VO<sub>2</sub>智能调温涂层的研究进展

doi:10.11896/cldb.24030036

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Abstract Vanadium dioxide (VO₂) , a typical binary transition metal oxide, has the characteristics of metal-insulator phase transformation, which can achieve the reversible transformation of monoclinic insulating phase and stable rutile metal phase at about 68 ℃, and it has a good application prospect in the construction field for it. In recent years, the preparation technology for VO₂ has been relatively mature, but the improvement of its thermochromic performance is still the focus of research. Based on it, with the thermochromic performance control of VO₂ as the center, this paper summarized the research progress of VO₂ intelligent temperature control coatings. Firstly, the crystal structure and band structure changes of VO₂ before and after the phase transition are summarized, and the three phase transition mechanisms based on the Mott theory, the Peierls theory and the Mott-Peierls synergy theory are discussed in detail. Secondly, the influence of elemental doping on the phase transition temperature of VO₂ is clarified, and the enhancement principle of the structural design of core-shell structure and multilayer film structure on the comprehensive properties of VO₂ such as optical properties, oxidation resistance and environmental stability is further clarified. Moreover, the characteristics and advantages of each strategy are analyzed and compared. Finally, the existing problems of VO₂ at the present stage are pointed out, and its future development is prospected. It is helpful to provide reference for researchers in related fields.

Key words： phase transitions ion doping core-shell structure multilayer membrane structure

Published: 10 April 2025 Online: 2025-04-10

CLC number:

TQ135.11

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	Articles by authors
	BAO Yan
	XIE Mengshuang
	GUO Ruyue
	ZHANG Jing

Cite this article:

BAO Yan,XIE Mengshuang,GUO Ruyue, et al. Research Progress of VO₂ Intelligent Temperature Control Coating[J]. Materials Reports, 2025, 39(7): 24030036-7.

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https://www.mater-rep.com/EN/10.11896/cldb.24030036 OR https://www.mater-rep.com/EN/Y2025/V39/I7/24030036

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