| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Synthesis of Ti3C2Tx MXene/SF-016 UV-resistant Composite and Its Application in Simulated Mural Conservation |
| FANG Yuan1,*, LI Doudou1, WANG Jia2, LU Zhiyong2, ZENG Lijun1, ZHAO Ting1, YANG Wenzong1,2, ZHU Jianfeng1
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1 MoE Key Laboratory of Materials and Technology for Unearthed Cultural Heritage Conservation, School of Conservation Science and Technology for Cultural Heritage, School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China 2 Key Scientific Research Base of the National Cultural Heritage Administration for Conservation, Restoration and Material Science of Museum-collected Murals (Shaanxi History Museum), Xi'an 710061, China |
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Abstract Acrylic resin Primal SF-016, a conventional polymeric consolidant for mural conservation, exhibits susceptibility to photodegradation under prolonged UV radiation. Ti3C2Tx MXene/SF-016 composites were successfully prepared through a solution blending method. X-ray diffraction (XRD), transmission electron microscopy (TEM), and Raman spectroscopy were used to investigate the structure of Ti3C2Tx MXene/SF-016 composites. The light transmittance, hydrophilicity, and UV-aging resistance were investigated. The microstructures, water vapor permeability, hydrophilicity, reinforcement strength and color differences of the simulated murals before and after consolidation by Ti3C2Tx MXene/SF-016 composites were investigated. The optimized composites demonstrated enhanced hydrophilicity and UV-aging resistance. For the composites with 0.005% and 0.01% Ti3C2Tx MXene, the UV-shielding performance improved 37%—44% while maintaining >80% visible light transmittance. After consolidation by Ti3C2Tx MXene/SF-016, the original porous morphology of the murals could be preserved, water vapor permeability, hydrophilicity and the reinforcement strength were improved. Chromatic stability was maintained at Ti3C2Tx MXene concentrations≤0.01%. The results show that Ti3C2Tx MXene/SF-016 composites have significant potential as innovative materials for mural conservation.
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Published: 25 April 2026
Online: 2026-05-06
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1 Gong X,Han X N,Chen K L. Conservation and Archaeological Science,2021,33(3),108(in Chinese). 龚欣, 韩向娜, 陈坤龙. 文物保护与考古科学, 2021, 33(3), 108. 2 Margariti C, Kallitsi N, Petrou M, et al. Studies in Conservation, 2010, 55, 152. 3 Yang R. Conservation and Archaeological Science, 2010, 22(1), 70(in Chinese). 杨蕊. 文物保护与考古科学, 2010, 22(1), 70. 4 Xu S H. Grassland Cultural Relics, 2020(1), 111(in Chinese). 许少华. 草原文物, 2020(1), 111. 5 Gong X, Han X N, Chen K L. Spectroscopy and Spectral Analysis, 2023, 43(7), 2181(in Chinese). 龚欣, 韩向娜, 陈坤龙. 光谱学与光谱分析, 2023, 43(7), 2181. 6 Naguib M, Kurtoglu M, Presser V, et al. Advanced Materials, 2011, 23, 4248. 7 Dai F Z, Xiang H, Sun Y, et al. Journal of Materials Science & Technology, 2019, 35, 1432. 8 Dai F Z, Zhang H, Xiang H, et al. Journal of Materials Science & Technology, 2020, 39, 161. 9 Hu T, Li Z J, Hu M M, et al. The Journal of Physical Chemistry C, 2017, 121(35), 19254. 10 Berdiyorov G R. AIP Advances, 2016, 6, 055105. 11 Zhang H J, Yang G, Zuo X Q, et al. Journal of Materials Chemistry A, 2016, 4, 12913. 12 Zhang T Y, Wang H, Tong J M, et al. Composites Communications, 2022, 33, 101235. 13 Qiang T, Qi X Y, Gao H H, et al. Polymer Bulletin, 2024, 81, 12243. 14 Wang S J, Li D S, Meng W J, et al. Journal of Materials Chemistry C, 2022, 10(13), 5336. 15 Xi Y E. Research on the influence of the ground layer technology and preservation environment of Tang Dynasty tomb murals in Shaanxi. Northwest University, China, 2020(in Chinese). 葸艳娥. 陕西唐墓壁画地仗层工艺及其保存环境影响研究. 硕士学位论文, 西北大学, 2020. 16 General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Standardization Administration of China. GB/T 14522-2008 Artificial climate aging test method for plastics, coatings and rubber materials used in mechanical industrial products—fluorescent ultraviolet lamp. , China Standards Press, China, 2008(in Chinese). 中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. GB/T 14522-2008 机械工业产品用塑料、涂料、橡胶材料人工气候老化试验方法—荧光紫外灯, 中国标准出版社, 2008. 17 ISO 2409:2020. Paints and varnishes-cross-cut test. International Organization for Standardization, Switzerland, 2020. 18 Du Z L, Zhu J F, Ma T, et al. Materials Reports, 2025, 39(8), 88(in Chinese). 杜之琳, 朱建锋, 马涛, 等. 材料导报, 2025, 39(8). 88. 19 General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of China. GB/T 17146-2015 Test method for water vapor permeability of building materials and products, China Standards Press, China, 2015(in Chinese). 中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. GB/T 17146-2015 建筑材料及其制品水蒸气透过性能试验方法, 中国标准出版社, 2015. 20 Li W F. Research on the conservation of mural diseases in museum collections. Master ’s Thesis, Shaanxi Normal University, China, 2015(in Chinese). 李文福. 馆藏壁画的病害治理研究. 硕士学位论文, 陕西师范大学, 2015. 21 Berns R S. Billmeyer and Saltzman’s principles of color technology. John Wiley & Sons, 2019. 22 Alhabeb M, Maleski K, Anasori B, et al. Chemistry of Materials, 2017, 29, 7633. 23 Sarycheva A, Shanmugasundaram M, Krayev A, et al. ACS Nano, 2022, 16(4), 6858. 24 Han Z F, Huang X, Chen J C, et al. Journal of Cultural Heritage, 2024, 67, 42. 25 Ge G, Zhang Y Z, Zhang W L, et al. ACS Nano, 2021, 15(2), 2698. 26 Zhang J Y, Wu J C, Langner S, et al. Advanced Functional Materials, 2022, 32(43), 2207101. 27 Wang L. Study on UV aging mechanism and aging resistance modification of stone cultural relics protection materials. Master ’s Thesis, Beijing University of Chemical Technology, China, 2023 (in Chinese). 王莉. 石质文物保护材料紫外光老化机理与耐老化改性研究. 硕士学位论文, 北京化工大学, 2023. 28 National Cultural Heritage Administration. WW/T 0113—2023 Technical specification for the conservation and restoration of flaking murals in ancient tombs, Cultural Relics Press, China, 2023(in Chinese). 国家文物局. WW/T 0113—2023 古代壁画起甲病害修复技术规范, 文物出版社, 2023. |
| [1] |
SHI Pei, JIA Weiming, CHEN Le, ZHEN Gang, MA Tao, ZHANG Xin, WANG Fen, ZHU Jianfeng, ZHANG Biao, LI Doudou. Analysis and Evaluation of Aging Resistance of Organic Bonding Materials Commonly Used in Pottery Cultural Relics[J]. Materials Reports, 2025, 39(20): 24070169-8. |
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