, 晏阳阳, 杨祯彧, 宋德军, 胡伟民, 杨胜利, 田世伟, 江海涛. TA24合金多道次热变形行为及管材制备仿真[J]. 材料导报, 2025, 39(2): 23120078-7.
[3] 焦纪强, 蒙峻, 谢文君, 刘建龙, 魏宁斐, 罗成, 郭方准, 王润成. 超高真空环境下TC4钛合金和ZrO2陶瓷的出气性能研究[J]. 材料导报, 2025, 39(1): 23090126-5.
[4] 常川川, 李菊, 李晓红, 金俊龙, 张传臣, 季亚娟. 热处理对同质异态TC17钛合金线性摩擦焊接头的影响[J]. 材料导报, 2024, 38(8): 22080152-5.
[5] 张明玉, 运新兵, 伏洪旺. BASCA热处理对TC10钛合金组织与断裂韧性的影响[J]. 材料导报, 2024, 38(7): 22080020-6.
[6] 张雷, 龙伟民, 樊志斌, 都东, 刘大双, 孙志鹏, 李宇佳, 尚勇. CuTi对Ti-6Al-4V钛合金表面金刚石/AlSi复合钎涂层组织与耐磨性能的影响[J]. 材料导报, 2024, 38(21): 23080114-4.
[7] 张健, 朱智浩, 张爽, 董闯. 高Al含量的亚稳β型Ti-Al-Mo-Nb-V系列钛合金的组织与力学性能[J]. 材料导报, 2024, 38(2): 22040297-6.
[8] 莫琛, 向阳, 陈坤, 张稳, 彭志航, 文瑾, 曹建辉. Al2O3f/Al2O3陶瓷基复合材料研究进展[J]. 材料导报, 2024, 38(18): 23030126-9.
[9] 王同波, 李伯龙, 亓鹏, 王云鹏, 莫永达, 娄花芬. 含铒近α型高温钛合金中α相的动/静态球化机制[J]. 材料导报, 2024, 38(17): 23100083-6.
[10] 李红梅, 孟建兵, 于浩洋, 董小娟, 周海安, 战胜杰, 唐友泉. ZnO纳米颗粒掺杂对镍钛合金表面微弧氧化膜层形貌及性能的影响[J]. 材料导报, 2024, 38(13): 22110123-7.
[11] 马昆林, 孟维琦, 申景涛, 胡明文, 王晓杰, 龙广成, 曾晓辉. 再生微粉性能激活研究及应用进展[J]. 材料导报, 2024, 38(10): 22100042-13.
[12] 杨瑞强, 汪永清, 常启兵, 周健儿. 烧结助剂MgO-Al2O3-SiO2-ZrO2提高管式支撑体的耐碱腐蚀性能研究[J]. 材料导报, 2023, 37(S1): 23040042-9.
[13] 谭钦文, 邓黎鹏, 易润华, 程东海, 李东阳. Ni中间层镁/钛异种材料电阻点焊接头组织与性能[J]. 材料导报, 2023, 37(7): 21090077-4.
[14] 方静, 祁文军, 胡国玉. 8 mm中厚板TC4钛合金TIG焊数值模拟及实验研究[J]. 材料导报, 2023, 37(22): 22030018-6.
[15] 屈盛官, 翟荐硕, 段晨风, 孙朋飞, 李小强. TC4钛合金二维超声振动车削性能研究[J]. 材料导报, 2023, 37(22): 22040390-9.
[1] Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[3] Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[4] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[5] Yingke WU,Jianzhong MA,Yan BAO. Advances in Interfacial Interaction Within Polymer Matrix Nanocomposites[J]. Materials Reports, 2018, 32(3): 434 -442 .
[6] Zhengrong FU,Xiuchang WANG,Qinglin JIN,Jun TAN. A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites[J]. Materials Reports, 2018, 32(3): 473 -482 .
[7] Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅡ: Durability and Life Prediction Model[J]. Materials Reports, 2018, 32(3): 496 -502 .
[8] Lixiong GAO,Ruqian DING,Yan YAO,Hui RONG,Hailiang WANG,Lei ZHANG. Microbial-induced Corrosion of Concrete: Mechanism, Influencing Factors,Evaluation Indices, and Proventive Techniques[J]. Materials Reports, 2018, 32(3): 503 -509 .
[9] Ningning HE,Chenxi HOU,Xiaoyan SHU,Dengsheng MA,Xirui LU. Application of SHS Technique for the High-level Radioactive Waste Disposal[J]. Materials Reports, 2018, 32(3): 510 -514 .
[10] Haoran CHEN, Yingdong XIA, Yonghua CHEN, Wei HUANG. Low-dimensional Perovskites: a Novel Candidate Light-harvesting Material for Solar Cells that Combines High Efficiency and Stability[J]. Materials Reports, 2018, 32(1): 1 -11 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed