锰基NASICON正极中反占位缺陷的形成机制及调控策略综述

doi:10.11896/cldb.25050151

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Abstract Manganese-based NASICON-type cathode materials, e.g., sodium manganese titanium phosphate (Na₃MnTi(PO₄)₃), have shown significant application potential in sodium-ion batteries due to high theoretical capacity, stable three-dimensional framework structure, and ra-pid sodium-ion conductivity. However, their practical performance is limited by Mn anti-site defects, including intrinsic anti-site defects (IASD) formed during material synthesis and derived anti-site defects (DASD) generated during charge-discharge processes. This review systematically summarizes recent strategies of defect suppression, including charge compensation, increasing defect formation energy, chemical bond reinforcement, and phosphorus source optimization. These approaches effectively mitigate voltage hysteresis during cycling while enhancing energy density and cycling stability. Future research is suggested to focus on integrating in-situ characterization techniques with multi-strategy synergistic optimization to advance the commercialization of high energy-density manganese-based NASICON cathode materials.

Key words： sodium-ion battery NASICON cathode anti-site defect voltage hysteresis

Published: 25 April 2026 Online: 2026-05-06

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TM911

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	Articles by authors
	ZHANG Jicong
	MA Ruguang
	LI Chang Ming

Cite this article:

ZHANG Jicong,MA Ruguang,LI Chang Ming. A Review on Formation Mechanisms and Regulation Strategies of Anti-site Defects in Mn-based NASICON Cathodes[J]. Materials Reports, 2026, 40(8): 25050151-7.

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https://www.mater-rep.com/EN/10.11896/cldb.25050151 OR https://www.mater-rep.com/EN/Y2026/V40/I8/25050151

