含碳耐火材料酚醛树脂结合剂的研究现状与展望<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.011.013

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Abstract Owing to high thermal conductivity for better thermal shock resistance and low wettability with slag to improve corrosion resistance, carbon containing refractories are largely and diversely produced for metallurgical processes. Phenolic resin has been widely used as binder of carbon containing refractories because of compatibility with graphite, high carbon yield, environmental friendliness, high adhesive strength. However, the pyrolytic carbon derived from phenolic resin shows amorphous structure, which is brittle and easy to oxidized at elevated temperature. Many studies focus on chemical modifications of phenolic resin. Aiming to improve the anti-oxidation or/and mechanical properties or to increase yield of phenolic-resin-derived carbon, transition metal compound, nanocarbon and semiconductive ceramic particles are frequently used as catalysts, to generate carbon nanotubes (CNTs) or carbon nanofibers (CNFs) with high degree of graphitization, as well as in-situ synthesis of SiC nanowires in phenolic-resin-derived carbon.

Key words： carbon containing refractories phenolic resin binder catalytic graphitization

Published: 10 June 2017 Online: 2018-05-04

CLC number:

TM912.9

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	Articles by authors
	DING Donghai
	YANG Shaoyu
	XIAO Guoqing

Cite this article:

DING Donghai,YANG Shaoyu,XIAO Guoqing. Progress in Phenolic Resin Binder for Carbon Containing Refractories[J]. Materials Reports, 2017, 31(11): 95-100.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.011.013 OR https://www.mater-rep.com/EN/Y2017/V31/I11/95

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