REVIEW PAPER |
|
|
|
|
|
Research Status of Corrosion Behavior for Uranium in Vapor Environment |
QIN Jianwei1, LUO Lizhu1, SHUAI Maobing2
|
1 Science and Technology on Surface Physics and Chemistry Laboratory, Mianyang 621700; 2 Institute of Material Science, Chinese Academic of Engineering and Physics, Mianyang 621700 |
|
|
Abstract Uranium is one of the most important nuclear material, which have been widely used in defense industry and energy engineering. However, its properties could be decreased due to the reaction with minor vapor existed in the environment during stockpile, which stems from the high chemical reactivity of uranium. A lot of researches are developed in order to recognize the reaction process between uranium and water. The main points of these reactions are reviewed in this paper, including the corrosion pro-ducts, corrosion kinetics and corrosion mechanisms. The future research areas are proposed based on the defect structures in uranium oxide, microstructure of the uranium metal and the inhibition mechanism by oxygen.
|
Published: 10 July 2017
Online: 2018-05-04
|
|
|
|
1 Luo L Z, Lai X C, Wang X L. Progress on uranium surface science [J].Prog Chem,2011,23(7):1322(in Chinese). 罗丽珠,赖新春,汪小琳. 我国铀表面科学研究进展[J]. 化学进展,2011,23(7):1322. 2 Xiong B T,Meng D Q, Yang W C. Experimental study on accele-rated corrosion uranium-water vapor by thermogravimetry[J].Ato-mic Energy Sci Technol,2005,39(3):226(in Chinese). 熊必涛,蒙大桥,杨维才. 金属铀在水气气氛中加速腐蚀的实验研究[J]. 原子能科学技术,2005,39(3):226. 3 Wang X L, Fu Y B, Xie R S. Study on the surface oxidation of uranium in different gaseous atmospheres [J]. China Nucl Sci Technol Rep,1996(S1):475(in Chinese). 汪小琳, 傅依备, 谢仁寿. 金属铀在各种气体环境中的表面氧化反应[J]. 中国核科技报告,1996(S1):475. 4 Wu Y P, Zhu S F, Liu T W, et al. Reaction of uranium and its alloy with oxygen and water vapor[J]. J Nucl Radiochem,2014,36(6):321(in Chinese). 吴艳萍, 朱生发, 刘天伟, 等. 铀及其合金的水氧腐蚀机理分析[J]. 核化学与放射化学,2014,36(6):321. 5 Kofstad P. High-temperature oxidation of metals[M]. New York: John Wiley Sons,1966:340. 6 Leibowitz L, Schnizlein J G, Bingle J D, et al. The kinetics of oxidation of uranium between 125° and 250°C [J]. J Electrochem Soc,1961,108(12):1155. 7 Orman S. Oxidation of uranium and uranium alloys[M]. MA: Brook Hill Publishing Company,1976:815. 8 Baker L, Bingle J D. The kinetics of oxidation of uranium between 300 and 625 ℃[J]. J Nucl Mater,1966,20:11. 9 Baker M M, Less L N, Orman S. Uranium + water reaction Part 1. Kinetics, products and mechanism[J]. Trans Faraday Soc,1966,108(62):2513. 10 Espriu-Gascon A, Llorca J, Dominguez M, et al. UO2 surface oxidation by mixtures of water vapor and hydrogen as a function of temperature[J]. J Nucl Mater,2015, 467:240. 11 Pearce R J, Bennett M J, Price J B. Oxidation of irradiated uranium in moist air [J]. Nucl Energy,1988,27:305. 12 Magnani N J. The reaction of uranium and its alloys with water vapor at low temperatures: SAND-74-0145[R]. Sandia National Laboratory, 1974. 13 Peretrukhin V F, Maslennikov A G, Tsivadze A Y, et al. Corrosion of uranium and its low content Zr, Nb, and Ru alloys in aqueous solutions [J]. Protect Metals,2008,44(3):211. 14 Hayward P J, Evans D G, Taylor P, et al. Oxidation of uranium in steam [J]. J Nucl Mater,1994,217(1-2):82. 15 Hilton B A. Review of oxidation rates of DOE spent nuclear fuel: Part 1-metallic fuel: ANL-00/24[R]. US DOE: Argonne National Laboratory,2000. 16 Totemeier T C. A review of the corrosion and pyrophoricity behavior of uranium and plutonium, ANL/ED/95-2[R]. US DOE: Argonne National Laboratory,1995. 17 Lynds L, Young W A, Mohl J S. An X-ray and density study of nonstoichiometry in uranium oxides[M]. NY: American Chemical Society,1962:58. 18 Alekseyev V A, Anan’yeva L A, Rafal’skiy R P. Effects of composition on lattice parameter of UO2+x[J]. Int Geology Rev,1981,23(10):1229. 19 Wilkinson W D. Uranium metallurgy[M]. New York: Interscience Publishers,1962:757. 20 Waber J T. A review of the corrosion behaviour of uranium, LA-2035[R]. Los Alamos: Los Alamos National Laboratory,1958. 21 Stitt C A, Paraskevoulakos C, Harker N J. The effects of metal surface geometry on the formation of uranium hydride [J]. Corros Sci,2015,98:63. 22 Ritchie A G.A review of the rates of reaction of uranium with oxygen and water vapour at temperatures up to 300 ℃[J]. J Nucl Mater,1981,102:170. 23 Colmenares C A. Oxidation mechanisms and catalytic properties of the actinides[J]. Prog Solid State Chem,1984,15:257. 24 Trimble D J. Reaction rate constant for uranium in water and water vapor, HNF-2853[R].Washington DC,1998. 25 Ritchie A G. The kinetics and mechanism of the uranium-water vapor reaction — An evaluation of some published work [J]. J Nucl Mater,1984,120:143. 26 Pearce R J, Kay P. The reaction of uranium in the U-O2-H2O and U-H2O Systems, TPRD/B/0954/R87[R]. Berkeley: Berkeley Nuclear Laboratories, 1987. 27 Abrefah J, Sell R L. Oxidation of K-west basin spent nuclear fuel in moist helium atmosphere: PNNL-12167[R]. Richland: Pacific Northwest National Laboratory,1999. 28 Ritchie A G, Greenwood R C, Randles S J. The kinetics of the uranium-oxygen water vapour reaction between 40 and 100 ℃[J]. J Nucl Mater,1986,139:121. 29 Pearce R J. A review of the rates of reaction of unirradiated uranium in gaseous atmospheres, RD/B/6231/R89[R]. Berkeley: Berkeley Nuclear Laboratories,1989. 30 Baker M M, Less L N, Orman S. Uranium + water reaction Part 2.Effect of oxygen and other gases[J]. Trans Faraday Soc,1966,108(62):2525. 31 Tiferet E, Mintz M H, Jacob I, et al. Inhibition of hydrogen chemisorption on uranium surfaces by traces of water vapor [J]. Surf Sci,2007,601:4925. 32 Allen G C, Tucker P M, Lewis R A. X-ray photoelectron spectroscopy study of the initial oxidation of uranium metal in oxygen + water-vapour mixtures [J]. J Chem Soc,1984,80:991. 33 Balloch M, Hamza A V. Hydrogen and water vapor adsorption on and reaction with uranium [J]. J Nucl Mater, 1996,230:259. 34 Manner W L, Lloyd J A, Paffett M T. Reexamination of the fundamental interactions of water with uranium [J]. J Nucl Mater,1999,275:37. 35 Winer K, Colmenares C A, Smith R L. Interaction of water vapor with clean and oxygen-covered uranium surfaces [J]. Surf Sci,1987,183:67. 36 Hedhili M N, Yakshinskiy B V, Madey T E. Interaction of water vapor with UO2(001)[J]. Surf Sci,2000,445:512. 37 Rabalais J W. Direct recoil spectrometry [J]. Critical Rev Solid State Mater Sci,1988,14(4):319. 38 Tiferet E, Zalkind S, Mintz M H. Interactions of water vapor with polycrystalline uranium surfaces— The low temperature regime[J]. Surf Sci,2007,601:936. 