高温防护铱合金改性的研究进展

doi:10.11896/cldb.24090001

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Abstract Iridium metal, with many advantages such as a high melting point, exceptionally low oxygen permeability, robust thermal shock resistance, and superior high-temperature oxidation resistance, is esteemed as one of the ideal materials for thermal protective coatings on hot end components of aerospace equipment which services in extreme high-temperature environments ranging from 1 800 to 2 200 ℃. However, due to the high catalytic activity, low emissivity, and volatility of iridium, the service life of iridium is significantly shortened, necessitating modifications such as alloying to enhance its durability and performance. To this end, this paper reviewed the recent progress of Ir-Al, Ir-Hf, Ir-Zr, Ir-Rh, Ir-Ta, Ir-Re, and Ir-Nb iridium alloys, Ir-Al-X (X=Ta, Hf, and Zr) ternary iridium-aluminum-based alloys, and Ir-Nb-Y (Y=Hf, Ta, and Ti) ternary iridium-niobium-based alloys for their high-temperature oxidation resistance. Moreover this study built the correlation between the composition and organization of the above iridium alloys and their high-temperature oxidation resistance or service life. It emphatically introduced the high temperature antioxidant effect and mechanism of iridium alloys doped with a single element or multiple elements, and discussed the high-temperature mechanical properties or interfacial bonding strength. Then the comparative analysis has clarified the potential alloying elements such as Hf, Al, Zr, and Rh, which can be used for the design and development of iridium alloys under extreme high temperature service environments. These may provide a reference and point to a direction for the design and development of iridium alloys for extreme high temperature service environments and engineering applications.

Key words： high-temperature oxidation resistance iridium alloy alloying modification thermal protection

Published: 10 November 2025 Online: 2025-11-10

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TB34

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	LIU Zhongyu
	DING Chenxi
	FANG Zhen
	LYU Biao
	HU Zhenfeng
	WANG Haoxu
	LIU Quan

Cite this article:

LIU Zhongyu,DING Chenxi,FANG Zhen, et al. Research Progress on Modification of Iridium Alloys for High Temperature Protection[J]. Materials Reports, 2025, 39(21): 24090001-13.

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https://www.mater-rep.com/EN/10.11896/cldb.24090001 OR https://www.mater-rep.com/EN/Y2025/V39/I21/24090001

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