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材料导报  2025, Vol. 39 Issue (21): 24100161-7    https://doi.org/10.11896/cldb.24100161
  无机非金属及其复合材料 |
水流作用下碱激发矿渣砂浆的氯离子传输规律
王远达, 张鸿儒*, 李从正, 樊静宜, 林旭健
福州大学土木工程学院,福州 350108
Transport of Chloride Ions in Alkali-Activated Slag Mortars Under Flowing Water
WANG Yuanda, ZHANG Hongru*, LI Congzheng, FAN Jingyi, LIN Xujian
College of Civil Engineering, Fuzhou University, Fuzhou 350108, China
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摘要 采用不同激发剂制备碱激发矿渣水泥(AAS)砂浆试块,设置不同流速(v)和作用方向的Cl-侵蚀环境,研究水流作用下AAS砂浆抗Cl-侵蚀性能的影响机理。此外,引入影响系数K(v)以考虑v对Cl-扩散系数的影响,并修正水流作用下AAS砂浆Cl-扩散系数。结果表明:相比切向水流,法向水流对AAS砂浆的微观形貌和孔结构破坏更严重;此外,AAS砂浆的Cl-侵蚀深度以及Cl-扩散系数D随着法向水流v的增大而增大;而随着切向水流v的增大呈先增后减的趋势;AAS的抗流动Cl-溶液侵蚀性能优于普通硅酸盐水泥,水玻璃的激发效果强于NaOH。此外,分别建立了考虑法向和切向水流v作用下AAS砂浆的Cl-浓度分布时变预测模型。
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王远达
张鸿儒
李从正
樊静宜
林旭健
关键词:  碱激发矿渣水泥  氯离子传输  水流作用    
Abstract: Utilizing different activators to prepare alkali activated slag cement (AAS) mortar specimens, and setting up chloride ion (Cl-) erosion environments with different water flow velocities (v) and action directions, the influence mechanism fo the Cl- erosion resistance of AAS mortar under flowing water conditions was explored. Additionally, an influence coefficient K(v) was introduced to account for the effect of v on the Cl- diffusion coefficient, and the Cl- diffusion coefficient of AAS mortar under flowing water was adjusted. The results indicate that normal flowing water causes more significant damage to microscopic morphology and pore structure of AAS mortar compared to tangential flowing water. Additionally, both the Cl- erosion depth and the Cl- diffusion coefficient (D) of AAS mortar increase with higher normal flow velocities, in contrast, as the tangential flow velocity increases, the D of AAS mortar rises first and then decreases. Furthermore, AAS demonstrated better resistance to Cl- erosion than ordinary Portland cement, and the excitation effect of water glass was stronger than that of NaOH. Finally, time-varying predictive models for Cl- concentration distribution in AAS mortar, accounting for both normal and tangential water flow velocities, were developed separately.
Key words:  alkali-activated slag cement    chloride ion transport    flowing water action
出版日期:  2025-11-10      发布日期:  2025-11-10
ZTFLH:  TU528  
基金资助: 国家自然科学基金面上项目(52178121);福建省自然科学基金面上项目及优青项目(2023J01060;2024J09017)
通讯作者:  *张鸿儒,博士,福州大学土木工程学院研究员、博士研究生导师。目前主要从事混凝土结构耐久性和建筑与工业固废资源化利用等方面的研究工作。hrzh@fzu.edu.cn   
作者简介:  王远达,福州大学土木工程学院博士研究生,在张鸿儒研究员的指导下进行研究。目前主要研究领域为再生骨料混凝土多尺度性能劣化。
引用本文:    
王远达, 张鸿儒, 李从正, 樊静宜, 林旭健. 水流作用下碱激发矿渣砂浆的氯离子传输规律[J]. 材料导报, 2025, 39(21): 24100161-7.
WANG Yuanda, ZHANG Hongru, LI Congzheng, FAN Jingyi, LIN Xujian. Transport of Chloride Ions in Alkali-Activated Slag Mortars Under Flowing Water. Materials Reports, 2025, 39(21): 24100161-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24100161  或          https://www.mater-rep.com/CN/Y2025/V39/I21/24100161
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