Abstract: Due to the shortage of energy resources and the problem of environmental pollution, it is essential to adopt proper ways to develop new energy storage materials to solve the problem. Lithium ion battery has been widely used, but the content of lithium elements on the earth is less, which limited the development of lithium-ion battery. The chemical properties of sodium and lithium are similar, which means sodium can replace the lithium as a new generation of energy material. Carbon material for sodium anode storage can be divided into natural graphite, graphene, soft carbon materials and hard carbon materials. This review aims to introduce the definition, problems and solutions of carbon materials, which has significant influence on modification of carbon mate-rials and applications in sodium ion batteries.
1 Jian Z L. Research on electrode material of new energy storage battery[D]. Wuhan:Wuhan University of Technology, 2012(in Chinese). 简泽浪. 新型储能电池电极材料研究[D].武汉:武汉理工大学,2012. 2 He H N, Wang H Y, Tang Y G, et al. Negative electrode material for sodium ion battery[J]. Prog Chem, 2014(4):572(in Chinese). 何菡娜, 王海燕, 唐有根,等. 钠离子电池负极材料[J]. 化学进展, 2014(4):572. 3 Evarts E C. Lithium batteries: To the limits of lithium[J]. Nature, 2015,526(7575):93. 4 Larcher D, Tarascon J M. Towards greener and more sustainable batteries for electrical energy storage[J]. Nat Chem, 2015,7(1):19. 5 Ye F P, Wang L, Lian F, et al. Research progress of sodium ion battery[J]. Prog Chem, 2013(8):1789(in Chinese). 叶飞鹏, 王莉, 连芳,等. 钠离子电池研究进展[J]. 化工进展, 2013(8):1789. 6 Li H, Wu C, Wu F, et al. Sodium ion batteries: A new option for energy storage batteries[J]. Acta Chim Sin, 2014,72(1):21(in Chinese). 李慧, 吴川, 吴锋,等. 钠离子电池:储能电池的一种新选择[J]. 化学学报, 2014,72(1):21. 7 Slater M D, Kim D, Lee E, et al. Sodium-ion batteries[J]. Adv Funct Mater, 2013,23(8):947. 8 Ding J, Wang H, Li Z, et al. Carbon nanosheet frameworks derived from peat moss as high performance sodium ion battery anodes[J]. Acs Nano, 2013,7(12):11004. 9 Baggetto L, Hah H Y, Jumas J C, et al. The reaction mechanism of SnSb and Sb thin film anodes for Na-ion batteries studied by X-ray diffraction, 119 Sn and 121 Sb M?ssbauer spectroscopies[J]. J Power Sources, 2014,267(267):329. 10Lu Y C, Ma C, Alvarado J, et al. Electrochemical properties of tin oxide anodes for sodium-ion batteries[J]. J Power Sources, 2011,17(4):403. 11Senguttuvan P, Rousse G, Seznec V, et al. Na2Ti3O7: Lowest voltage ever reported oxide insertion electrode for sodium ion batteries[J]. Chem Mater, 2011,23(18):4109. 12Jernej B, Froebe A, Ajhler T, et al. Conversion reactions for sodium-ion batteries[J]. Phys Chem Chem Phys Pccp, 2013,15(38):15876. 13Yin J, Qi L, Wang H. Sodium titanate nanotubes as negative electrode materials for sodium-ion capacitors[J]. ACS Appl Mater Interfaces, 2012,4(5):2762. 14Kim H, Hong J, Park Y, et al. Sodium storage behavior in natural graphite using ether-based electrolyte systems[J]. Adv Funct Mater, 2015,25(4):534. 15Zhu Z, Cheng F, Hu Z, et al. Highly stable and ultrafast electrode reaction of graphite for sodium ion batteries[J]. J Power Sources, 2015,293:626. 16Ji L, Meduri P, Agubra V, et al. Graphene-based nanocomposites for energy storage[J]. Adv Energy Mater, 2016,6(16):1502159. 17Choe J H, Kim N R, Lee M E, et al. Flexible graphene stacks for sodium-ion storage[J]. Chemelectrochem, 2017,4:716. 