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材料导报  2026, Vol. 40 Issue (5): 25030201-11    https://doi.org/10.11896/cldb.25030201
  无机非金属及其复合材料 |
基于稀土发光材料荧光强度比技术的光学温度传感研究进展
郑玉华2, 杨柳1, 郭宁3, 杨凯栋1, 张永政1, 李振民1,*, 崔彦斌2,*
1 中国稀土学会,北京 100081;
2 中国科学院过程工程研究所,介科学与工程全国重点实验室,北京 100190;
3 上海理工大学材料与化学学院,上海 200093
Advancements in Optical Temperature Sensing Utilizing Rare-earth Luminescent Materials via Fluorescence Intensity Ratio Technique
ZHENG Yuhua2, YANG Liu1, GUO Ning3, YANG Kaidong1, ZHANG Yongzheng1, LI Zhenmin1,*, CUI Yanbin2,*
1 The Chinese Society of Rare Earths, Beijing 100081, China;
2 State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China
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摘要 在恶劣、特殊环境下对物体进行准确可靠的非接触式温度测量是一项极具挑战性的工作。光学温度传感在非接触式测温、大尺度成像、医疗中局部温度的精确测量,以及对难以接近物体的直接温度测量,具有非常广阔的应用前景。本文回顾了基于稀土发光材料荧光强度比技术的光学温度传感研究进展,对不同稀土发光材料的光学温度传感机制、温度依赖的激发/发射光谱、双发射峰的构建、荧光强度数据拟合过程中的比值技术等做了详细阐述,并介绍了光学测温材料的最新进展。从基于双发射峰(单激发)和单发射峰(双激发)荧光强度比这两个比值技术方案归纳了该领域目前获得的重要成果,并讨论了需要克服的主要挑战。该领域的研究表明,与传统测温方案相比,光学温度传感在测温灵敏度、不受电磁干扰、易于实时监测等方面具有独特的优势。
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郑玉华
杨柳
郭宁
杨凯栋
张永政
李振民
崔彦斌
关键词:  稀土发光材料  荧光强度比技术  光学温度传感  热耦合能级  双发光中心    
Abstract: Conducting precise and dependable non-contact temperature measurements in harsh and unique environments presents a significant challenge. Optical temperature sensing offers substantial promise for various applications, including non-contact temperature measurement, large-scale imaging, precise temperature measurement in localized medical settings, and direct temperature measurement of inaccessible objects. This paper provides a comprehensive review of advancements in optical temperature sensing based on the fluorescence intensity ratio technique utilizing rare-earth luminescent materials. It delves into the optical temperature sensing mechanisms of diverse rare-earth luminescent materials, temperature-dependent excitation/emission spectra, the establishment of dual-emission peaks, and the ratio technique employed in the fitting process of fluorescence intensity data. Additionally, it introduces the latest developments in optical temperature measurement materials. The paper summarizes key achievements achieved so far from the perspectives of FIR techniques based on dual-emission peaks (under single excitation), single-emission peaks (under dual excitation), and discusses the primary challenges that remain to be addressed. Research in this field has shown that, compared to conventional temperature measurement methods, optical temperature sensing offers unique benefits in terms of temperature measurement sensitivity, immunity to electromagnetic interference, and the facility for real-time monitoring.
Key words:  rare-earth luminescent material    fluorescence intensity ratio technique    optical temperature sensing    thermally coupled levels    dual luminescent centers
出版日期:  2026-03-10      发布日期:  2026-03-10
ZTFLH:  TQ133.3  
通讯作者:  *王欣,博士,北京医院临床试验研究中心、研究员、硕士研究生导师。主要研究领域为社会与管理药学。wangxinannie@126.com
孙正明,博士,教授、博士研究生导师。主要研究领域包括纳米层状材料及其复合材料、无铅锡基焊料、新型储能材料和金属晶须自发生长现象及机理。zmsun@seu.edu.cn   
作者简介:  郑玉华,博士,中国科学院过程工程研究所介科学与工程全国重点实验室副研究员、硕士研究生导师,主要从事纳米材料制备与工业化应用等工作。
引用本文:    
郑玉华, 杨柳, 郭宁, 杨凯栋, 张永政, 李振民, 崔彦斌. 基于稀土发光材料荧光强度比技术的光学温度传感研究进展[J]. 材料导报, 2026, 40(5): 25030201-11.
ZHENG Yuhua, YANG Liu, GUO Ning, YANG Kaidong, ZHANG Yongzheng, LI Zhenmin, CUI Yanbin. Advancements in Optical Temperature Sensing Utilizing Rare-earth Luminescent Materials via Fluorescence Intensity Ratio Technique. Materials Reports, 2026, 40(5): 25030201-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25030201  或          https://www.mater-rep.com/CN/Y2026/V40/I5/25030201
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