39 Mintz M H, Shamir N. The use of direct recoil spectrometry (DRS) for the study of water vapor interactions on polycrystalline metallic surfaces—The H2O/U and H2O/Ti systems [J]. Appl Surf Sci,2005,252(3):633. 40 Tiferet E, Mintz M H, Shamir N, et al. Inhibition of hydrogen chemisorption on uranium surfaces by traces of water vapor[J]. Surf Sci,2007,601(21):4925. 41 Tiferet E, Mintz M H, Zalkind S. Heat treatment effects on the surface chemisorption behavior of strained uranium: The H2O/U reaction [J]. J Alloys Compd,2007,444-445: 177. 42 Cohen S, Mintz M H, Zalkind S, et al. Water chemisorption on a sputter deposited uranium dioxide film — Effect of defects [J]. Solid State Ionics,2014,263:39. 43 Liu Z X. The adsorption and dissociation of oxygen-contained gas molecule on uranium surface: A first-principles study [D]. Changsha:Hunan University, 2012. 刘智骁. 含氧气体分子在铀表面吸附与解离特性的第一性原理研究[D]. 长沙:湖南大学,2012. 44 Bo T, Lan J H, Wang C Z, et al. First-principles study of water reaction and H2 formation on UO2 (111) and (110) single crystal surfaces [J]. J Phys Chem C,2014,118:21935. 45 Lu G, Bernasek S L, Schwartz J. Oxidation of a polycrystalline titanium surface by oxygen and water [J]. Surf Sci,2000,458:80. 46 Chen J R, Hsiung G Y, Hsu Y J. Water adsorption-desorption on aluminum surface [J]. Appl Surf Sci,2001,169-170:679. 47 Henderson M A. The interaction of water with solid surfaces: Fundamental aspects revisited [J]. Surf Sci Rep, 2002,46:1. 48 Idriss H. Surface reactions of uranium oxide powder, thin films and single crystals [J]. Surf Sci Rep,2010,65:67. 49 Condon J B. Nucleation and growth in the hydriding reaction of uranium [J]. J Less Common Metal,1980,73:105. 50 Colmenares C, Howell R H, MacCrone R K. Application of positron annihilation, electron paramagnetic resonance and thermogravimetric techniques to the study of uranium oxidation, UCRL-90093[R]. US: Lawrence Livermore National Labaoratory,1984. 51 Howell R H, Colmenares C, McCreary T. Oxidation and hydriding of uranium studied by positron annihilation, UCRL-85925[R]. US: Lawrence Livermore National Labaoratory, 1983. 52 Haschke J M. Reactions of plutonium and uranium with water: Kinetics and potential hazards, La-13069-MS[R]. Los Alamos National Labaratory,1995. 53 Haschke J M. Corrosion of uranium in air and water vapor: Consequences for environmental dispersal [J]. J Alloys Compd,1998,278:149. 54 Haschke J M, Allen T H, Morales L A. Reactions of plutonium dioxide with water and hydrogen-oxygen mixtures: Mechanisms for corrosion of uranium and plutonium[J]. ChemInform,2001,32(13):78. 55 Haschke J M,Allen T H,Stakebake J L. Reaction kinetics of plutonium with oxygen, water, and humid air: Moisture enhancement of the corrosion Rate[J]. J Alloys Compd, 1996,243(1-2):23. 56 Weirick L J. The oxidation of uranium in low partial pressures of oxygen and water vapor at 100°C, SAND83-0618[R]. Sandia National Laboratories,1960. 57 McGillivray G W. Studies of the kinetics and mechanism of the oxidation of uranium by dry and moist air A model for determining the oxidation rate over a wide range of temperatures and water vapour pressures[J]. J Nucl Mater, 1994,208(1-2):81. |
|
|
|