Progress in Phenolic Resin Binder for Carbon Containing Refractories
DING Donghai1,2,3 , YANG Shaoyu1, XIAO Guoqing1
1 College of Materials and Mineral Resources, Xi’an University of Architecture and Technology, Xi’an 710055; 2 Postdoctoral Mobile Research Station of Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an 710055; 3 State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039
Abstract: Owing to high thermal conductivity for better thermal shock resistance and low wettability with slag to improve corrosion resistance, carbon containing refractories are largely and diversely produced for metallurgical processes. Phenolic resin has been widely used as binder of carbon containing refractories because of compatibility with graphite, high carbon yield, environmental friendliness, high adhesive strength. However, the pyrolytic carbon derived from phenolic resin shows amorphous structure, which is brittle and easy to oxidized at elevated temperature. Many studies focus on chemical modifications of phenolic resin. Aiming to improve the anti-oxidation or/and mechanical properties or to increase yield of phenolic-resin-derived carbon, transition metal compound, nanocarbon and semiconductive ceramic particles are frequently used as catalysts, to generate carbon nanotubes (CNTs) or carbon nanofibers (CNFs) with high degree of graphitization, as well as in-situ synthesis of SiC nanowires in phenolic-resin-derived carbon.
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2017, Vol. 31 