18Yan Y, Yin Y X, Guo Y G, et al. A sandwich-like hierarchically porous carbon/graphene composite as a high-performance anode material for sodium-ion batteries[J]. Adv Energy Mater, 2014,4(8):1079. 19Wenzel S, Hara T, Janek J, et al. Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies[J]. Energy Environmental Sci, 2011,4(9):3342. 20Ling C, Mizuno F. Boron-doped graphene as a promising anode for Na-ion batteries[J]. Phys Chem Chem Phys, 2014,16(22):10419. 21Choi S H, Ko Y N, Lee J K, et al. 3D MoS2-graphene microspheres consisting of multiple nanospheres with superior sodium ion storage properties[J]. Adv Funct Mater, 2015,25(12):1780. 22Wen Y, He K, Zhu Y, et al. Expanded graphite as superior anode for sodium-ion batteries[J]. Nat Commun, 2014,5:4033. 23Cohn A P, Share K, Carter R, et al. Ultrafast solvent-assisted sodium ion intercalation into highly crystalline few-layered graphene[J]. Nano Lett, 2015,16(1):543. 24Jia X P, Chen M. Research progress of electrode materials for sodium ion batteries[J]. J China Academy of Electronic Science, 2012,7(6):581(in Chinese). 贾旭平, 陈梅. 钠离子电池电极材料研究进展[J]. 中国电子科学研究院学报, 2012,7(6):581. 25Jian Z, Bommier C, Luo L, et al. Insights on the mechanism of Na-ion storage in soft carbon anode[J]. Chem Mater, 2017,29(5):2314. 26Miao Y, Zong J, Liu X. Phosphorus-doped pitch-derived soft carbon as an anode material for sodium ion batteries[J]. Mater Lett, 2017,188:355. 27Cao B, Liu H, Xu B, et al. Mesoporous soft carbon as an anode material for sodium ion batteries with superior rate and cycling perfor-mance[J]. J Mater Chem A, 2016,4(17):6472. 28Luo W, Jian Z, Xing Z, et al. Electrochemically expandable soft carbon as anodes for Na-ion batteries[J]. Acs Central Sci, 2015,1(9):516. 29Pan H L, Hu Y S, Li H, et al. Research progress of electrode material structure of room temperature sodium ion energy storage battery[J]. Chinese J Sci Chem, 2014(8):1269(in Chinese). 潘慧霖, 胡勇胜, 李泓,等. 室温钠离子储能电池电极材料结构研究进展[J]. 中国科学化学, 2014(8):1269. 30Lotfabad E M, Ding J, Cui K, et al. High-density sodium and lithium ion battery anodes from banana peels[J]. Acs Nano, 2014,8(7):7115. 31Bai Y, Wang Z, Wu C, et al. Hard carbon originated from polyvinyl chloride nanofibers as high-performance anode material for Na-ion battery[J]. ACS Appl Mater Interfaces, 2015,7(9):5598. 32Xiao L, Cao Y, Henderson W A, et al. Hard carbon nanoparticles as high-capacity, high-stability anodic materials for Na-ion batteries[J]. Nano Energy, 2015,19:279. 33Prabakar S J R, Jeong J, Pyo M. Nanoporous hard carbon anodes for improved electrochemical performance in sodium ion batteries[J]. Electrochimica Acta, 2015,161:23. 34Tang K, Fu L, White R J, et al. Hollow carbon nanospheres with superior rate capability for sodium-based batteries[J]. Adv Energy Mater, 2012,2(7):873. 35Xu F, Tang Z, Huang S, et al. Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres for enhanced adsorption and energy storage[J]. Nat Commun, 2015,6:7221. 36Wang Z, Long Q, Yuan L, et al. Functionalized N-doped interconnected carbon nanofibers as an anode material for sodium-ion storage with excellent performance[J]. Carbon, 2013,55(2):328. 37Wang H G, Wu Z, Meng F L, et al. Nitrogen-doped porous carbon nanosheets as low-cost, high-performance anode material for sodium-ion batteries[J]. Chemsuschem, 2013,6(1):56.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2017, Vol. 31 