1 Toledo O M, Oliveira Folho D, Diniz A S A C. Renewable & Sustainable Energy Reviews, 2010, 14(1), 506.
2 Paolella A, Faure C, Timoshevskii V, et al. Journal of Materials Che-mistry A, 2017, 5(36), 18919.
3 Chen G, Huang Q, Wu T, et al. Advanced Functional Materials, 2020, 30(34), 2001289.
4 Wei Y F, Xia H C, Zhang J N. Materials Reports, 2024, 38(8), 23120085 (in Chinese).
魏一帆, 夏会聪, 张佳楠. 材料导报, 2024, 38(8), 23120085.
5 Wang S J, Xiao H, Ren Y R, et al. Materials Reports, 2021, 35(24), 24006 (in Chinese).
汪仕杰, 肖慧, 任玉荣, 等. 材料导报, 2021, 35(24), 24006.
6 Zhu Z S, Zhou Y, Liu J F, et al. Chinese Journal of Power Sources, 2023, 47(6), 715 (in Chinese)
朱展枢, 周宇, 刘杰飞, 等. 电源技术, 2023, 47(6), 715.
7 Wang Y F. Nei Jiang Science & Technology, 2023, 44(12), 78 (in Chinese).
王一帆. 内江科技, 2023, 44(12), 78.
8 Li X J, Xu G Y, Zhao S S, et al. High Voltage Engineering, 2024, 50(6), 2397 (in Chinese).
李相俊, 胥国毅, 赵珊珊, 等. 高电压技术, 2024, 50(6), 2397.
9 Zhang H, Gao Y, Liu X, et al. Advanced Energy Materials, 2023, 13(23), 2300149.
10 Hao Z, Shi X, Yang Z, et al. Advanced Materials, 2024, 36(7), 2305135.
11 Liu Y, Sun C, Li Y, et al. Energy Storage Materials, 2023, 57, 69.
12 Dunn B, Kamath H, Tarascon J M. Science, 2011, 334(6058), 928.
13 Rudola A, Sayers R, Wright C J, et al. Nature Energy, 2023, 8(3), 215.
14 Jin T, Li H, Zhu K, et al. Chemical Society Reviews, 2020, 49(8), 2342.
15 Pan H, Hu Y S, Chen L. Energy & Environmental Science, 2013, 6(8), 2338.
16 Ling Y, Zhou J, Guo S, et al. ACS Applied Materials & Interfaces, 2021, 13(49), 58665.
17 Liu Z, Xu X, Ji S, et al. Chemistry, 2020, 26(35), 7747.
18 Li M M, Qiu X Y, Yin Y X, et al. The Chinese Journal of Process Engineering, 2023, 23(6), 799 (in Chinese).
李苗苗, 邱祥云, 尹延鑫, 等. 过程工程学报, 2023, 23(6), 799.
19 Wang Q C, Hu E, Pan Y, et al. Advanced Science, 2017, 4(11), 1700219.
20 Thompson A H, Whittingham M S. Materials Research Bulletin, 1977, 12(7), 741.
21 Mizushima K, Jones P C, Wiseman P J, et al. Materials Research Bulletin, 1980, 15(6), 783.
22 Qian J, Wu C, Cao Y, et al. Advanced Energy Materials, 2018, 8(17), 1702619.
23 Jiang Y, Yu S, Wang B, et al. Advanced Functional Materials, 2016, 26(29), 5315.
24 Ren W, Zhu Z, Qin M, et al. Advanced Functional Materials, 2019, 29(15), 1806405.
25 Wang L, Song J, Qiao R, et al. Journal of the American Chemical Society, 2015, 137(7), 2548.
26 Xu C, Xiao R, Zhao J, et al. American Chemical Society Energy Letters, 2022, 7(1), 97.
27 Hou J, Hadouchi M, Sui L, et al. Energy Storage Materials, 2021, 42, 307.
28 Ghosh S, Barman N, Senguttuvan P. Small, 2020, 16(45), 2003973.
29 Soundharrajan V, Alfaruqi M H, Lee S, et al. Journal of Materials Chemistry A, 2020, 8(24), 12055.
30 Zhou W, Xue L, Lü X, et al. Nano Letters, 2016, 16(12), 7836.
31 Ghosh S, Barman N, Mazumder M, et al. Advanced Energy Materials, 2020, 10(6), 1902918.
32 Zhang J, Liu Y, Zhao X, et al. Advanced Materials, 2020, 32(11), 1906348.
33 Gao H, Li Y, Park K, et al. Chemistry of Materials, 2016, 28(18), 6553.
34 Li H, Xu M, Gao C, et al. Energy Storage Materials, 2020, 26(325), 33.
35 Fang J, Wang S, Li Z, et al. Journal of Materials Chemistry A, 2016, 4(4), 1180.
36 Duan W, Zhu Z, Li H, et al. Journal of Materials Chemistry A, 2014, 2(23), 8668.
37 Gao H, Seymour I D, Xin S, et al. Journal of the American Chemical Society, 2018, 140(51), 18192.
38 Wang Q, Ling C, Li J, et al. Chemical Engineering Journal, 2021, 425, 130680.
39 Zhu T, Hu P, Cai C, et al. Nano Energy, 2020, 70, 104548.
40 Zhu T, Hu P, Wang X, et al. Advanced Energy Materials, 2019, 9(9), 1803436.
41 Liu Y, Rong X, Bai R, et al. Nature Energy, 2023, 8(10), 1088.
42 Xu C, Hua W, Feng G, et al. Angewandte Chemie International Edition, 2025, 64(22), e202502758.
43 Xu C, Hua W, Zhang Q, et al. Advanced Functional Materials, 2023, 33(33), 2302810.
44 Chen S, Hou J, He X, et al. ACS Applied Materials & Interfaces, 2024, 16(39), 52653.
45 Hu P, Zhu T, Cai C, et al. Angewandte Chemie International Edition, 2023, 62(14), e202219304.
46 Hu P, Zhu T, Ma J, et al. Chemical Communications, 2019, 55(58), 8486.
47 Gu Z Y, Guo J Z, Cao J M, et al. Advanced Materials, 2022, 34(14), 2110108.
48 Deng S, Song C, Cheng S, et al. ACS Nano, 2025, 19, 10, 10381.
49 Zhang J, Lin C, Xia Q, et al. ACS Energy Letters, 2021, 6(6), 2081.
50 Liu R, Zheng S, Yuan Y, et al. Advanced Energy Materials, 2021, 11(3), 2003256.
51 Liu R, Xu G, Li Q, et al. ACS Applied Materials & Interfaces, 2017, 9(50), 43632.
52 Wang J, Zhang B, Cai Z, et al. Science Bulletin, 2022, 67(7), 716.
53 Yu Y S, Kim C, Shapiro D A, et al. Nano Letters, 2015, 15(7), 4282.
54 Malik R, Burch D, Bazant M, et al. Nano Letters, 2010, 10(10), 4123.
55 Guo Y, Yao Y, Guo C, et al. Energy & Environmental Science, 2024, 17(20), 7749.
56 Song Y, Cui Y, Geng L, et al. Advanced Energy Materials, 2024, 14(7), 2303207.
57 Zheng J, Teng G, Xin C, et al. Journal of Physical Chemistry Letters, 2017, 8(22), 5537.
58 Wu K, Ran P, Yin W, et al. Angewandte Chemie International Edition, 2024, 63(42), e202410326.
59 Chen S, Wu G, Jiang H, et al. Nature, 2025, 638(8051), 676.