N/O/P共掺杂三聚氰胺基多孔碳材料的制备及储锌性能研究

doi:10.11896/cldb.23100113

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (9988KB)
Export: BibTeX | EndNote (RIS)

Abstract In this work, via a hydrothermal process, melamine and hexa-p-aldehyde phenoxycyclotriphosphazene (HAPCP) were used as raw materials to prepare the cross-linking product rich in nitrogen, phosphorus, and oxygen, which was subsequently carbonized and activated to obtain the carbon-based electrode material for cathode of zinc-ion hybrid capacitors. The morphology, structure, and chemical composition of the carbon-based electrode material were characterized by means of scanning electron microscopy (SEM), X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and nitrogen adsorption-desorption test. The experiment indicated that the prepared carbon-based material had a porous and rough surface morphology, amorphuous carbon structure, and contained nitrogen, phosphorus, and oxygen heteroatoms. The resultant product with a HAPCP/melamine molar ratio of 1∶5 and an activation temperature of 800 ℃ (HMAc-800) exhibited a specific capacitance of 390 F·g^-1 at a current density of 0.5 A·g^-1. The zinc-ion hybrid capacitor, assembled with HMAc-800 as the cathode material and a zinc sheet as the anode, delivered a power density of 456 W·kg^-1 at an energy density of 139 Wh·kg^-1, demonstrated a strong energy storage capacity.

Key words： melamine carbon-based material electrochemical performance zinc-ion hybrid capacitor

Published: 25 January 2025 Online: 2025-01-21

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LI Pengjuan
	ZOU Zhenyu
	HUANG Pengfei
	JIN Xin
	WU Xiaoyu
	LI Xiaoli

Cite this article:

LI Pengjuan,ZOU Zhenyu,HUANG Pengfei, et al. Preparation and Zinc Storage Properties of N/O/P Co-doped Melamine-based Porous Carbon Materials[J]. Materials Reports, 2025, 39(2): 23100113-7.

URL:

https://www.mater-rep.com/EN/10.11896/cldb.23100113 OR https://www.mater-rep.com/EN/Y2025/V39/I2/23100113

1 Zhu Q, Zhao D, Cheng M, et al. Advanced Energy Materials, 2019, 9(36), 1901081.
2 Wei F, Zeng Y, Guo Y, et al. Chemical Engineering Journal, 2023, 468, 143576.
3 Liu Y, Wu L. Nano Energy, 2023, 109,108290.
4 Titirici M M, White R J, Brun N, et al. Chemical Society Reviews, 2015, 44(1), 250.
5 Jagadale A D, Rohit R C, Shinde S K, et al. ChemNanoMat, 2021, 7(10), 1082.
6 Zhang D, Li L, Gao Y, et al. ChemElectroChem, 2021, 8(9), 1541.
7 Yang X J, Liu Y X. Zhejiang Chemical Industry, 2017, 48(1), 26(in Chinese).
杨晓洁, 刘迎新. 浙江化工, 2017, 48(1), 26.
8 Fan H, Hu X, Zhang S, et al. Carbon, 2021, 180, 254.
9 Yang L, He X, Wei Y, et al. Nano Research, 2022, 15(5), 4068.
10 Chen A B,Wang Y Y, Yu Y F, et al. Journal of Materials Science, 2017, 52, 3153.
11 Wang D W, Pan Z M, Chen G X, et al. Electrochimica Acta, 2021, 379, 138170.
12 Shen Z F, Song Y, Yin C C, et al. Microporous and Mesoporous Mate-rials, 2021, 322, 111158.
13 Sheng Z, Lin X C, Wei H, et al. Journal of Power Sources, 2021, 515, 230629.
14 Wang S, Feng J F, Pan H. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 651, 129622.
15 Wang Y L,Zhao P Y,et al. Carbon, 2023, 22, 66.
16 Liu T, Zhang L Y, You W, et al. Small, 2018, 14(12), 1702407.
17 Liu P G, Gao Y, Tan Y Y, et al. Nano Research, 2019, 12(11), 2835.
18 Shaikh J S, Shaikh N S, Sabale S, et al. Materials Today Chemistry, 2021, 21,100480.
19 Altinci O C, Demir M. Energy & Fuels, 2020, 34(6), 7658.
20 Lu S Y, Lu Y, Jin M, et al. Applied Surface Science, 2017, 422, 900.
21 Li Z J, Wang D Z, Sun Z C, et al. Electrochimica Acta, 2023, 455,142440.
22 Cheng H L, Chen X C, Yu H Y, et al. ACS Applied Energy Materials, 2020, 3(10), 10080.
23 Zhu C, Wang M, Yang G, et al. Journal of Solid State Electrochemistry, 2017, 21(12), 3631.
24 Shao D N, Wang L, Guo J Y, et al. Journal of Materials Science: Mate-rials in Electronics, 2020, 31(13), 10811.
25 Lin X H, Yin S M, Zhang W B, et al. Diamond and Related Materials, 2022, 125,109025.
26 Cui H N, Mi H Y, Ji C C, et al. Journal of Materials Chemistry A, 2021, 9(42), 23941.
27 Chen S H, Yang G Q, Zhao X J, et al. Frontiers in Chemistry, 2020, 8, 663
28 Sun G Q, Xiao Y K, Lu B, et al. ACS Applied Materials & Interfaces, 2020, 12, 7239.