二维碳基材料在锂硫电池中的研究进展

doi:10.11896/cldb.23100229

材料导报

2025, Vol. 39

Issue (7): 23100229-10 https://doi.org/10.11896/cldb.23100229

无机非金属及其复合材料

二维碳基材料在锂硫电池中的研究进展

徐婉琳^1,2,†, 冯腾锐^1,2,†, 吴琪^1,2,*, 夏杰桢^1,2, 曹蓉^1,2

1 西藏大学理学院, 拉萨 850000
2 西藏大学供氧研究院, 珠峰研究院, 拉萨 850000

Research Progress of Two-dimensional Carbon-based Material in Lithium-Sulfur Battery

XU Wanlin^1,2,†, FENG Tengrui^1,2,†, WU Qi^1,2,*, XIA Jiezhen^1,2, CAO Rong^1,2

1 School of Science, Xizang University, Lhasa 850000, China
2 Institute of Oxygen Supply, Center of Tibetan Studies (Everest Research Institute), Xizang University, Lhasa 850000, China

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摘要锂硫电池(Li-S电池)因其高能量密度和高比容量等优势被公认为是极具前景的先进储能系统之一。但Li-S电池由于复杂的电化学反应机制,仍存在许多未被解决的难题,例如穿梭效应、过高的电化学能垒、硫的低导电性以及硫阴极体积变化等。这些问题导致锂硫电池的实际库仑效率低下、真实容量不能达到理论预期、循环稳定性难以满足使用需求,使得锂硫电池至今未能商业化。而设计合理的电池正极材料,优化功能性隔膜是较为可行的途径。二维碳基材料具有丰富的物理、化学以及电化学性质,具备非常高的可调控性。得益于这些优势,二维碳基材料在锂硫电池中逐渐得到广泛应用。本文综述了包括石墨烯、二维缺陷碳基材料、非金属掺杂碳基材料、金属掺杂碳基材料、非金属碳化物和金属碳化物等多种二维碳基材料在锂硫电池中的研究进展和性能表现,总结了目前仍然存在的一些问题,并对其未来的发展进行了展望。

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	徐婉琳
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关键词: 锂硫电池二维碳基材料穿梭效应导电性改性

Abstract: Lithium-sulfur batteries (Li-S batteries) are regarded as one of the most promising modern energy storage systems due to their high theoretical energy density and specific capacity. However, their commercial application still faces huge challenges, such as fast capacity decay, poor cycle stability and short lifetime, originating from the shuttle effect, high electrochemical energy barrier, low conductivity of sulfur species, and volume change of sulfur cathode. Optimizing functional separators and designing appropriate positive electrode materials for batteries is a feasible approach. Two-dimensional (2D) carbon-based materials are now widely used in Li-S batteries as sulfur host materials, since they are highly controllable and have a wide range of physical, chemical, and electrochemical characteristics. This paper reviews the research progress of 2D carbon-based materials in Li-S batteries, including graphene, 2D defective carbon-based materials, non-metallic doped carbon-based materials, metal-doped carbon-based materials, non-metallic carbides and metal carbides, and their corresponding catalytic performance. Finally, we highlight a few issues that still require addressing and forecast the future development in the application of Li-S batteries.

Key words: lithium-sulfur battery two-dimensional carbon-based material shuttle effect conductivity modification

出版日期: 2025-04-10 发布日期: 2025-04-10

ZTFLH:

O4-1

基金资助: 国家自然科学基金(22168036);西藏自治区科技计划项目(XZ202201YD0020C);西藏自治区自然科学基金重点项目(XZ202301ZR0026G)

通讯作者: *吴琪,国家海外高层次人才,西藏大学理学院特聘研究员、硕士研究生导师。主要围绕计算物理和计算材料科学领域开展前瞻性、原创性问题研究,具体包括低维纳米材料的模拟与设计、高原特色环境与材料理论计算的研究工作,专注于电化学析氢制氧以及太阳能电解水制氢制氧理论研究。wuqi@utibet.edu.cn

作者简介: 徐婉琳,现为西藏大学理学院硕士研究生,在吴琪特聘研究员的指导下进行研究。目前主要研究领域为新型电池的理论设计与研究,如Li-S电池、Na-K电池等。冯腾锐,现为西藏大学理学院硕士研究生,在吴琪特聘研究员的指导下进行研究,目前主要研究领域为新型电池的理论设计与研究,如Li-S电池、Na-K电池等。
†共同第一作者

引用本文:

徐婉琳, 冯腾锐, 吴琪, 夏杰桢, 曹蓉. 二维碳基材料在锂硫电池中的研究进展[J]. 材料导报, 2025, 39(7): 23100229-10.
XU Wanlin, FENG Tengrui, WU Qi, XIA Jiezhen, CAO Rong. Research Progress of Two-dimensional Carbon-based Material in Lithium-Sulfur Battery. Materials Reports, 2025, 39(7): 23100229-10.

