| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| A Review of Aging Mechanism on Polymer-modified Asphalt Binders |
| ZHANG Yuan1,2, CAO Zixuan1, YU Jiangmiao1,2,3, YU Huayang1, ZOU Guilian1,*
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1 School of Civil Engineering and Transportation, South China University of Technology, Guangzhou 510641, China
2 State Key Laboratory of Subtropical Building and Urban Science, South China University of Technology, Guangzhou 510640, China
3 Central Fortune Creation Technology Group Co., Ltd., Foshan 528000, Guangdong, China |
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Abstract This paper reviews three types of polymer modifiers commonly used in asphaltbinders and their improvement in the performance of asphalt binders, analyses the effect of aging on polymer-modified asphalt. Moreover, the aging mechanism of polymer-modified asphalt binders is explained from polymer phase degradation, chain breakage, and free radical formation respectively. Differences in different polymer-modified asphalt binders due to aging at the macro and micro scales have been generalized. Finally, the research progress of antioxidants based on aging mechanism is summarized. The results show that the three main types of polymers used in asphalt are thermoplastic elastomers, thermoset elastomers, and plastics. Polymer-modified asphalt binders exhibit different aging characteristics from base asphalt binders, resulting from the dominant role of polymer degradation in the aging of modified asphalt binders. Macroscopically, the aging of polymer-modified asphalt includes oxidation of the base binders and degradation of the polymer phase. Microscopically, this includes dehydrogenation of the asphalt molecule, cycloalkane aromatization, polymer molecule chain breakage, the formation of oxygen-containing groups, and chemical-physical cross-linking of the polymer and asphalt binders groups. Currently, the methods for studying polymer degradation levels include the solvent oil method, extraction met-hod and characteristic peak method, which have their pros and cons, and more experimental methods for polymer degradation characterization need to be explored in the future. In addition, it is recommended to establish a complete aging theory system from various aspects such as rheological properties, microstructure, and molecular dynamics. At the same time, the development of antioxidants from the multifunctionality, economy, sustainability, and long-lasting and other aspects of comprehensive consideration is also one of the directions in future research.
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Published: 25 May 2025
Online: 2025-05-13
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2025, Vol. 39 
