磷酸铁基聚阴离子型钠离子电池正极材料改性策略

doi:10.11896/cldb.24120135

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Abstract With the rapid growth of global energy storage demands, sodium-ion batteries (SIB) have attracted significant attention due to their remarkable cost-effectiveness. As the core functional component of battery, the cathode material plays a decisive role in determining the electrochemical performance. Currently, the main cathode materials for SIB, such as layered oxides and Prussian blue analogs, exhibit certain limitations in terms of structural stability. In contrast, iron phosphate-based polyanion (IPBP) cathode materials, with unique multi-anion induction effect, exhibit exceptional structural stability and long cycling life. Furthermore, the abundant reservation of sodium (Na) and iron (Fe) endows IPBP-based SIB with a cost advantage over lithium-ion batteries, positioning them promising candidates for large-scale applications. However, the larger ionic radius of sodium ions results in higher migration barriers, and IPBP materials exist limitations in conductivity and energy density. To overcome these shortcomings, various modification strategies have been proposed, including ion doping, morphological and structural design, interface engineering and integrated approaches, to enhance the electrochemical performance of IPBP materials. This review systematically summarizes the current research and main challenges of IPBP cathode materials, focusing on the mechanisms of different modification strategies and their impact on improving electrochemical performance. Finally, the future research and application prospects of IPBP cathode materials are discussed. This review aims to provide valuable insights for the research of IPBP cathode materials for SIBs and promote the application of SIBs in large-scale energy storage systems.

Key words： sodium-ion battery cathode material polyanion sodium iron phosphate ion doping structure design interface engineering

Published: Online: 2026-02-13

CLC number:

TB34

Corresponding Authors: ziliyu@scu.edu.cn

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	WANG Yan
	TANG Wenjian
	GU Aiqun
	XIE Meiju
	YU Zili

Cite this article:

WANG Yan,TANG Wenjian,GU Aiqun, et al. Modification Strategy of Iron Phosphate-based Polyanionic Sodium-ion Battery Cathode Materials[J]. Materials Reports, 2026, 40(3): 24120135-11.

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https://www.mater-rep.com/EN/10.11896/cldb.24120135 OR https://www.mater-rep.com/EN/Y2026/V40/I3/24120135

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