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https://www.mater-rep.com/CN/10.11896/cldb.23100229 或 https://www.mater-rep.com/CN/Y2025/V39/I7/23100229

1 Deng R, Wang M, Yu H, et al. Energy & Environmental Materials, 2022, 5(3), 777.
2 Li Y, Guo S. Matter, 2021, 4(4), 1142.
3 Angulakshmi N, Dhanalakshmi R B, Sathya S, et al. Batteries & Supercaps, 2021, 4(7), 1064.
4 Liang Z, Shen J, Xu X, et al. Advanced Materials, 2022, 34(30), 2200102.
5 Gu X, Zhang S, Hou Y. Chinese Journal of Chemistry, 2016, 34(1), 13.
6 Li Z, Sun H, Pang Y, et al. Materials, 2021, 14(4), 861.
7 Xie S, Chen X, Wang C, et al. Small, 2022, 18(18), 2200395.
8 Luo S, Yao M, Lei S, et al. Nanoscale, 2017, 9(14), 4646.
9 Shao Q, Wu Z S, Chen J. Energy Storage Materials, 2019, 22, 284.
10 Deng N, Feng Y, Wang G, et al. Chemical Engineering Journal, 2020, 401, 125976.
11 Tang J, Zhao Q, Li F, et al. Nanoscale, 2021, 13(45), 18883.
12 Li F, Anjarsari Y, Wang J, et al. Carbon Letters, 2023, 33(5), 1321.
13 Wang J, Ma F, Sun M. RSC Advances, 2017, 7(27), 16801.
14 Wang X, Wang Z, Chen L. Journal of Power Sources, 2013, 242, 65.
15 Wang H, Yang Y, Liang Y, et al. Nano Letters, 2011, 11(7), 2644.
16 Baumann A E, Downing J R, Burns D A, et al. ACS Applied Materials & Interfaces, 2020, 12(33), 37173.
17 Li R, Zhang M, Fu X, et al. ACS Applied Electronic Materials, 2022, 4(7), 3263.
18 Guan W, Wang T, Liu Y, et al. Advanced Energy Materials, 2023, 13(45), 2302565.
19 Yi Z, Su F, Huo L, et al. Applied Surface Science, 2020, 503, 144446.
20 Tong Z, Huang L, Liu H, et al. Advanced Functional Materials, 2021, 31(11), 2010455.
21 Zhang W, Li Y, Lv H, et al. Small Structures, 2023, 4(3), 2200244.
22 Xiong D G, Zhang Z, Huang X Y, et al. Journal of Energy Chemistry, 2020, 51, 90.
23 Pourali Z, Yaftian M R, Sovizi M R. Materials Chemistry and Physics, 2018, 217, 117.
24 Xia J, Cao R, Zhao L, et al. Journal of Colloid and Interface Science, 2023, 630, 317.
25 Liang Z, Yang D, Tang P, et al. Advanced Energy Materials, 2021, 11(5), 2003507.
26 Park J S, Park D Y, Yang S M, et al. Carbon, 2022, 196, 304.
27 Sun W, Song Z, Feng Z, et al. Nano-Micro Letters, 2022, 14(1), 222.
28 Dong Y, Xu B, Hu H, et al. Physical Chemistry Chemical Physics, 2021, 23(23), 12958.
29 Amaral M M, Mujib S B, Santos E A, et al. Journal of Energy Storage, 2023, 72, 108388.
30 Wu J, Ye T, Wang Y, et al. ACS Nano, 2022, 16(10), 15734.
31 Zhou F, Li Z, Luo X, et al. Nano Letters, 2018, 18(2), 1035.
32 Al Salem H, Chitturi V R, Babu G, et al. RSC Advances, 2016, 6(111), 110301.
33 Zhou F, Song L T, Lu L L, et al. ChemNanoMat, 2016, 2(10), 937.
34 Wang J, Wang L, Li Z, et al. Journal of Electronic Materials, 2023, 52(6), 3526.
35 Abbas S A, Ding J, Wu S H, et al. ACS Nano, 2017, 11(12), 12436.
36 Fang D, Wang Y, Liu X, et al. ACS Nano, 2019, 13(2), 1563.
37 Fang M, Chen Z, Liu Y, et al. Journal of Materials Chemistry A, 2018, 6(4), 1630.
38 Lei T, Chen W, Lv W, et al. Joule, 2018, 2(10), 2091.
39 Pei F, Lin L, Fu A, et al. Joule, 2018, 2(2), 323.
40 Chen W, Lei T, Lv W, et al. Advanced Materials, 2018, 30(40), 1804084.
41 Feng G, Liu X, Wu Z, et al. Journal of Alloys and Compounds, 2020, 817, 152723.
42 García-Soriano F J, Para M L, Luque G L, et al. Journal of Solid State Electrochemistry, 2020, 24, 2341.
43 Huang J Q, Xu Z L, Abouali S, et al. Carbon, 2016, 99, 624.
44 Fan Y, Yang Z, Hua W, et al. Advanced Energy Materials, 2017, 7(13), 1602380.
45 Zhang Y, Ma L, Tang R, et al. Applied Surface Science, 2022, 585, 152498.

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